Abstract
This study aimed to develop wearable devices of textile-based triboelectric nanogenerators (TENGs) integrated with plastic metal electrodes. The plastic metal electrodes were developed using Ga-In liquid alloy with glaze powders as the contact electrodes of the textile-based TENGs. Moreover, nylon and polyester textiles with different microstructures/nanostructures were selected as frictional electrodes in TENGs to achieve high flexibility, stability, and electric conductivity. The experimental results indicated that the maximum output voltage and current of the textile-based TENGs were 30.96 V and 3.07 μA, respectively, when the TENG comprised a nylon layer with embroidered square array patterns and a polyester layer with polyvinylidene fluoride nanofibers. Furthermore, these TENGs could generate a maximum output power of 13.97 μW when the external load resistance was 10 MΩ. After a continuous 7200 cycle operation with a reciprocating linear motion platform having a pneumatic cylinder, the textile-based TENG exhibited excellent stability and durability. The fabricated TENGs integrated in a commercial coat, shoe, kneecap, and wristband achieved biomechanical energy conversion functions with high electrical performance for practical applications of self-powered devices.
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References
Aricò AS, Bruce P, Scrosati B, Tarascon JM, Schalkwijk WV (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4:366–377
Wang ZL, Song J (2006) Piezoelectric nanogenerators based on zinc oxide nanowire arrays. Science 312:242–246
Wang X (2012) Piezoelectric nanogenerators-harvesting ambient mechanical energy at the nanometer scale. Nano Energy 1:13–24
Fan FR, Tian ZQ, Wang ZL (2012) Flexible triboelectric generator. Nano Energy 1:328–334
Gal CW, Han JS, Park JM, Kim JH, Park SJ (2019) Fabrication of micro piezoelectric rod array using metallic mold system for mass production. Int J Adv Manuf Technol 101:2815–2823
Zhang QS, Chen XB, Yang Q, Zhang WJ (2012) Development and characterization of a novel piezoelectric-driven stick-slip actuator with anisotropic-friction surfaces. Int J Adv Manuf Technol 61:1029–1034
Saha CR, O’Donnell T, Wang N, McCloskey P (2008) Electromagnetic generator for harvesting energy from human motion. Sensors Actuators A Phys 147:248–253
Dresselhaus MS, Chen G, Tang MY, Yang R, Lee H, Wang D, Ren Z, Fleurial JP, Gogna P (2007) New directions for low-dimensional thermoelectric materials. Adv Mater 19:1043–1053
Cuadrasa A, Gasulla M, Ferrari V (2010) Thermal energy harvesting through pyroelectricity. Sensors Actuators A Phys 158:132–139
Jeon YP, Park JH, Kim TW (2018) Highly-enhanced triboelectric nanogenerators based on zinc-oxide nanoripples acting as a triboelectric layer. Appl Surf Sci 445:50–55
Jeon YP, Park JH, Kim TW (2019) Highly flexible triboelectric nanogenerators fabricated utilizing active layers with a ZnO nanostructure on polyethylene naphthalate substrates. Appl Surf Sci 466:210–214
Taghavi M, Sadeghi A, Mazzolai B, Beccai L, Mattoli V (2014) Triboelectric-based harvesting of gas flow energy and powerless sensing applications. Appl Surf Sci 323:82–87
Cheng GG, Jiang SY, Li K, Zhang ZQ, Wang Y, Yuan NY, Ding JN, Zhang W (2017) Effect of argon plasma treatment on the output performance of triboelectric nanogenerator. Appl Surf Sci 412:350–356
Chen J, Zhu G, Yang J, **g Q, Bai P, Yang W, Qi X, Su Y, Wang ZL (2015) Personalized keystroke dynamics for self-powered human-machine interfacing. ACS Nano 9:105–116
Yang J, Chen J, Su Y, **g Q, Li Z, Yi F, Wen X, Wang Z, Wang ZL (2015) Eardrum-inspired active sensors for self-powered cardiovascular system characterization and throat-attached anti-interference voice recognition. Adv Mater 27:1316–1326
Seung W, Gupta MK, Lee KY, Shin KS, Lee JH, Kim TY, Kim S, Lin J, Kim JH, Kim SW (2015) Textile-based wearable triboelectric nanogenerator. ACS Nano 9:3501–3509
Zhang Z, He J, Wen T, Zhai C, Han J, Mu J, Jia W, Zhang B, Zhang W, Chou X, Xue C (2017) Magnetically levitated-triboelectric nanogenerator as a self-powered vibration monitoring sensor. Nano Energy 33:88–97
Kim I, Jeon H, Kim D, You J, Kim D (2018) All-in-one cellulose based triboelectric nanogenerator for electronic paper using simple filtration process. Nano Energy 53:975–981
Zhang Z, Du K, Chen X, Xue C, Wang K (2018) An air-cushion triboelectric nanogenerator integrated with stretchable electrode for human-motion energy harvesting and monitoring. Nano Energy 53:108–115
Shi L, Dong S, Ding P, Chen J, Liu S, Huang S, Xu H, Farooq U, Zhang S, Li S, Luo J (2019) Carbon electrodes enable flat surface PDMS and PA6 triboelectric nanogenerators to achieve significantly enhanced triboelectric performance. Nano Energy 55:548–557
