Abstract
In this chapter, we introduce recent progress on cyclic polymer synthesis using chain polymerization techniques including controlled radical polymerizations of vinyl monomers combined with click chemistries as well as metathesis polymerization of cyclic olefins or several alkynes. In order to eliminate highly diluted conditions ([M]0 < 1.0 mM) for the ring-closure, supra chemistries including electrostatic self-assembly and rotaxane are practical. We introduce our original procedure, N-heterocyclic carbene-initiated anionic polymerization of vinyl monomers and subsequent ring-closing, in which we do not have to use highly diluted condition ([M]0 = 1.0–2.0 M).We introduce our original procedure, N-heterocyclic carbene-initiated anionic polymerization of vinyl monomers and subsequent ring-closing, in which we do not have to use highly diluted condition ([M]0 = 1.0–2.0 M).
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Muramatsu, Y., Takasu, A. (2022). Synthesis of Cyclic Vinyl Polymers via N-Heterocyclic Carbene (NHC)-Initiated Anionic Polymerization and Subsequent Ring-Closure Without Highly Dilute Conditions. In: Tezuka, Y., Deguchi, T. (eds) Topological Polymer Chemistry. Springer, Singapore. https://doi.org/10.1007/978-981-16-6807-4_17
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