SpringerLink
Log in

Effect of Active Elements on the Oxidation Behaviour of Al2O3-Formers

  • Chapter
The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys

  • 250 Accesses

Abstract

The main mechanisms suggested in the literature for interpreting the effect of active elements on the growth and adhesion of alumina scales are reviewed and discussed, with particular emphasis on some of the more recent contributions.

First, the various active elements will be considered on whether they can detrimentally affect alumina scales, show varying effects or improve the protective character of such scales.

Then, the discussion will be focused on some of the more important mechanisms developed during the recent years and which account for the improvement of the properties of Al2O3 scales, i.e. effect of active elements on:

  • the strengthening of the alloy-scale bonding with relation to segregation phenomena;

  • the scale morphology and microstructure;

  • the diffusion mechanisms;

  • the scale plasticity.

The discussion will be supported by results obtained on doped massive alumina.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

eBook
USD 9.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. D.P. Whittle and J. Stringer, Phil. Trans. R. Soc. London, Ser. A, 1980, 295, 309.

    Article  CAS  Google Scholar 

  2. G.C. Wood and F.H. Stott, in High Temperature Corrosion, NACE-6, 1983, 227.

    Google Scholar 

  3. H. Hindam and D.P. Whittle, Oxid. Met., 1982, 18, 245.

    Article  CAS  Google Scholar 

  4. F.H. Stott and G.C. Wood, Mat. Sci. and Eng., 1987, 87, 267.

    Article  CAS  Google Scholar 

  5. A.M. Huntz, Mat. Sci. and Eng., 1987, 87, 251.

    Article  CAS  Google Scholar 

  6. D.P. Moon, UKAEA Report no AERE R 12930, 1988.

    Google Scholar 

  7. J.G. Smeggil, A.W. Funkenbusch and N.S. Bornstein, Met. Trans., 1986, 17A, 923.

    CAS  Google Scholar 

  8. J.G. Smeggil, Mat. Sci. and Eng., 1987, 87, 261.

    Article  CAS  Google Scholar 

  9. A.R. Nicoll and G. Wahl, Superalloys 1984, Met. Soc. of AIME Pub., 1984, 805.

    Google Scholar 

  10. A. Boumaza, G. Moulin and A.M. Huntz, Oxid. Met., 1988, 30, 3-4, 141, and A. Boumaza, Thesis, University Paris XI, Orsay, France, 1987.

    Google Scholar 

  11. R. Mevrel, ONERA, private communication.

    Google Scholar 

  12. M.H. Lagrange, A.M. Huntz and J.H. Davidson, Corr. Sci., 1984, 24 (7), 613.

    Article  CAS  Google Scholar 

  13. D. Fellman, Y. Bienvenu and M. Foucault, Mem. Sci. Rev. Met., 1983, 80, 37.

    Google Scholar 

  14. S. Taniguchi and T. Shibata, 10th ICMC, Madras 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, Vol IV, 3385.

    Google Scholar 

  15. P. Pauwels, Thesis, ENSMP-ARMINES, France, 1988.

    Google Scholar 

  16. A.S. Kahn, C.E. Lowell and C.A. Barret, J. of the Electrochemical Soc., 1980, 127 (3), 670.

    Article  CAS  Google Scholar 

  17. J.L. Pandey, S. Prakash, and M.L. Mehta, 10th ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol IV, 3507.

    Google Scholar 

  18. D. Saxena, S. Prakash, M.L. Mehta and I.P. Saraswat, 10 ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol IV, 3495.

    Google Scholar 

  19. P. Choquet, Doctor Thesis, University Paris XI, Orsay, France, 1987 and P. Choquet and R. Mevrel, Proc. Int. Conf. on Metallurgical Coatings, San Diego, 17-21 April 1989., D. Diot, P. Choquet and R. Mevrel, Proc. ICRS-2, 23-25 Nov. 1988, Nancy.

