Organic Electrochemical Transistor

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Introduction to Organic Electronic Devices
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Abstract

Organic thin-film transistors (OTFTs) can generally be classified into two types: organic field effect transistors (OFET) and organic electrochemical transistors (OECT). Although both types of devices have been demonstrated for circuit and sensor applications (Brown et al. in Science 270:972–974, 1995; Schwartz et al. in Nat Commun 4:1859, 2013; Burgt et al. in Nat Mater 16:414–419, 2017; Khodagholy et al. in Nat Commun 4:2133, 2013), their research priorities are very different.

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References

  1. Brown AR, Pomp A, Hart CM, de Leeuw DM (1995) Logic gates made from polymer transistors and their use in ring oscillators. Science 270:972–974

    Article  ADS  Google Scholar 

  2. Schwartz G, Tee BCK, Mei J, Appleton AL, Kim DH, Wang H, Bao Z (2013) Flexible polymer transistors with high pressure sensitivity for application in electronic skin and health monitoring. Nat Commun 4:1859

    Article  ADS  Google Scholar 

  3. van de Burgt Y, Lubberman E, Fuller EJ, Keene ST, Faria GC, Agarwal S, Marinella MJ, Talin AA, Salleo A (2017) A non-volatile organic electrochemical device as a low-voltage artificial synapse for neuromorphic computing. Nat Mater 16:414–419

    Article  ADS  Google Scholar 

  4. Khodagholy D, Rivnay J, Sessolo M, Gurfinkel M, Leleux P, Jimison LH, Stavrinidou E, Herve T, Sanaur S, Owens RM, Malliaras GG (2013) High transconductance organic electrochemical transistors. Nat Commun 4:2133

    Article  ADS  Google Scholar 

  5. Gelinck G, Heremans P, Nomoto K, Anthopoulos TD (2010) Organic transistors in optical displays and microelectronic applications. Adv Mater 22:3778–3798

    Article  Google Scholar 

  6. Cantatore E, Geuns TCT, Gelinck GH, van Veenendaal E, Gruijthuijsen AFA, Schrijnemakers L, Drews S, de Leeuw DM (2007) A 13.56-MHz RFID system based on organic transponders. IEEE J Solid State Circuits 42:84–92

    Article  ADS  Google Scholar 

  7. Khodagholy D, Doublet T, Quilichini P, Gurfinkel M, Leleux P, Ghestem A, Ismailova E, Herve T, Sanaur S, Bernard C, Malliaras GG (2013) In vivo recordings of brain activity using organic transistors. Nat Commun 10:1038

    Google Scholar 

  8. White HS, Kittlesen GP, Wrighton MS (1984) Chemical derivatization of an array of three gold microelectrodes with polypyrrole: fabrication of a molecule-based transistor. J Am Chem Soc 106:5375–5377

    Article  Google Scholar 

  9. Bernards DA, Malliaras GG (2007) Steady-state and transient behavior of organic electrochemical transistors. Adv Funct Mater 17:3538–3544

    Article  Google Scholar 

  10. Bernards DA, Macaya DJ, Nikolou M, DeFranco JA, Takamatsu S, Malliaras GG (2008) Enzymatic sensing with organic electrochemical transistors. J Mater Chem 18:116–120

    Article  Google Scholar 

  11. Lin P, Yan F, Chan HLW (2010) Ion-sensitive properties of organic electrochemical transistors. ACS Appl Mater Interfaces 2:1637–1641

    Article  Google Scholar 

  12. Lin P, Yan F, Yu JJ, Chan HLW, Yang M (2010) The application of organic electrochemical transistors in cell-based biosensors. Adv Mater 22:3655–3660

    Article  ADS  Google Scholar 

  13. Lin P, Luo X, Hsing IM, Yan F (2011) Organic electrochemical transistors integrated in flexible microfluidic systems and used for label-free DNA sensing. Adv Mater 23:4035–4040

    Article  Google Scholar 

  14. Wang N, Yang A, Fu Y, Li Y, Yan F (2019) Functional organic thin film transistors for biosensing. Acc Chem Res 52:277–287

    Article  Google Scholar 

  15. He RX, Zhang M, Tan F, Leung PHM, Zhao XZ, Chan HLW, Yang M, Yan F (2012) Detection of bacteria with organic electrochemical transistors. J Mater Chem 22:22072–22076

    Article  Google Scholar 

  16. Khodagholy D, Curto VF, Fraser KJ, Gurfinkel M, Byrne R, Diamond D, Malliaras GG, Benito-Lopez F, Owens RM (2012) Organic electrochemical transistor incorporating an ionogel as a solid-state electrolyte for lactate sensing. J Mater Chem 22:4440–4443

