Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 293))

  • 126 Accesses

Abstract

It is important to understand the effect of molybdenum on the nitrided ferritic stainless steels as it enhances the interstitial diffusion of nitrogen in the ferrite matrix by controlling the precipitation of chromium nitrides and thus minimizes the amount of chromium depletion present in the stainless steels. In this study, Fe–16 wt%Cr–1 wt%Mo, and Fe–16 wt%Cr–2wt%Mo alloys, representative of certain ferritic stainless-steel compositions are prepared via powder metallurgy process route (mechanical alloying followed by compaction and sintering). These specimens are salt bath nitrided at 480 °C for a nitriding time period of 4 h. The phase transformations at the nitrided surfaces were investigated by XRD investigations. The hardness of these nitrided Fe–16%Cr–1%Mo and Fe–16%Cr–2%Mo alloys is measured using a Vickers hardness setup and compared with un-nitrided samples. It is found that an increase in molybdenum content enhanced the surface hardness of these nitrided alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 139.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 129.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Free ship** worldwide - see info
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. German, R.M.: Powder Metallurgy Science. Metal Powder Industries Federation, Princeton, NJ, USA (1994)

    Google Scholar 

  2. Kaysser, W.A., Petzow, G.: Present state of liquid phase sintering. Powder Metall. 28(3), 145–150 (1985)

    Google Scholar 

  3. Bergman, O., Lindqvist, B., Bengtsson, S.: Influence of sintering parameters on the mechanical performance of PM steels pre-alloyed with chromium. In: Materials Science Forum, vol. 534, pp. 545–548. Trans Tech Publications Ltd, (2007)

    Google Scholar 

  4. Bergman, O.: Effects of Nitrogen Uptake during Sintering on the Properties of PM Steels Prealloyed with Chromium (2001)

    Google Scholar 

  5. Chauhan, S., Verma, V., Prakash, U., Tewari, P.C., Khanduja D.: Studies on induction hardening of powder-metallurgy-processed Fe–Cr/Mo alloys. Int. J. Miner., Metall., Mater. 24(8), 918–925 (2017)

    Google Scholar 

  6. Marcu, T., Molinari, A., Straffelini, G., Berg, S.: Microstructure and tensile properties of 3%Cr–0.5%Mo high carbon PM sintered steels, Powder Metall. 48(2), 139 (2005)

    Google Scholar 

  7. Mozetič, M.: Surface modification to improve properties of materials. Materials 12(3), 441 (2019)

    Google Scholar 

  8. Czerwinski, F.: Thermochemical treatment of metals. Heat Treatment–Conventional Nov. Appl. 26(5), 73–112 (2012)

    Google Scholar 

  9. Mittemeijer, E.J., Marcel Somers, A.J.: Thermochemical Surface Engineering of Steels. Woodhead Publishing, Cambridge (2014)

    Google Scholar 

  10. Natarajan, S.: Thermochemical Surface Engineering of Steels, pp. 875–878 (2015)

    Google Scholar 

  11. Suryanarayana, C: Bibliography on Mechanical Alloying and Milling. Cambridge International Science Publishing (1995)

    Google Scholar 

  12. Park, J., Jeong, G., Kang, S., Lee, S.-J., Choi, H.: Fabrication of Fe–Cr–Mo powder metallurgy steel via a mechanical-alloying process. Met. Mater. Int. 21(6), 1031–1037 (2015)

    Article  Google Scholar 

  13. Kumar, N., Chaudhari, G.P., Meka, S.R.: Investigation of low-temperature liquid nitriding conditions for 316 stainless steel for improved mechanical and corrosion response. Trans. Indian Inst. Metals 73(1), 235–42 (2020)

    Google Scholar 

  14. JCPDS. PDF-2 Database, Version 2.1. International Center for Diffraction Data (2002)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Subrahmanyam .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Subrahmanyam, S., Pardhasaradhi, D.V.T., Savanth, T., Kumar, R.S. (2023). Influence of Molybdenum on Nitride Strengthening of Fe–Cr–Mo Alloys. In: Tewari, A., Dhawan, N., Agarwal, G., Das, S., Mishra, S., Karmakar, A. (eds) Proceedings of the 3rd International Conference on Advances in Materials Processing: Challenges and Opportunities. AMPCO 2022. Springer Proceedings in Physics, vol 293. Springer, Singapore. https://doi.org/10.1007/978-981-99-1971-0_12

Download citation

Publish with us

Policies and ethics

Navigation