    Google Scholar 

  20. I.M. Allam, D.P. Whittle and J. Stringer, Oxid. Met., 1978, 12 (1), 35.

    Article  CAS  Google Scholar 

  21. J.C. Pivin, D. Delaunay, C. Roques-Carmes, A.M. Huntz and P. Lacombe, Corr. Sci., 1980, 20, 351.

    Article  CAS  Google Scholar 

  22. G. Ben Abderrazik, G. Moulin, A.M. Huntz and R. Berneron, J. of Mat. Sci., 1984, 19, 3173.

    Article  Google Scholar 

  23. A.M. Huntz, G. Moulin and G. Ben Abderrazik, Ann. Chim. Fr., 1986, 11, 291.

    CAS  Google Scholar 

  24. J. Rousselet, Doctor thesis, University Paris XI, Orsay, France, 1988, and Proceedings of Euroanalysis VI, 7-11 Sept. 1987, Paris, Ed. GAMS, Paris.

    Google Scholar 

  25. A.W. Funkenbusch, J.G. Smeggil and N.S. Bornstein, Met. Trans., 1985, 16A, 1164.

    CAS  Google Scholar 

  26. D.G. Lees, Oxid. Met., 1987, 27 (1-2), 75.

    Article  CAS  Google Scholar 

  27. C.L. Briant and K.L. Luthra, Met. Trans., 1988, 19A, 2091 and 2099.

    Google Scholar 

  28. R.P. Messmer and C.L. Briant, Acta Met., 1982, 30, 457.

    Article  CAS  Google Scholar 

  29. H. Hindam and D.P. Whittle, J. Electrochem. Soc., 1982, 129, 1147.

    Article  CAS  Google Scholar 

  30. J.H. Davidson, P. Lacombe, A.M. Huntz, C. Roques-Carmes, J.C. Pivin and D. Delaunay, in: Behaviour of high temperature alloys in aggressive environments. The Metals Society, London, 1980, 209.

    Google Scholar 

  31. D.P. Whittle and D.H. Boone, Proc. 8th ICMC, Mainz, 1981, Dechema, Frankfurt-Main, 718.

    Google Scholar 

  32. C.S. Giggins and F.S. Pettit, Report ARL 75-0234, 1975.

    Google Scholar 

  33. I.A. Allam, D.P. Whittle and J. Stringer, Oxid. Met., 1979, 13, 381.

    Article  CAS  Google Scholar 

  34. F.A. Golightly, F.H. Stott and G.C. Wood, J. Electrochem. Soc., 1976, 126, 1035.

    Article  Google Scholar 

  35. D. Delaunay and A.M. Huntz, J. Mat. Sci., 1982, 17, 2027.

    Article  CAS  Google Scholar 

  36. F.A. Golightly, F.H. Stott and G.C. Wood, Oxid. Met., 1976, 10, 163.

    Article  CAS  Google Scholar 

  37. C.S. Giggins, B.H. Kear, F.S. Pettit and J.K. Tien, Met. Trans., 1974, 5, 1685.

    Article  CAS  Google Scholar 

  38. J.D. Kuenzly and D.L. Douglass, Oxid. Met., 1974, 8, 139.

    Article  CAS  Google Scholar 

  39. J.K. Tien and F.S. Pettit, Met. Trans., 1972, 3, 1587.

    Article  CAS  Google Scholar 

  40. A. Kumar, M. Hasrallah and D.L. Douglass, Oxid. Met., 1974, 8, 227.

    Article  CAS  Google Scholar 

  41. T. Amano, S. Yajima and Y. Saito, Trans. JIM, 1979, 20, 431.

    CAS  Google Scholar 

  42. J.L. Smialek and R. Gibala, Met. Trans., 1983, 14A, 2143.

    CAS  Google Scholar 

  43. J.C. Pivin, C. Roques-Carmes, J. Chaumont and H. Bernas, Corr. Sci., 1980, 20, 947.

    Article  CAS  Google Scholar 

  44. A.B. Anderson, S.P. Mehandra and J.L. Smialek, J. Electrochem. Soc. 1985, 132, 1695.

    Article  CAS  Google Scholar 

  45. J.G. Smeggil, A.W. Funkenbusch and N.S. Bornstein, Proc. Spring Electrochemical Society Meeting, Cincinnati, Ohio, 1984.

