Structural and Optoelectronic Properties of Spin-Coated CH3NH3PbCl3 Thin Film Using Non-halide Source of Lead

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Electronic Systems and Intelligent Computing

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 686))

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Abstract

In recent times, methylammonium lead chloride (CH3NH3PbCl3) perovskites have great significance as the optoelectronic material. Besides all the promising advantages, there are some problems which need to be resolved, one of such problem is to synthesize well-crystalline, highly homogeneous and the less-defective surface of the perovskites by reducing the synthesis complexity. In this continual search of better properties, we have synthesized of CH3NH3PbCl3 film by replacing traditional halide source of lead with a non-halide source of lead. We have also analysed their structural, morphological and optical properties of the film using XRD, FEG-SEM and DRS UV-Vis spectroscopy techniques. The detailed study confirms the cubic structure of the as-prepared film without any contamination. Surface morphology shows the formation of homogeneous spherical particles with an average size of 0.165 µm. DRS UV-Vis data shows a wide bandgap of 3.7 eV and due to that high transparency in the visible region of light. These outcomes open up the door for CH3NH3PbCl3 film as a vital transparent conductor.

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References

  1. Wang Q, Lyu M, Zhang M, Yun J, Chen H, Wang L (2015) Transition from tetragonal to cubic phase of organohalide perovskite: The role of chlorine in crystal formation of CH3NH3PbI3 on TiO2 Substrates. J Phys Chem Lett 6:4379–4384

    Google Scholar 

  2. Maculan G, Sheikh AD, Abdelhady AL, Saidaminov MI, Haque MA, Murali B, Alarous E, Mohammed OF, Wu T, Bakr OM (2015) CH3NH3PbCl3 single crystals: inverse temperature crystallization and visible-blind UV-photodetector. J Phys Chem Lett 6:3781–3786

    Google Scholar 

  3. Tian Y, Ling Y, Shu Y, Zhou C, Besara T, Siegrist T, Gao H, Ma B (2016) A Solution-processed organometal halide perovskite hole transport layer for highly efficient organic light-emitting diodes. Adv Electron Mater 2:1600165

    Article  Google Scholar 

  4. Sarkar P, Tripathy SK, Baishnab KL, Palai G (2019) Structural, optoelectronic, and morphological study of indium‑doped methylammonium lead chloride perovskites. 125:580

    Google Scholar 

  5. Sarkar P, Mayengbam R, Tripathy SK, Baishnab KL (2019) Cubic methylammonium lead chloride perovskite as a transparent conductor in solar cell applications: an experimental and theoretical study. Ind J Pure Appl Phys 57:891–899

    Google Scholar 

  6. **ao Z, Dong Q, Bi C, Shao Y, Yuan Y, Huang J (2014) Solvent annealing of perovskite‐induced crystal growth for photovoltaic‐device efficiency enhancement. Adv Mater 26:6503–6509

    Google Scholar 

  7. Nie W, Tsai H, Asadpour R, Blancon JC, Neukirch AJ, Gupta G, Crochet JJ, Chhowalla M, Tretiak S, Alam MA, Wang HL (2015) High-efficiency solution-processed perovskite solar cells with millimeter-scale grains. Science 347:522–525(2015)

    Google Scholar 

  8. Mashiyama H, Kurihara Y, Azetsu T (1998) Disordered cubic perovskite structure of CH3NH3PbX3 (X=Cl, Br, I). J Kor Phys Soc 32:S156–S158

    Google Scholar 

  9. Zhang Z, Ren L, Yan H, Guo S, Wang S, Wang M, ** K (2017) Bandgap narrowing in bi-doped CH3NH3PbCl3 perovskite single crystals and thin films. J Phys Chem 121:17436–17441

    Google Scholar 

  10. Wakamiya A, Endo M, Sasamori T, Tokitoh N, Ogomi Y, Hayase S, Murata Y (2014) Reproducible fabrication of efficient perovskite-based solar cells: X-ray crystallographic studies on the formation of CH3NH3PbI3 layers. Chem Lett 43:711–713

    Google Scholar 

  11. Moore DT, Sai H, Tan KW, Smilgies DM, Zhang W, Snaith HJ, Wiesner U, Estroff LA (2015) Crystallization kinetics of organic–inorganic trihalide perovskites and the role of the lead anion in crystal growth. J Am Chem Soc 137:2350–2358

    Google Scholar 

  12. Zhang W, Saliba M, Moore DT, Pathak SK, Hörantner MT, Stergiopoulos T, Stranks SD, Eperon GE, Alexander-Webber JA, Abate A, Sadhanala A (2015) Ultrasmooth organic–inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells. Nat Commun 6:6142

    Article  Google Scholar 

  13. Forgács D, Sessolo M, Bolink HJ (2015) Lead acetate precursor based pin perovskite solar cells with enhanced reproducibility and low hysteresis. J Mater Chem A 3:14121–14125

    Google Scholar 

  14. Qing J Chandran HT, Xue HT, Guan ZQ, Liu TL, Tsang SW, Lo MF, Lee CS (2015) Simple fabrication of perovskite solar cells using lead acetate as lead source at low temperature. Org Electron 27:12–17

    Google Scholar 

  15. Zhao Q, Li GR, Song J, Zhao Y, Qiang Y, Gao XP (2016) Improving the photovoltaic performance of perovskite solar cells with acetate. Sci Rep 6:38670

    Article  Google Scholar 

  16. Shen C, Courté M, Krishna A, Tang S, Fichou D (2017) Quinoidal 2,2′,6,6′‐tetraphenyl‐dipyranylidene as a dopant‐free hole‐transport material for stable and cost‐effective perovskite solar cells. Energy Technol 5:1852–1858

