Abstract
Ferrierite, BETA and ultrastable Y zeolites with restricted differences in chemical composition, crystallite size, platinum content and prepared via discrete methods were transformed into bifunctional catalysts and catalytically tested in the hydroconversion reaction of decane.
From a detailed inspection of the product distribution, criteria were selected which enabled to characterize each structure. The Ferrierite zeolites were easily distinguishable from the other large pore zeolites. The discrimination of zeolite ultrastable Y from zeolite BETA required the simultaneous consideration of all selected criteria. The limited variation of the physical and physico-chemical properties of a given zeolite structure was not found to influence the product distribution in a significant way.
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References
Weisz, P.B. and Frillette, V.J., J. Phys. Chem., 64, 1960, 382.
Weisz, P.B., Pure & Appl. Chem., 52, 1980, 2091.
Csicsery, S.M., in “Zeolite Chemistry and Catalysis”, ACS Monograph No. 171, J.A. Rabo, Ed., Washington, 1976, 680.
Csicsery, S.M., Zeolites, 4, 1984, 202.
Derouane, E.G., in “Catalysis by Zeolites”, B. Imelik et al., Eds., Elsevier, Amsterdam, 1980, Stud. Surf. Sci. Catal., 4, 1980, 5.
Derouane, E.G., in “Intercalation Chemistry”, M.S. Whittingham and A.J. Jackson, Eds., Academic Press, New York, 1982, 101.
Derouane, E.G., in “Catalysis on the energy Scene”, S. kaliaguine and A. Mahay, Eds., Elsevier, Amsterdam, 1984, Stud. Surf. Sci. Catal., 19, 1984, 1.
Derouane, E.G., in “Zeolites : Science and Technology”, F. Ramôa Ribeiro et al., Eds., Nato ASI Series E, No. 80, Nyhoff, 1984, 347.
Frillette, V.J., Haag, W.O. and Lago, R.M., J. Catal., 67, 1981, 218.
Haag, W.O., Lago, R.M. and Weisz, P.B., Faraday Disc. Chem. Soc., 72:, 1982, 317.
Dewing, J., J. Mol. Catal., 27, 1984, 25.
Gnep, N.S., