Abstract
The content of chlorobenzene in graphene was determined by gas chromatography mass spectrometry. The four methods of solvent soaking method, Soxhlet extraction method, ultrasonic method, ultrasonic solvent soaking method and the extraction effect of the extraction parameters on the content of chlorobenzene in graphene were investigated respectively. The results show that the ratio of solvent to graphene is 30:1. The method of immersing in solvent for 1 h after ultrasonic for 8 min can achieve the maximum extraction of graphene chlorobenzene by repeating twice. The influence of the type of chromatographic column, the temperature of the column oven and the split ratio on the test results were investigated. The results showed that the best effect is when the column oven temperature is 100 ℃ and the split ratio is 10:1. The spiked recovery rate of the method is between 93.4 and 107.3%, the repeatability is 5.6%, the stability is 9.3%, the method detection limit is 0.00048%, and the sample detection limit is 0.015%. It can be used for trace chlorine in graphene. Accurate determination of benzene.
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Lu, Y., Guo, G., You, X., Wu, L., Xun, Q., Liu, X. (2022). Determination of Chlorobenzene in Graphene by Gas Chromatography Mass Spectrometry. In: Gany, A., Fu, X. (eds) 2021 International Conference on Development and Application of Carbon Nanomaterials in Energetic Materials. ICCN 2021. Springer Proceedings in Physics, vol 276. Springer, Singapore. https://doi.org/10.1007/978-981-19-1774-5_38
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DOI: https://doi.org/10.1007/978-981-19-1774-5_38
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