SpringerLink
Log in

Homo- and copolymerizations of 3-(N-carbazolyl)-1-propyne and its homologues by Mo and W catalysts

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

3-(N-Carbazolyl)-1-propyne polymerized with MoCl5- and WCl6-based catalysts to produce a polymer in high yields. The MoCl5 and MoCl5-n-Bu4Sn catalysts were the most effective (the systems solidified immediately after initiation of polymerization with these catalysts). The product polymer was a yellow solid insoluble in any solvent. Copolymerization of the present monomer with tert-butylacetylene by MoCl5-n-Bu4Sn produced a copolymer; it had a high molecular weight (M w 350,000), completely dissolved in toluene, CHCl3 etc, and formed a free-standing film by solution casting. ω-N-Carbazolyl-1-hexyne and-1-octyne produced toluene-insoluble polymers with WCl6-Ph4Sn.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. For reviews, see: Costa, G., in “Comprehensive Polymer Science”, Pergamon, Oxford, 1989, Vol. 4, Chap. 9.

    Google Scholar 

  2. Masuda, T., Higashimura, T., in “Silicon-Based Polymer Science”, Am. Chem. Soc., Washington, D. C., 1990, Chap. 35.

    Google Scholar 

  3. Dumitrescu, S., Percec, V., Simionescu, C. I., J. Polym. Sci., Polym. Chem. Ed., 15, 2893 (1977)

    Google Scholar 

  4. Kmínek, I., Cimurová, V., Nespurek, S., Makromol. Chem., 190, 1025 (1989)

    Google Scholar 

  5. Park, J.-W., Lee, J.-H., Cho, H.-N., Choi, S.-K., Macromolecules, 26, 1191 (1993)

    Google Scholar 

  6. Hubert, A. J., Reimlinger H., J. Chem. Soc. C, 1968, 606

  7. Masuda, T., Hamano, T., Tsuchihara, K., Higashimura, T., Macromolecules, 22, 1036 (1989)

    Google Scholar 

  8. Masuda, T., Okano, Y., Kuwane, T., Higashimura, T., Polym. J., 12, 907 (1980)

    Google Scholar 

  9. Masuda, T., Yoshimura, T., Tamura, K., Higashimura, T., Macromolecules, 20, 1734 (1987)

    Google Scholar 

  10. Nakano, M., Masuda, T., Higashimura, T., unpublished data.

Download references

Author information

Authors and Affiliations

  1. Department of Polymer Chemistry, Kyoto University, 606-01, Kyoto, Japan

    Mitsuru Nakano, Toshio Masuda & Toshinobu Higashimura

Authors
  1. Mitsuru Nakano
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Toshio Masuda
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Toshinobu Higashimura
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nakano, M., Masuda, T. & Higashimura, T. Homo- and copolymerizations of 3-(N-carbazolyl)-1-propyne and its homologues by Mo and W catalysts. Polymer Bulletin 34, 191–197 (1995). https://doi.org/10.1007/BF00316395

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00316395

Keywords

Search

Navigation