Li Z, Zhu M, Qiu Q, Yu J, Ding B (2018) Multilayered fiber-based triboelectric nanogenerator with high performance for biomechanical energy harvesting. Nano Energy 53:726–733
Yang W, Wang X, Li H, Wu J, Hu Y, Li Z, Liu H (2019) Fundamental research on the effective contact area of micro-/nano-textured surface in triboelectric nanogenerator. Nano Energy 57:41–47
He T, Shi Q, Wang H, Wen F, Chen T, Ouyang J, Lee C (2019) Beyond energy harvesting - multi-functional triboelectric nanosensors on a textile. Nano Energy 57:338–352
Zhu G, Bai P, Chen J, Wang ZL (2013) Power-generating shoe insole based on triboelectric nanogenerators for self-powered consumer electronics. Nano Energy 2:688–692
Sun J, Li W, Liu G, Li W, Chen M (2015) Triboelectric nanogenerator based on biocompatible polymer materials. J Phys Chem C 119:9061–9068
Iftekhar ASM, Chung GS (2016) Fabrication and characterization of self-powered active hydrogen sensor based on triboelectric nanogenerator. Procedia Eng 168:239–242
Zhu G, Lin ZH, **g Q, Bai P, Pan C, Yang Y, Zhou Y, Wang ZL (2013) Toward large-scale energy harvesting by a nanoparticle-enhanced triboelectric nanogenerator. Nano Lett 13:847–853
Yang Y, Zhang H, Chen J, Lee S, Hou TC, Wang ZL (2013) Simultaneously harvesting mechanical and chemical energies by a hybrid cell for self-powered biosensors and personal electronics. Energy Environ Sci 6:1744–1749
Dhakar L, Pitchappa P, Tay FEH, Lee C (2016) An intelligent skin based self-powered finger motion sensor integrated with triboelectric nanogenerator. Nano Energy 19:532–540
Yang SY, Shih JF, Chang CC, Yang CR (2017) Development of high-flexible triboelectric generators using plastic metal as electrodes. Appl Phys A Mater Sci Process 123:128
Shih JF, Yang SY, Chang CC, Yang CR (2018) Wearable sensors developed using a novel plastic metal material. Appl Phys A Mater Sci Process 124:799
Hou TC, Yang Y, Zhang H, Chen J, Chen LJ, Wang ZL (2013) Triboelectric nanogenerator built inside shoe insole for harvesting walking energy. Nano Energy 2:856–862
Ko YH, Lee SH, Leem JW, Yu JS (2014) High transparency and triboelectric charge generation properties of nano-patterned PDMS. RSC Adv 4:10216–10220
Chen J, Guo H, Ding P, Pan R, Wang W, Xuan W, Wang X, ** H, Dong S, Luo J (2016) Transparent triboelectric generators based on glass and polydimethylsiloxane. Nano Energy 30:235–241
Zhang X, Qu N, Li H, Xu Z (2015) Investigation of machining accuracy of micro-dimples fabricated by modified microscale pattern transfer without photolithography of substrates. Int J Adv Manuf Technol 81:1475–1485
Hassanin H, Qstadi H, Jiang K (2013) Surface roughness and geometrical characterization of ultra-thick micro moulds for ceramic micro fabrication using soft lithography. Int J Adv Manuf Technol 67:2293–2300
Leksakul K, Limcharoen A (2014) Central composite designs coupled with simulation techniques for optimizing RIE process. Int J Adv Manuf Technol 70:1219–1225
Zhang XS, Han MD, Wang RX, Meng B, Zhu FY, Sun XM, Hu W, Wang W, Li ZH, Zhang HX (2014) High-performance triboelectric nanogenerator with enhanced energy density based on single-step fluorocarbon plasma treatment. Nano Energy 4:123–131
Shang W, Gu GQ, Yang F, Zhao L, Cheng G, Du ZL, Wang ZL (2017) A sliding-mode triboelectric nanogenerator with chemical group grated structure by shadow mask reactive ion etching. ACS Nano 11:8796–8803
Mannsfeld SCB, Tee BCK, Stoltenberg RM, Chen CVHH, Barman S, Muir BVO, Sokolov AN, Reese C, Bao Z (2010) Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers. Nat Mater 9:859–864
Diaz AF, Felix-Navarro RM (2004) A semi-quantitative tribo-electric series for polymeric materials: the influence of chemical structure and properties. J Electrost 62:277–290
Fang J, Wang X, Lin T (2011) Electrical power generator from randomly oriented electrospun poly(vinylidene fluoride) nanofibre membranes. J Mater Chem 21:11088–11091
Zhu G, Pan C, Guo W, Chen CY, Zhou Y, Yu R, Wang ZL (2012) Triboelectric-generator-driven pulse electrodeposition for micropatterning. Nano Lett 12:4960–4965
Zhong J, Zhong Q, Fan F, Zhang Y, Wang S, Hu B, Wang ZL, Zhou J (2013) Finger ty** driven triboelectric nanogenerator and its use for instantaneously lighting up LEDs. Nano Energy 2:491–497
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We thank the Ministry of Science and Technology of Taiwan for financially supporting this research under the projects MOST 107-2221-E-027-129-MY2 and MOST 107-2622-E-027-019-CC3.
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Chang, CC., Shih, JF., Chiou, YC. et al. Development of textile-based triboelectric nanogenerators integrated with plastic metal electrodes for wearable devices. Int J Adv Manuf Technol 104, 2633–2644 (2019). https://doi.org/10.1007/s00170-019-04160-9
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DOI: https://doi.org/10.1007/s00170-019-04160-9