Abstract
The comparison of the deep eutectic solvents (DESs) and ionic liquids (ILs) is presented in this chapter. DESs have proved to be a good alternative to traditional organic solvents and ionic liquids (ILs) in many biocatalytic processes. DESs are preferred over conventional ILs because they are easy to synthesize, stable, cost-competitive and typically most of them are environment friendly
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A.P. Abbott, G. Capper, D.L. Davies, R.K. Rasheed, V. Tambyrajah, Novel solvent properties of choline chloride/urea mixtures. Chem. Commun. 1, 70–71 (2003)
A.P. Abbott, D. Boothby, G. Capper, D.L. Davies, R.K. Rasheed, Deep Eutectic Solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids. J. Am. Chem. Soc. 126(29), 9142–9147 (2004)
A.P. Abbott, G. Capper, D.L. Davies, H.L. Munro, R.K. Rasheed, V. Tambyrajah, Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains. Chem. Commun. 19, 2010–2011 (2001)
I.M. Aroso, A. Paiva, R.L. Reis, A.R.C. Duarte, Natural deep eutectic solvents from choline chloride and betaine—Physicochemical properties. J. Mol. Liq. 241, 654–661 (2017)
Q.B. Cheng, L.W. Zhang, Highly efficient enzymatic preparation of daidzein in deep eutectic solvents. Molecules 22(1), 186 (2017)
Y.H. Choi, J. vanSpronsen, Y. Dai, M. Verberne, F. Hollmann, I.W.C.E. Arends, G.J. Witkamp, R. Verpoorte, Are natural deep eutectic solvents the missing link in understanding cellular metabolism and physiology? Plant Physiol. 156(4), 1701–1705 (2011)
C. Florindo, F.S. Oliveira, L.P.N. Rebelo, A.M. Fernandes, I.M. Marrucho, Insights into the synthesis and properties of deep eutectic solvents based on cholinium chloride and carboxylic acids. ACS Sustain. Chem. Eng. 2(10), 2416–2425 (2014)
M. Francisco, A.S.B. Gonzalez, S.L. Garcia de Dios, W. Weggemans, M.C. Kroon, Comparison of a low transition temperature mixture (LTTM) formed by lactic acid and choline chloride with choline lactate ionic liquid and the choline chloride salt: Physical properties and vapour-liquid equilibria of mixtures containing water and ethanol. RSC Adv. 3(45), 23553–23561 (2013)
R. Germani, M. Orlandini, M. Tiecco, T. Del Giacco, Novel low viscous, green and amphiphilic N-oxides/phenylacetic acid based Deep Eutectic Solvents. J. Mol. Liq. 240, 233–239 (2017)
M.C. Gutierrez, M.L. Ferrer, C.R. Mateo, F. del Monte, Freeze-drying of aqueous solutions of deep eutectic solvents: a suitable approach to deep eutectic suspensions of self-assembled structures. Langmuir 25(10), 5509–5515 (2009)
J.P. Hallett, T. Welton, Room-temperature ionic liquids: solvents for synthesis and catalysis. 2. Chem. Rev. 111(5), 3508–3576 (2011)
M. Hayyan, M.A. Hashim, M.A. Al-Saadi, A. Hayyan, I.M. AlNashef, M.E.S. Mirghani, Assessment of cytotoxicity and toxicity for phosphonium-based deep eutectic solvents. Chemosphere 93(2), 455–459 (2013). https://doi.org/10.1016/j.chemosphere.2013.05.013
M. Hayyan, M.A. Hashim, A. Hayyan, M.A. Al-Saadi, I.M. AlNashef, M.E.S. Mirghani, O.K. Saheed, Are deep eutectic solvents benign or toxic? Chemosphere 90(7), 2193–2195 (2013). https://doi.org/10.1016/j.chemosphere.2012.11.004
M. Hayyan, C.Y. Looi, A. Hayyan, W.F. Wong, M.A. Hashim, In vitro and in vivo toxicity profiling of ammonium-based deep eutectic solvents. PLoS ONE 10(2), e0117934 (2015). https://doi.org/10.1371/journal.pone.0117934
M. Hayyan, Y.P. Mbous, C.Y. Looi, W.F. Wong, A. Hayyan, Z. Salleh, O. Mohd-Ali, Natural deep eutectic solvents: cytotoxic profile. Springerplus 5, 913 (2016). https://doi.org/10.1186/s40064-016-2575-9
G. Imperato, E. Eibler, J. Niedermaier, B. König, Low-melting sugar-urea-salt mixtures as solvents for Diels-Alder reactions. Chem. Commun. 9, 1170–1172 (2005)
H.R. Jhong, D.S.H. Wong, C.C. Wan, Y.Y. Wang, T.C. Wei, A novel deep eutectic solvent-based ionic liquid used as electrolyte for dye-sensitized solar cells. Electrochem. Commun. 11(1), 209–211 (2009)
S.P. Kelley, A. Narita, J.D. Holbrey, K.D. Green, W.M. Reichert, R.D. Rogers, Understanding the effects of ionicity in salts, solvates, co-crystals, ionic co-crystals, and ionic liquids, rather than nomenclature, is critical to understanding their behavior. Cryst. Growth Des. 13(3), 965–975 (2013)
M. Krolikowska, M. Zawadzki, U. Domanska, D. Ramjugernath, P. Naidoo, The influence of temperature and composition on the density, viscosity and excess properties of aqueous mixtures of carboxylic-based ionic liquids. J. Chem. Thermodyn. 109, 71–81 (2017)
H. Lores, V. Romero, I. Costas, C. Bendicho, I. Lavilla, Natural deep eutectic solvents in combination with ultrasonic energy as a green approach for solubilisation of proteins: application to gluten determination by immunoassay. Talanta 162, 453–459 (2017)
Y.P. Mbous, M. Hayyan, W.F. Wong, C.Y. Looi, M.A. Hashim, Unraveling the cytotoxicity and metabolic pathways of binary natural deep eutectic solvent systems. Sci Rep 7, 41257 (2017). https://doi.org/10.1038/srep41257
M. Moghimi, A. Roosta, Physical properties of aqueous mixtures of (choline chloride + glucose) deep eutectic solvents. J. Chem. Thermodyn. 129(2019), 159–165 (2019)
J. PÅ‚otka-Wasylka, M. de la Guardia, V. Andruch, M. Vilkova, Deep eutectic solvents vs ionic liquids: similarities and differences. Microchem. J. 159, 105539 (2020)
W. Qian, J. Texter, F. Yan, Frontiers in poly(ionic liquid)s: syntheses and applications. Chem. Soc. Rev. 46(4), 1124–1159 (2017)
K. Radosevic, M.C. Bubalo, V.G. Srcek, D. Grgas, T.L. Dragicevic, I.R. Redovnikovic, Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents. Ecotoxicol. Environ. Saf. 112, 46–53 (2015). https://doi.org/10.1016/j.ecoenv.2014.09.034
T. Raj, R. Gaur, P. Dixit, R.P. Gupta, V. Kagdiyal, R. Kumar, D.K. Tuli, Ionic liquid pretreatment of biomass for sugars production: driving factors with a plausible mechanism for higher enzymatic digestibility. Carbohydr. Polym. 149, 369–381 (2016)
R. Ratti, Ionic liquids: synthesis and applications in catalysis. Adv. Chem. Ser. 2014, 729842 (2014)
B.D. Ribeiro, C. Florindo, L.C. Iff, M.A.Z. Coelho, I.M. Marrucho, Menthol-based eutectic mixtures: hydrophobic low viscosity solvents. ACS Sustain. Chem. Eng. 3(10), 2469–2477 (2015)
K.N. Ruckart, R.A. O’Brien, S.M. Woodard, K.N. West, T.G. Glover, Porous solids impregnated with task-specific ionic liquids as composite sorbents. J. Phys. Chem. C 119(35), 20681–20697 (2015)
A. Satlewal, R. Agrawal, S. Bhagia, J. Sangoro, A.J. Ragauskas, Natural deep eutectic solvents for lignocellulosic biomass pretreatment: recent developments, challenges and novel opportunities. Biotechnol. Adv. 36(8), 2032–2050 (2018)
S.K. Singh, A.W. Savoy, Ionic liquids synthesis and applications: an overview. J. Mol. Liq. 297, 112038 (2020)
S. Singh, G. Cheng, N. Sathitsuksanoh, D. Wu, P. Varanasi, A. George, V. Balan, X. Gao, R. Kumar, B.E. Dale, C.E. Wyman, B.A. Simmons, Comparison of different biomass pretreatment techniques and their impact on chemistry and structure. Front. Energy. Res. 2, 62 (2015)
E.L. Smith, A.P. Abbott, K.S. Ryder, Deep Eutectic Solvents (DESs) and their applications. Chem. Rev. 114(21), 11060–11082 (2014)
X. Tang, M. Zuo, Z. Li, H. Liu, C. **ong, X. Zeng, Y. Sun, L. Hu, S. Liu, T. Lei, L. Lin, Green processing of lignocellulosic biomass and its derivatives in deep eutectic solvents. Chemsuschem 10(13), 2696–2706 (2017)
D.J.G.P. van Osch, L.J.B.M. Kollau, A. van den Bruinhorst, S. Asikainen, M.A.A. Rocha, M.C. Kroon, Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation. PCCP 19(4), 2636–2665 (2017)
M. Vilková, J. Płotka-Wasylka, V. Andruch, The role of water in deep eutectic solvent-base extraction. J. Mol. Liq. 304, 112747 (2020)
P. Walden, Über die Molekulargr¨osse und elektrische Leitf¨ahigkeit einiger geschmolzener Salze. Bull. Acad. Imper. Sci. (st Petersburg) 8, 405–422 (1914)
P. Xu, G.W. Zheng, M.H. Zong, N. Li, W.Y. Lou, Recent progress on deep eutectic solvents in biocatalysis. Bioresour. Bioprocess. 4(1), 34 (2017)
X.H. Yao, D.Y. Zhang, M.H. Duan, Q. Cui, W.J. Xu, M. Luo, C.Y. Li, Y.G. Zu, Y.J. Fu, Preparation and determination of phenolic compounds from Pyrola incarnata Fisch. with a green polyols based-deep eutectic solvent. Sep. Purif. Technol. 149, 116–123 (2015)
C.G. Yoo, Y. Pu, A.J. Ragauskas, Ionic liquids: promising green solvents for lignocellulosic biomass utilization. Curr. Opin. Green. Sustain. Chem. 5, 5–11 (2017)
M. Zakrewsky, A. Banerjee, S. Apte, T.L. Kern, M.R. Jones, R.E. Del Sesto, A.T. Koppisch, D.T. Fox, S. Mitragotri, Choline and geranate deep eutectic solvent as a broad-spectrum antiseptic agent for preventive and therapeutic applications. Adv Healthc Mater. 5(11), 1282–1289 (2016)
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Bajpai, P. (2021). Comparison of Deep Eutectic Solvents and Ionic Liquids. In: Deep Eutectic Solvents for Pretreatment of Lignocellulosic Biomass. SpringerBriefs in Applied Sciences and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-16-4013-1_7
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