    Google Scholar 

  46. C.L. Briant and R.A. Mulford, Met. Trans., 1982, 13A, 745.

    Google Scholar 

  47. J.L. Smialek, NASA, TM 81676, 1981, and TM 100 209, 1987. J.L. Smialek and R. Browning, NASA TM 87168, 1985.

    Google Scholar 

  48. J.L. Smialek, Met. Trans. 1987, A18, 164.

    Google Scholar 

  49. H. Hindam and W.W. Smeltzer, J. Electrochem. Soc., 1980, 127, 1630 and Oxid. Met., 1980, 14 (4), 337.

    Google Scholar 

  50. J. Jedlinski, 10th ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol VI, 3709.

    Google Scholar 

  51. S.S. Mrowec, A. Gil and A. Jedlinski, Werkstoffe und Korrosion, 1987, 38, 563.

    Article  CAS  Google Scholar 

  52. A.M. Huntz, G. Ben Abderrazik, G. Moulin, E.W. Joung and J.H.W. De Wit, Applied Surface Science, 1987, 28, 345 and Solid State Ionics, 1987, 22, 285.

    Google Scholar 

  53. E.J. Felten and F.S. Pettit, Oxid. Met., 1976, 10, 189.

    Article  CAS  Google Scholar 

  54. T.A. Ramanarayanan, R. Ayer, R. Petkovic-Luton and D.P. Leta, Oxid. Met., 1988, 9, (5-6), 445.

    Article  Google Scholar 

  55. D. Nicolas-Chaubet, Thesis, University Paris XI, Orsay, 1989.

    Google Scholar 

  56. J.K. Doychak, T.E. Mitchell and J.L. Smialek, Mat. Res. Soc. Symp. Proc., 1985, 39, 475.

    Article  CAS  Google Scholar 

  57. J. Jedlinski and S. Mrowec, Mat. Sci. and Eng., 1987, 87, 281.

    Article  CAS  Google Scholar 

  58. G. Tremouilles, Doctor Thesis, University Paris VI, France, 1988, and G. Termouilles, J.L. Derep and R. Portier, Advances in Thermal Spraying, ITCS’86, Pergamon 1986, 465.

    Google Scholar 

  59. J.D. Cawley, and J.W. Halloran, J. Amer. Cer. Soc., 1986, 69 (8), C 195–196.

    Article  Google Scholar 

  60. G. Petot-Ervas, D. Deweirder, M. Loudjani, B. Lesage and A.M. Huntz, Advances in Ceramics, 1987, 23, 125.

    CAS  Google Scholar 

  61. I.A. Bondar, Izv. Akad. Nauk. SSSR, Neorg. Mat., 1984, 20 (2), 257.

    CAS  Google Scholar 

  62. D. Bouchet, University Paris XI, Orsay, private communication.

    Google Scholar 

  63. D. Prot, B. Lesage, C. Monty and A.M. Huntz, unpublished work.

    Google Scholar 

  64. K.P.R. Reddy, J.L. Smialek and A.R. Cooper, Oxid. Met., 1982, 17 (5-6), 429.

    Article  CAS  Google Scholar 

  65. T.A. Ramanarayanan, M. Rachavan and R. Petkovic-Luton, Oxid. Met., 1984, 22 (3-4), 83, and J. Electrochem. Soc., 1984, 131 (4), 923.