    Article  Google Scholar 

  17. Fu Y, Wang N, Yang A, Law H, Li L, Yan F (2017) Highly sensitive detection of protein biomarkers with organic electrochemical transistors. Adv Mater 29:1703787

    Article  Google Scholar 

  18. Paul EW, Ricco AJ, Wrighton MS (1985) Resistance of polyaniline films as a function of electrochemical potential and the fabrication of polyaniline-based microelectronic devices. J Phys Chem 89:1441–1447

    Article  Google Scholar 

  19. Thackeray JW, Wrighton MS (1986) Chemically responsive microelectrochemical devices based on platinized poly(3-methylthiophene): Variation in conductivity with variation in hydrogen, oxygen, or pH in aqueous solution. J Phys Chem 90:6674–6679

    Article  Google Scholar 

  20. Scheiblin G, Coppard R, Owens RM, Mailley P, Malliaras GG (2017) Referenceless pH sensor using organic electrochemical transistors. Adv Mater Technol 2:1600141

    Article  Google Scholar 

  21. Dabke RB, Singh GD, Dhanabalan A, Lal R, Contractor AQ (1997) An ion-activated molecular electronic device. Anal Chem 69:724–727

    Article  Google Scholar 

  22. Mousavi Z, Ekholm A, Bobacka J, Ivaska A (2009) Ion-selective organic electrochemical junction transistors based on poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate). Electroanalysis 21:472–479

    Article  Google Scholar 

  23. Bernards DA, Malliaras GG, Toombes GES, Gruner SM (2006) Gating of an organic transistor through a bilayer lipid membrane with ion channels. Appl Phys Lett 89:053505

    Article  ADS  Google Scholar 

  24. Chao SH, Wrighton MS (1987) Characterization of a “solid-state” polyaniline based transistor: water vapor dependent characteristics of a device employing a poly(vinyl alcohol)/phosphoric acid solid-state electrolyte. J Am Chem Soc 109:6627–6631

    Article  Google Scholar 

  25. Nilsson D, Kugler T, Svensson PO, Berggren M (2002) An all-organic sensor transistor based on a novel electrochemical transducer concept printed electrochemical sensors on paper. Sens Actuators B Chem 86:193–197

    Article  Google Scholar 

  26. Hoa DT, Kumar TNS, Punekar NS, Srinivasa RS, Lal R, Contractor AQ (1992) Biosensor based on conducting polymers. Anal Chem 64:2645–2646

    Article  Google Scholar 

  27. Bartlett PN, Birkin PR (1993) Enzyme switch responsive to glucose. Anal Chem 65:1118–1119

    Article  Google Scholar 

  28. Zhu ZT, Mabeck JT, Zhu CC, Cady NC, Batt CA, Malliaras GG (2004) A simple poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonic acid) transistor for glucose sensing at neutral pH. Chem Commun 1556–1557

    Google Scholar 

  29. Macaya DJ, Nikolou M, Takamatsu S, Mabeck JT, Owens RM, Malliaras GG (2007) Simple glucose sensors with micromolar sensitivity based on organic electrochemical transistors. Sens Actuators B Chem 123:374–378

    Article  Google Scholar 

  30. Kanungo M, Srivastava DN, Kumar A, Contractor AQ (2002) Conductimetric immunosensor based on poly(3,4-ethylenedioxythiophene). Chem Commun 680–681

    Google Scholar 

  31. Kim DJ, Lee NE, Park JS, Park IJ, Kim JG, Cho HJ (2010) Organic electrochemical transistor based immunosensor for prostate specific antigen (PSA) detection using gold nanoparticles for signal amplification. Biosens Bioelectron 25:2477–2482

    Article  Google Scholar 

  32. Krishnamoorthy K, Gokhale RS, Contractor AQ, Kumar A (2004) Novel labelfree DNA sensors based on poly(3,4-ethylenedioxythiophene). Chem Commun 820–821

    Google Scholar 

  33. Tang H, Lin P, Chan HL, Yan F (2011) Highly sensitive dopamine biosensors based on organic electrochemical transistors. Biosens Bioelectron 26:4559–4563

    Article  Google Scholar 

  34. Campana A, Cramer T, Simon DT, Berggren M, Biscarini F (2014) Electrocardiographic recording with conformable organic electrochemical transistor fabricated on resorbable bio-scaffold. Adv Mater 26:3874–3878

    Article  Google Scholar 

  35. Danober L, Deransart C, Depaulis A, Vergnes M, Marescaux C (1998) Pathophysiological mechanisms of genetic absence epilepsy in the rat. Prog Neurobiol 55:27–57

    Article  Google Scholar 

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Correspondence to Guangye Zhang .

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Zhang, G., **e, C., You, P., Li, S. (2022). Organic Electrochemical Transistor. In: Introduction to Organic Electronic Devices . Springer, Singapore. https://doi.org/10.1007/978-981-19-6091-8_7

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