Abstract
In this paper we provide a mathematical framework for localized plasmon resonance of nanoparticles. Using layer potential techniques associated with the full Maxwell equations, we derive small-volume expansions for the electromagnetic fields, which are uniformly valid with respect to the nanoparticle’s bulk electron relaxation rate. Then, we discuss the scattering and absorption enhancements by plasmon resonant nanoparticles. We study both the cases of a single and multiple nanoparticles. We present numerical simulations of the localized surface plasmonic resonances associated to multiple particles in terms of their separation distance.
Similar content being viewed by others
References
Agarwal, A., Huang, S.W., ODonnell, M., Day, K.C., Day, M. Kotov, N. and Ashkenazi S.: Targeted gold nanorod contrast agent for prostate cancer detection by photoacoustic imaging. J. Appl. Phys. 102, 064701 (2007)
Ammari, H., Chow, Y.T., Liu, K., Zou, J.: Optimal shape design by partial spectral data. ar**v:1310.6098
Ammari H., Ciraolo G., Kang H., Lee H., Milton G.W.: Spectral theory of a Neumann–Poincaré-type operator and analysis of cloaking due to anomalous localized resonance. Arch. Ration. Mech. Anal. 208, 667–692 (2013)
Ammari H., Ciraolo G., Kang H., Lee H., Milton G.W.: Anomalous localized resonance using a folded geometry in three dimensions. Proc. R. Soc. A 469, 20130048 (2013)
Ammari H., Ciraolo G., Kang H., Lee H., Milton G.W.: Spectral theory of a Neumann–Poincaré-type operator and analysis of anomalous localized resonance II. Contemp. Math. 615, 1–14 (2014)
Ammari H., Ciraolo G., Kang H., Lee H., Yun K.: Spectral analysis of the Neumann–Poincaré operator and characterization of the stress concentration in anti-plane elasticity. Arch. Ration. Mech. Anal. 208, 275–304 (2013)
Ammari H., Garnier J., Millien P.: Backpropagation imaging in nonlinear harmonic holography in the presence of measurement and medium noises. SIAM J. Imaging Sci. 7, 239–276 (2014)
Ammari H., Iakovleva E., Lesselier D., Perrusson G.: MUSIC-type electromagnetic imaging of a collection of small three-dimensional inclusions. SIAM J. Sci. Comput. 29, 674–709 (2007)
Ammari, H., Kang, H.: Polarization and Moment Tensors with Applications to Inverse Problems and Effective Medium Theory. Applied Mathematical Sciences, Vol. 162, Springer-Verlag, New York, 2007
Ammari, H., Kang, H., Lee, H.: Layer Potential Techniques in Spectral Analysis. Mathematical Surveys and Monographs series, Vol. 153, Amer. Math. Soc., 2009
Ammari H., Kang H., Lee H., Lim M., Yu S.: Enhancement of near cloaking for the full Maxwell equations. SIAM J. Appl. Math. 73, 2055–2076 (2013)
Ammari H., Khelifi A.: Electromagnetic scattering by small dielectric inhomogeneities. J. Math. Pures Appl. 82, 749–842 (2003)
Ammari, H., Millien, P., Ruiz, M., Zhang, H.: Mathematical analysis of plasmonic nanoparticles: the scalar case. ar**v:1506.00866
Ammari H., Vogelius M., Volkov D.: Asymptotic formulas for perturbations in the electromagnetic fields due to the presence of inhomogeneities of small diameter II. The full Maxwell equations. J. Math. Pures Appl. 80, 769–814 (2001)
Anker J.N., Paigre Hall W., Lyandres O., Shah N.C., Zhao J., Van Duyne R.P.: Biosensing with plasmonic nanosensors. Nat. Mater. 7, 442–453 (2008)
Archambault A., Teperik T.V., Marquier F., Greffet J.J.: Surface plasmon Fourier optics. Phys. Rev. B 79, 195414 (2009)
Baffou G., Girard C., Quidant R.: Map** heat origin in plasmonic structures. Phys. Rev. Lett. 104, 136805 (2010)
Baffou G., Quidant R.: Thermo-plasmonics: using metallic nanostructures as nano-sources of heat. Laser Photonics Rev. 7, 171–187 (2013)
Baffou G., Quidant R., Girard C.: Heat generation in plasmonic nanostructures: influence of morphology. Appl. Phys. Lett. 94, 153109 (2009)
Baffou G., Rigneault H.: Femtosecond-pulsed optical heating of gold nanoparticles. Phys. Rev. B 84, 035415 (2011)
Bonnetier, E., Triki, F.: Pointwise bounds on the gradient and the spectrum of the Neumann–Poincaré operator: the case of 2 discs. Multi-scale and high-contrast PDE: from modelling, to mathematical analysis, to inversion, 81–91, Contemp. Math. Vol. 577, Amer. Math. Soc., Providence, RI, 2012
Bonnetier E., Triki F.: On the spectrum of the Poincaré variational problem for two close-to-touching inclusions in 2D. Arch. Ration. Mech. Anal. 209, 541–567 (2013)
El-Brolossy T., Abdallah T., Mohamed M.B., Abdallah S., Easawi K., Negm S., Talaat H.: Shape and size dependence of the surface plasmon resonance of gold nanoparticles studied by photoacoustic technique. Euro. Phys. J. 153, 361–364 (2008)
Buffa A., Costabel M., Sheen D.: On traces for \({H(\mathrm{curl}, \Omega)}\) in lipschitz domains. J. Math. Anal. Appl. 276, 845–867 (2002)
Chapuis P.O., Laroche M., Volz S., Greffet J.J.: Naer-field induction heating of metallic nanoparticles due to infrared magnetic dipole contribution. Phys. Rev. B 77, 125402 (2008)
Chen H., Shao L., Ming T., Sun Z., Zhao C., Yang B., Wang J.: Understanding the photothermal conversion efficiency of gold nanocrystals. Small 6, 2272–2280 (2010)
Colas des Francs G., Derom S., Vincent R., Bouhelier A., Dereux A.: Mie plasmons: modes volumes, quality factors, and coupling strengths (purcell factor) to a dipolar emitter. Int. J. Opt. 2012, 175162 (2012)
Colton, D., Kress, R.: Inverse Acoustic and Electromagnetic Scattering Theory, Vol. 93. Springer, Berlin, 2012
Colton, D., Kress, R.: Integral Equation Methods in Scattering Theory, Vol. 72. SIAM, Philadelphia, 2013
Gil, M.I.: Norm Estimations for Operator Valued Functions and Applications, Vol. 192. CRC Press, Boca Raton, 1995
Govorov A.O., Richardson H.: Generating heat with metal nanoparticles. NanoToday (1) 2, 20–39 (2007)
Govorov A.O., Zhang W., Skeini T., Richardson H., Lee J., Kotov N.A.: Gold nanoparticle ensembes as heaters and actuators: melting and collective plasmon resonances. Nanoscale Res. Lett. 1, 84–90 (2006)
Grieser D.: The plasmonic eigenvalue problem. Rev. Math. Phys. 26, 1450005 (2014)
Griesmaier R.: An asymptotic factorization method for inverse electromagnetic scattering in layered media. SIAM J. Appl. Math. 68, 1378–1403 (2008)
Grua P., Morreeuw J.P., Bercegol H., Jonusauskas G., Vallée F.: Electron kinetics and emission for metal nanoparticles exposed to intense laser pulses. Phys. Rev. B 68, 035424 (2003)
Hao F., Nehl C.L., Hafner J.H., Nordlander P.: Plasmon resonances of a gold nanostar. Nano Lett. 7, 729–732 (2007)
Helsing J., Perfekt K.M.: On the polarizability and capacitance of the cube. Appl. Comput. Harmon. Anal. 34, 445–468 (2013)
Homola J.: Electromagnetic theory of surface plasmons. Springer Ser. Chem. Sens. Biosens. 4, 3–44 (2006)
Hutter E., Fendler J.H.: Exploitation of localized surface plasmon resonance. Adv. Mater. 16, 1685–1706 (2004)
Jain P.K., Lee K.S., El-Sayed I.H., El-Sayed M.A.: Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: applications in biomedical imaging and biomedicine. J. Phys. Chem. B 110, 7238–7248 (2006)