    Google Scholar 

  66. E.W.A. Young and J.H.W. De Wit, Solid State Ionics, 1985, 16, 39 and Oxid. Met., 1986, 26, 351.

    Google Scholar 

  67. M.J. Bennet and D.P. Moon, this conference.

    Google Scholar 

  68. M.M. El Aiat and F.A. Kroger, J. Am. Ceram. Soc., 1982, 65 (6), 280.

    Article  Google Scholar 

  69. G.J. Dienes, D.O. Welch, C.R. Fisher, R.D. Hatcher, D. Lazareth and M. Samberg, Phys. Rev., 1975, B11 (8), 3060.

    Google Scholar 

  70. S. Lartigue, Doctor Thesis, University Paris XI, Orsay, France, 1988 and Phys. Rev., 1975, B11 (8), 3060.

    Google Scholar 

  71. M.H. Lagrange, A.M. Huntz and J.Y. Laval, Ann. Chim. Fr., 1987, 12, 9.

    CAS  Google Scholar 

  72. A.M. Huntz, G. Moulin and B. Lesage, Proc. 9th ICMC, Toronto, June 3-7, 1984, voll II, National Research Council of Canada, Toronto, 1984, 400.

    Google Scholar 

  73. A.E. Paladino and W.D. Kingery, J. Chem. Phys., 1962, 37 (5), 957.

    Article  CAS  Google Scholar 

  74. Y. Oishi and W.D. Kingery, J. Chem. Phys., 1960, 33 (2), 480.

    Article  CAS  Google Scholar 

  75. F.A. Kroger, Solid State Ionics, 1984, 12, 189.

    Article  Google Scholar 

  76. A. Atkinson, this conference.

    Google Scholar 

  77. J. Nowok, Oxid. Met., 1982, 18 (1-2), 1.

    Article  CAS  Google Scholar 

  78. J. Castaing, this conference.

    Google Scholar 

  79. C. Carry and A. Mocellin, Ceramics International, 1987, 13, 89.

    Article  CAS  Google Scholar 

  80. A.M. Huntz et al., Mat. Sci. and Techn., 1988, 4 (5), 470 and 1988, 4 (12), 1079.

    Google Scholar 

  81. D. Delaunay, A.M. Huntz and P. Lacombe, Corr. Sci., 1980, 20, 1109.

    Article  CAS  Google Scholar 

  82. K.L. Luthra and C.L. Briant, Oxid. Met., 1986, 26 (5-6), 397.

    Article  CAS  Google Scholar 

  83. R.M. Cannon, W.H. Rhodes and A.H. Heuer, J. Am. Ceram. Soc., 1980, 63, 46.

    Article  CAS  Google Scholar 

  84. M.I. Manning, in: Corrosion and Mechanical Stress at High Temperature, eds. V. Guttman and M. Merz, Applied Science Publishers Ltd., London, 1981, 323.

    Google Scholar 

  85. J.D. Cawley, J.W. Halloran and A.R. Cooper, NASA T.M. 83622, 1984.

    Google Scholar 

  86. W.D. Kingery, D.C. Hill and R.P. Nelson, J. Amer. Cer. Soc., 1960, 43, 473.

    Article  CAS  Google Scholar 

  87. Y. Oishi, H. Koizumi, Y. Sakka and K. Ando, J. Met. Sc. Letter, 1985, 4 (2), 176.

    Article  Google Scholar 

  88. H. Haneda, Y. Miyasawa and S. Shirasaki, J. of Crystal Growth, 1984, 68 (2), 581.

    Article  CAS  Google Scholar 

  89. M.F. Berard, J. Amer. Cer. Soc., 1968, 51_, 648.

    Article  Google Scholar 

  90. M.F. Berard, J. Amer. Cer. Soc., 1967, 50, 113.

    Article  Google Scholar 

  91. K. Ando, J. Amer. Cer. Soc., 1983, 66, C–222.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Métallurgie Structurale, ISMA, CNRS UA, 1107, Université Paris XI, 91405, Orsay Cedex, France

    A. M. Huntz

Authors
  1. A. M. Huntz
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. CEC Joint Research Centre, Institute of Advanced Materials, Petten, The Netherlands

    E. Lang

Rights and permissions

Reprints and permissions

Copyright information

© 1989 ECSC, EEC, EAEC. Brussels and Luxembourg

About this chapter

Cite this chapter

Huntz, A.M. (1989). Effect of Active Elements on the Oxidation Behaviour of Al2O3-Formers. In: Lang, E. (eds) The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1147-5_7

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-1147-5_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7009-6

  • Online ISBN: 978-94-009-1147-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation