Abstract
A new generation of smart coating contain nano capsule that actively respond to changes in the local environment has triggered great interest among material researchers in the field of anti-corrosion. Many researchers reported that the preparation of pH-responsive nano capsules is usually applying unfriendly chemicals, a complex procedure and time-consuming, which remains as a great challenge for effective corrosion protections. This review presents, the achievement during the last 10 years in the field of pH-responsive nano-capsules, the formulation technique of such nano-capsule, testing and evaluation of the pH-responsive nano-capsule.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Ou B, Wang Y, Lu Y (2021) A review on fundamentals and strategy of epoxy-resin-based anticorrosive coating materials. Polymer-Plastics Technol Mater 60(6):601–625
Zhang C, Wang H, Zhou Q (2018) Preparation and characterization of microcapsules based self-healing coatings containing epoxy ester as healing agent. Prog Org Coat 125:403–410
da Cunha ABM, Leal DA, Santos LRL, Riegel-Vidotti IC, Marino CEB (2020) pH-sensitive microcapsules based on biopolymers for active corrosion protection of carbon steel at different pH. Surf Coat Technol 402
Chen L, Yu Z, Yin D, Cao K (2021) Preparation and anticorrosion properties of BTA@HNTs-GO nanocomposite smart coatings. Compos Interfaces 28(1):1–16
Zhou C et al (2020) Epoxy composite coating with excellent anticorrosion and self-healing performances based on multifunctional zeolitic imidazolate framework derived nanocontainers. Chem Eng J 385
Hao X et al (2020) Antifouling and antibacterial behaviors of capsaicin-based pH responsive smart coatings in marine environments. Mater Sci Eng C 108
Ress J, Martin U, Bosch J, Bastidas DM (2021) Protection of carbon steel rebars by epoxy coating with smart environmentally friendly microcapsules. Coatings 11(20):1–12
**e ZH, Shan S (2018) Nanocontainers-enhanced self-healing Ni coating for corrosion protection of Mg alloy. J Mater Sci 53(5):3744–3755
Siva T, Sathiyanarayanan S (2015) Self healing coatings containing dual active agent loaded urea formaldehyde (UF) microcapsules. Prog Org Coat 82:57–67
Sun D, An J, Wu G, Yang J (2015) Double-layered reactive microcapsules with excellent thermal and non-polar solvent resistance for self-healing coatings. J Mater Chem A, 3(8):4435–4444
Cai H, Wang P, Zhang D (2020) Smart anticorrosion coating based on stimuli-responsive micro/nanocontainer: a review. J Oceanol Limnol 38(4):1045–1063
Wang J et al (2021) A CO2-responsive anti-corrosion ethyl cellulose coating based on the pH-response mechanism. Corros Sci 180
Ni X, Gao Y, Zhang X, Lei Y, Sun G, You B (2021) An eco-friendly smart self-healing coating with NIR and pH dual-responsive superhydrophobic properties based on biomimetic stimuli-responsive mesoporous polydopamine microspheres. Chem Eng J 406
Wang W et al (2018) pH-responsive Capsaicin@chitosan nanocapsules for antibiofouling in marine applications. Polymer 158:223–230
Koochaki MS, Khorasani SN, Neisiany RE, Ashrafi A, Trasatti SP, Magni M (2021) A highly responsive healing agent for the autonomous repair of anti-corrosion coatings on wet surfaces. In operando assessment of the self-healing process. J Mater Sci 56(2):1794–1813
Yang YJ, Yaakob SM, Rabat NE, Shamsuddin MR, Man Z (2020) Release kinetics study and anti-corrosion behaviour of a pH-responsive ionic liquid-loaded halloysite nanotube-doped epoxy coating. RSC Adv 10(22):13174–13184
Li J, Zeng H, Luo JL (2021) Probing the corrosion resistance of a smart electroless Ni-P composite coating embedded with pH-responsive corrosion inhibitor-loaded nanocapsules. Chem Eng J 421
Miras J, Liu C, Blomberg E, Thormann E, Vílchez S, Esquena J (2021) pH-responsive chitosan nanofilms crosslinked with genipin. Colloids Surf A Physicochemical Eng Aspects 616
Liang Y et al (2016) Facile synthesis of smart nanocontainers as key components for construction of self-healing coating with superhydrophobic surfaces. Nanoscale Res Lett 11(1)
