Abstract
In this work, Ba0.9Er0.1TiO3 thin films have been synthesized on SiO2/Si substrate using solgel method. The effect of annealing temperature on crystalline structure and surface morphology of the films has been studied via X-ray diffraction (XRD) and atomic force microscopy (AFM). XRD patterns reveal the crystalline structure with tetragonal phase for the films annealed at 700 °C and above. The lattice volume shows an increasing trend for the fabricated thin films with the increased annealing temperature. On the other hand, grain size obtained via AFM micrographs is increased along the increased annealing temperature which forms a larger grain during its crystallization process. The larger grain formation could be a better contribution to the alteration of other properties, but the formation of the immediate or secondary phases at 720 °C and above could also deteriorate the device performance. Among the samples, Ba0.9Er0.1TiO3 thin film that annealed at 700 °C shows the phase-pure crystalline BaTiO3 structure with no other phases, suggesting that 700 °C is the optimum annealing temperature for this type of material in our case.
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References
Chen, L., Liang, X., Long, Z., & Wei, X. (2012a). Upconversion photoluminescence properties of Er3+-doped BaxSr1−xTiO3 powders with different phase structure. Journal of Alloys and Compounds, 516, 49–52. https://doi.org/10.1016/j.jallcom.2011.11.121.
Chen, L., Wei, X. H., & Fu, X. (2012b). Effect of Er substituting sites on upconversion luminescence of Er3+-doped BaTiO3 films. Transactions of the Nonferrous Metals Society of China, 22, 1156–1160. https://doi.org/10.1016/S1003-6326(11)61299-5.
Cullity, B. D., & Stock, S. R. (2001). Elements of X-ray diffraction. Reading, Massachusetts Book Chapter.
Dang, N. V., Nguyen, H. M., Chuang, P. Y., Thanh, T. D., Lam, V. D., Lee, C. H. et al. (2012). Structure of BaTi1−xFexO3−del multiferroics using X-ray analysis. Chinese Journal of Physics, 50, 262–270. http://psroc.org/cjp/download.php?type=paper&vol=50&num=2&page=262. Accessed May 31, 2017.
Gadelmawla, E. S., Koura, M. M., Maksoud, T. M. A., Elewa, I. M., & Soliman, H. H. (2002). Roughness parameters. Journal of Materials Processing Technology, 123, 133–145. https://doi.org/10.1016/S0924-0136(02)00060-2.
García-Hernández, M., García-Murillo, A., de Carrillo-Romo, F. J., de Morales-Ramíarez, Á. J., Meneses-Nava, M.A., Gonzalez-Penguelly, B. et al. (2013). Effect of starting materials on the morphological and optical properties of Er doped BaTiO3 nanocrystalline films. Material Transaction, 54, 806–810. https://doi.org/10.2320/matertrans.m2012313.
Gomes, M. A., Lima, Á. S., Eguiluz, K. I. B., & Salazar-Banda, G. R. (2016). Wet chemical synthesis of rare earth-doped barium titanate nanoparticles. Journal Materials Science, 51, 4709–4727. https://doi.org/10.1007/s10853-016-9789-7.
Kaźmierczak-Bałata, A., Bodzenta, J., Krzywiecki, M., Juszczyk, J., Szmidt, J., & Firek, P. (2013). Application of scanning microscopy to study correlation between thermal properties and morphology of BaTiO3 thin films. Thin Solid Films, 545, 217–221. https://doi.org/10.1016/j.tsf.2013.08.007.
Krishnan, P. S. S. R., & Munroe, P. R. (2013). Influence of fabrication conditions on the ferroelectric polarization of barium titanate thin films. Journal of Asian Ceramic Societies, 1, 149–154. https://doi.org/10.1016/j.jascer.2013.04.001.
