Selectivity Induced by the Void Structure of Zeolite Beta and Ferrierite in the Hydroconversion Reaction of N-Decane

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Chemical Reactions in Organic and Inorganic Constrained Systems

Part of the book series: NATO ASI Series ((ASIC,volume 165))

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Abstract

Ferrierite, BETA and ultrastable Y zeolites with restricted differences in chemical composition, crystallite size, platinum content and prepared via discrete methods were transformed into bifunctional catalysts and catalytically tested in the hydroconversion reaction of decane.

From a detailed inspection of the product distribution, criteria were selected which enabled to characterize each structure. The Ferrierite zeolites were easily distinguishable from the other large pore zeolites. The discrimination of zeolite ultrastable Y from zeolite BETA required the simultaneous consideration of all selected criteria. The limited variation of the physical and physico-chemical properties of a given zeolite structure was not found to influence the product distribution in a significant way.

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© 1986 D. Reidel Publishing Company, Dordrecht, Holland

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Martens, J.A., Perez-Pariente, J., Jacobs, P.A. (1986). Selectivity Induced by the Void Structure of Zeolite Beta and Ferrierite in the Hydroconversion Reaction of N-Decane. In: Setton, R. (eds) Chemical Reactions in Organic and Inorganic Constrained Systems. NATO ASI Series, vol 165. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4582-1_9

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  • DOI: https://doi.org/10.1007/978-94-009-4582-1_9

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8536-6

  • Online ISBN: 978-94-009-4582-1

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