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Photophysical Properties of Three-Dimensional Transition Metal Tris-Oxalate Network Structures

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Transition Metal and Rare Earth Compounds

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 241))

Abstract

Excitation energy transfer processes play an important role in many areas of physics, chemistry and biology. The three-dimensional oxalate networks of composition [MIII(bpy)3][MIM′III(ox)3]ClO4 (bpy=2,2′-bipyridine, ox=oxalate, MI=alkali ion) allow for a variety of combinations of different transition metal ions. The combination with chromium(III) on both the tris-bipyridine as well as the tris-oxalate site constitutes a model system in which it is possible to differentiate unambiguously between energy transfer from [Cr(ox)3]3− to [Cr(bpy)3]3+ due to dipole-dipole interaction on the one hand and exchange interaction on the other hand. Furthermore it is possible to just as unambiguously differentiate between the common temperature dependent phonon-assisted energy migration within the 2E state of [Cr(ox)3]3−, and a unique resonant process.

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Acknowledgements

We thank N. Amstutz for the synthesis of the samples used in this study, and S. Decurtins and his co-workers for their help with the determination of the concentrations of donors and acceptors in the mixed crystals. We thank H. Riesen for helpful discussion in particular on the topic of FLN spectroscopy and spectral hole burning. Figure 3b is by courtesy of S. Decurtins. This work was financially supported by the Swiss National Science Foundation and NFP47.

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  1. Département de Chimie Physique, Université de Genève, Bâtiment de Science II, 30 quai Ernest Ansermet, 1211, Genève 4, Switzerland

    Andreas Hauser, Marianne E. von Arx, Vaughan S. Langford, Ueli Oetliker, Selim Kairouani & Anne Pillonnet

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  1. Andreas Hauser
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  2. Marianne E. von Arx
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  3. Vaughan S. Langford
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Correspondence to Andreas Hauser .

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Hauser, A., von Arx, M.E., Langford, V.S., Oetliker, U., Kairouani, S., Pillonnet, A. Photophysical Properties of Three-Dimensional Transition Metal Tris-Oxalate Network Structures. In: Transition Metal and Rare Earth Compounds. Topics in Current Chemistry, vol 241. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b96860

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  • DOI: https://doi.org/10.1007/b96860

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-20948-5

  • Online ISBN: 978-3-540-39904-9

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