    Google Scholar 

  17. Wolff CM, Zu F, Paulke A, Toro LP, Koch N, Neher D (2017) Reduced interface-mediated recombination for high open-circuit voltages in CH3NH3PbI3 solar cells. Adv Mater 29:1700159

    Article  Google Scholar 

  18. **ao M, Huang F, Huang W, Dkhissi Y, Zhu Y, Eheridge J, Gray-Weale A, Bach U, Cheng Y-B, Spiccia L (2014) A fast deposition-crystallization procedure for highly efficient lead iodide perovskite thin-film solar cells. Angew Chem Int Ed 53:9898–9903

    Article  Google Scholar 

  19. Liu Z, Lee E-C Solvent engineering of the electron transport layer using 1,8-diiodooctane for improving the performance of perovskite solar cells. Org Electron 24:101–105

    Google Scholar 

  20. You J, Yang YM, Hong Z, Song T-B, Meng L, Liu Y, Jiang C, Zhou H, Chang W-H, Li G, Yang Y (2014) Moisture assisted perovskite film growth for high performance solar cells. Appl Phys Lett 105:183902

    Article  Google Scholar 

  21. Qing J, Chandran H-T, Cheng Y-H, Liu X-K, Li H-W, Tsang S-W, Lo M-F, Lee C-S (2015) Chlorine incorporation for enhanced performance of planar perovskite solar cell based on lead acetate precursor. ACS Appl Mater Interfaces 7:23110–23116

    Google Scholar 

  22. Li C, Guo Q, Wang Z, Bai Y, Liu L, Wang F, Zhou E, Hayat T, Alsaedi A, Tan ZA (2017) Efficient planar structured perovskite solar cells with enhanced open-circuit voltage and suppressed charge recombination based on a slow grown perovskite layer from lead acetate precursor. ACS Appl Mater Interfaces 9:41937–41944

    Article  Google Scholar 

  23. Liu Y, Liu Z, Lee E-C (2018) Dimethyl-sulfoxide-assisted improvement in the crystallization of lead-acetate-based perovskites for high-performance solar cells. J Mater Chem C 6:6705–6713(2018)

    Google Scholar 

  24. Zhang Z, Zheng W, Lin R, Huang F (2018) High-sensitive and fast response to 255 nm deep-UV light of CH3NH3PbX3 (X=Cl, Br, I) bulk crystals. R Soc Open Sci 5:180905

    Article  Google Scholar 

  25. Hsu HP, Li LC, Shellaiah M, Sun KW (2019) Structural, photophysical, and electronic properties of CH3NH3PbCl3 single crystals. Sci Rep 9:13111

    Article  Google Scholar 

  26. Studenyak I, Kranjec M, Kurik M (2014) Urbach rule in solid state physics. Int J Opt Appl 4:76–83

    Google Scholar 

  27. Wang ZK, Li M, Yang YG, Hu Y, Ma H, Gao XY, Liao LS (2016) High efficiency Pb–In binary metal perovskite solar cells. Adv Mater 28:6695–6703

    Google Scholar 

  28. Nandi P, Giri C, Swain D, Manju U, Topwal D (2019) Room temperature growth of CH3NH3PbCl3 single crystals by solvent evaporation method. Cryst Eng Commun 21:656–661

    Article  Google Scholar 

  29. Zheng E, Yuh B, Tosado GA, Yu Q (2017) Solution-processed visible-blind UV-A photodetectors based on CH3NH3PbCl3 perovskite thin films. J Mater Chem C 5:3796–3806

    Article  Google Scholar 

  30. Zhang Z, Ren L, Yan H, Guo S, Wang S, Wang M, ** K (2017) Bandgap Narrowing in bi-doped CH3NH3PbCl3 perovskite single crystals and thin films. J Phys Chem C 121:17436–17441

    Article  Google Scholar 

  31. Tetsuka H, Shan YJ, Tezuka K, Imoto H, Wasa K (2005) Transparent conductive In-doped Cd3TeO6 thin films with perovskite structure deposited by radio frequency magnetron sputtering. J Mater Res 41:2256–2260

    Article  Google Scholar 

  32. Balachandran U, Odekirk B, Eror NG (1982) Electrical conductivity in calcium titanate. J Solid State Chem 41:185–194

    Article  Google Scholar 

  33. Piskunov S, Heifets E, Eglitis RI, Borstel G (2004) Bulk properties and electronic structure of SrTiO3, BaTiO3, PbTiO3 perovskites: an ab initio HF/DFT study. Comput Mater Sci 29:165–178

    Article  Google Scholar 

  34. Kumar A, Balasubramaniam KR, Kangsabanik J, Vikram, Alam A (2016) Crystal structure, stability, and optoelectronic properties of the organic-inorganic wide-band-gap perovskite CH3NH3BaI3: candidate for transparent conductor applications. Phys Rev 94:180105–180110

    Google Scholar 

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Acknowledgements

This work was supported by CSIR, New Delhi and ECR scheme (File No. ECR/2016/001404) of SERB, Government of India.

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Correspondence to Paramita Sarkar .

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Sarkar, P., Tripathy, S.K., Baishnab, K.L. (2020). Structural and Optoelectronic Properties of Spin-Coated CH3NH3PbCl3 Thin Film Using Non-halide Source of Lead. In: Mallick, P.K., Meher, P., Majumder, A., Das, S.K. (eds) Electronic Systems and Intelligent Computing. Lecture Notes in Electrical Engineering, vol 686. Springer, Singapore. https://doi.org/10.1007/978-981-15-7031-5_88

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  • DOI: https://doi.org/10.1007/978-981-15-7031-5_88

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