Mitic, V. V., Nikolic, Z. S., Pavlovic, V. B., Paunovic, V., Miljkovic, M., Jordovic, B., et al. (2010). Influence of rare-earth dopants on barium titanate ceramics microstructure and corresponding electrical properties. Journal of the American Ceramic Society, 93, 132–137. https://doi.org/10.1111/j.1551-2916.2009.03309.x.
Qi, Y., Zhang, L., **, G., Wan, Y., Tang, Y., Xu, D., et al. (2014). UV-visible spectra and conductive property of Mn-doped BaTiO3 and Ba0.93Sr0.07TiO3 ceramics. Ferroelectrics, 458, 64–69. https://doi.org/10.1080/00150193.2013.849995.
Rosenberger, J., Nass, R., & Schmidt, H. (1992). Crystallization behaviour of barium titanate thin films. In European materials research society monographs (pp. 343–349). Elsevier, Oxford. https://doi.org/10.1016/b978-0-444-89344-4.50041-0.
Stawski, T. M., Vijselaar, W. J. C., Göbel, O. F., Veldhuis, S. A., Smith, B. F., Blank, D. H. A., et al. (2012). Influence of high temperature processing of sol–gel derived barium titanate thin films deposited on platinum and strontium ruthenate coated silicon wafers. Thin Solid Films, 520, 4394–4401. https://doi.org/10.1016/j.tsf.2012.02.029.
Supasai, T., Dangtip, S., Learngarunsri, P., Boonyopakorn, N., Wisitsoraat, A., & Hodak, S. K. (2010). Influence of temperature annealing on optical properties of SrTiO3/BaTiO3 multilayered films on indium tin oxide. Applied Surface Science, 256, 4462–4467. https://doi.org/10.1016/j.apsusc.2010.01.072.
Tudose, I. V., Horváth, P., Suchea, M., Christoulakis, S., Kitsopoulos, T., & Kiriakidis, G. (2007). Correlation of ZnO thin film surface properties with conductivity. Applied Physics A, 89, 57–61. https://doi.org/10.1007/s00339-007-4036-3.
Viviani, M., Buscaglia, M. T., Buscaglia, V., Mitoseriu, L., Testino, A., & Nanni, P. (2002). Electrical properties of Er-doped BaTiO3 ceramics for PTCR applications. In Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002 (pp. 103–106). https://doi.org/10.1109/isaf.2002.1195881.
Woldu, T., Raneesh, B., Sreekanth, P., Ramana Reddy, M. V., Philip, R., & Kalarikkal, N. (2015). Size dependent nonlinear optical absorption in BaTiO3 nanoparticles. Chemical Physics Letters, 625, 58–63. https://doi.org/10.1016/j.cplett.2015.02.020.
Yang, X., Guo, H., Chen, K., Zhang, W., Lou, L., Yin, M. (2004). Er3+ doped BaTiO3 optical-waveguide thin films elaborated by sol-gel method. Journal of Rare Earths, 22, 36–39. http://cj.re-journal.com/en/guokanshow.asp?id=4218. Accessed May 31, 2017.
Zhang, Y., Hao, J., Mak, C. L., & Wei, X. (2011). Effects of site substitutions and concentration on upconversion luminescence of Er3+-doped perovskite titanate. Optics Express, 19, 1824–1829. https://doi.org/10.1364/OE.19.001824.
Acknowledgements
This work is partially supported by Fundamental Research Grant Scheme (FRGS) with the Grant number 9003-00479, funded by the Ministry of Higher Education (KPT). The authors also gratefully acknowledge the helpful comments and suggestions of the reviewers, which have improved the presentation.
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Ooi, Z.V., Saif, A.A. (2018). Effect of Annealing Temperature on Structural Properties of Ba0.9Er0.1TiO3 Thin Films. In: Saian, R., Abbas, M. (eds) Proceedings of the Second International Conference on the Future of ASEAN (ICoFA) 2017 – Volume 2. Springer, Singapore. https://doi.org/10.1007/978-981-10-8471-3_74
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DOI: https://doi.org/10.1007/978-981-10-8471-3_74
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