Jain P.K., El-Sayed I.H., El-Sayed M.A.: Au nanoparticles target cancer. Nanotoday 2, 18–29 (2007)
Kang H., Seo J.K.: Inverse conductivity problem with one measurement: uniqueness of balls in \({\mathbb{R}^3}\). SIAM J. Appl. Math. 59, 851–867 (1999)
Kellogg, O.D.: Foundations of Potential Theory. Reprint from the first edition of 1929. Die Grundlehren der Mathematischen Wissenschaften, Band 31 Springer-Verlag, Berlin-New York, 1967
Khavinson D., Putinar M., Shapiro H.S.: Poincaré’s variational problem in potential theory. Arch. Ration. Mech. Anal. 185, 143–184 (2007)
Link S., Burda C., Nikoobakht B., El-Sayed M.A.: Laser-induced shape changes of colloidal gold nanorods using femtosecond and nanosecond laser pulses. J. Phys. Chem. B 104, 6152–6163 (2000)
Mayergoyz I.D., Fredkin D.R., Zhang Z.: Electrostatic (plasmon) resonances in nanoparticles. Phys. Rev. B 72, 155412 (2005)
Mayergoyz I.D., Zhang Z.: Numerical analysis of plasmon resonances in nanoparticules. IEEE Trans. Mag. 42, 759–762 (2006)
Mitrea D., Mitrea M., Pipher J.: Vector potential theory on nonsmooth domains in \({\mathbb{R}^3}\) and applications to electromagnetic scattering. J. Fourier Anal. Appl. 3, 131–192 (1996)
Nédélec, J.C.: Acoustic and Electromagnetic Equations: Integral Representat ions for Harmonic Problems, Springer-Verlag, New York, 2001
Nelayah J., Kociak M., Stéphan O., García De Abajo F.J., Tencé M., Henrard L., Taverna D., Pastoriza-Santos I., Liz-Marzán L.M., Colliex C.: Map** surface plasmons on a single metallic nanoparticle. Nat. Phys. 3, 348–353 (2007)
Nguyen H.M., Vogelius M.S.: A representation formula for the voltage perturbations caused by diametrically small conductivity inhomogeneities. Proof of uniform validity. Ann. Inst. H. Poincar Anal. Non Linéaire 26, 2283–2315 (2009)
Oldenburg S.J., Averitt R.D., Westcott S.L., Halas N.J.: Nanoengineering of optical resonances. Chem. Phys. Lett. 288, 243–247 (1998)
Pendry, J.B.: Radiative exchange of heat between nanostructures. J. Phys.: Condens. Matter 11, 6621-33 (1999)
Rethfeld B., Kaiser A., Vicanek M., Simon G.: Ultrafast dynamics of nonequilibrium electrons in metals under femtosecond laser irradiation. Phys. Rev. B 65, 214303 (2002)
Sarid, D., Challener, W.A.: Modern Introduction to Surface Plasmons: Theory, Mathematica Modeling, and Applications. Cambridge University Press, New York, 2010
Scholl J.A., Koh A.L., Dionne J.A.: Quantum plasmon resonances of individual metallic nanoparticles. Nature 483, 421–428 (2012)
Torres R.H.: Maxwell’s equations and dielectric obstacles with Lipschitz boundaries. J. Lond. Math. Soc. (2) 57, 157–169 (1998)
Volkov A.N., Sevilla C., Zhigilei L.V.: Numerical modeling of short pulse laser interaction with Au nanoparticle surrounded by water. Appl. Surf. Sci. 253, 6394–6399 (2007)
Vu X.H., Levy M., Barroca T., Tran H.N., Fort E.: Gold nanocrescents for remotely measuring and controlling local temperature. Nanotechnology 24, 325501 (2013)
Author information
Authors and Affiliations
Corresponding author
Additional information
Communicated by W. E
This work was supported by the ERC Advanced Grant Project MULTIMOD-267184.
Rights and permissions
About this article
Cite this article
Ammari, H., Deng, Y. & Millien, P. Surface Plasmon Resonance of Nanoparticles and Applications in Imaging. Arch Rational Mech Anal 220, 109–153 (2016). https://doi.org/10.1007/s00205-015-0928-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00205-015-0928-0