Taryba M et al (2011) The combined use of scanning vibrating electrode technique and micro-potentiometry to assess the self-repair processes in defects on ‘smart’ coatings applied to galvanized steel. Electrochimica Acta 56(12):4475–4488
Fu J et al (2013) Acid and alkaline dual stimuli-responsive mechanized hollow mesoporous silica nanoparticles as smart nanocontainers for intelligent anticorrosion coatings. ACS Nano 7(12):11397–11408
Manoj A, Ramachandran R, Menezes PL (2020) Self-healing and superhydrophobic coatings for corrosion inhibition and protection. Int J Adv Manuf Technol 106(5–6):2119–2131
Ouyang Y, Li LX, **e ZH, Tang L, Wang F, Zhong CJ A self-healing coating based on facile pH-responsive nanocontainers for corrosion protection of magnesium alloy. J Magnes Alloys
Sun M, Yerokhin A, Bychkova MY, Shtansky DV, Levashov EA, Matthews A (2020) Self-healing plasma electrolytic oxidation coatings doped with benzotriazole loaded halloysite nanotubes on AM50 magnesium alloy. Corros Sci 111:753–769
He Y, Xu W, Tang R, Zhang C, Yang Q (2015) PH-Responsive nanovalves based on encapsulated halloysite for the controlled release of a corrosion inhibitor in epoxy coating. RSC Adv 5(110):90609–90620
Shahini MH, Taheri N, Mohammadloo HE, Ramezanzadeh B (2021) A comprehensive overview of nano and micro carriers aiming at curtailing corrosion progression. J Taiwan Inst Chem Eng. Taiwan Institute of Chemical Engineers
Leal DA, Riegel-Vidotti IC, Ferreira MGS, Marino CEB (2018) Smart coating based on double stimuli-responsive microcapsules containing linseed oil and benzotriazole for active corrosion protection. Corros Sci 130:56–63
**ng X, Wang J, Li Q, Hu W, Yuan J (2018) A novel acid-responsive HNTs-based corrosion inhibitor for protection of carbon steel. Colloids Surf A Physicochemical Eng Aspects 553:295–304
**ng X et al (2020) A novel method to control the release rate of halloysite encapsulated Na2MoO4 with Ca2+ and corrosion resistance for Q235 steel. Appl Clay Sci 188
Jia Y, Qiu T, Guo L, Ye J, He L, Li X (2020) Preparation of pH responsive smart nanocontainer via inclusion of inhibitor in graphene/halloysite nanotubes and its application in intelligent anticorrosion protection. Appl Surf Sci 504
Falcón JM, Otubo LM, Aoki IV (2016) Highly ordered mesoporous silica loaded with dodecylamine for smart anticorrosion coatings. Surf Coat Technol 303(Part B):319–329
Alizadeh M, Sarabi AA (2019) pH-Responsive MFPTT microcapsules containing dimethyl sulfoxide: preparation, characterization and tuning the release behavior of microcapsule contents. Prog Org Coat 134:78–90
Khan A, Hassanein A, Habib S, Nawaz M, Shakoor RA, Kahraman R (2020) Hybrid Halloysite Nanotubes as Smart Carriers for Corrosion Protection. ACS Appl Mater Interfaces 12(33):37571–37584
Falcón JM, Sawczen T, Aoki IV (2015) Dodecylamine-loaded halloysite nanocontainers for active anticorrosion coatings. Front Mater 2
Saremi M, Yeganeh M (2014) Application of mesoporous silica nanocontainers as smart host of corrosion inhibitor in polypyrrole coatings. Corros Sci 86:159–170
Acknowledgements
The authors would like to acknowledge the Ministry of Higher Education for providing financial support under Fundamental Research Grant Scheme (FRGS) No. FRGS/1/2019/TK05/UMP/02/5 (University reference RDU1901128) and University Malaysia Pahang for laboratory facilities as well as additional financial support under Internal Research grant PGRS210373.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Mohamed, N.S., Alias, J., Johari, N.A., Zanurin, A. (2023). pH-Responsive Nanocapsules as Smart Coating for Corrosion Protection: A Review. In: Ismail, M.Y., Mohd Sani, M.S., Kumarasamy, S., Hamidi, M.A., Shaari, M.S. (eds) Technological Advancement in Mechanical and Automotive Engineering. ICMER 2021. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-19-1457-7_26
Download citation
DOI: https://doi.org/10.1007/978-981-19-1457-7_26
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-19-1456-0
Online ISBN: 978-981-19-1457-7
eBook Packages: EngineeringEngineering (R0)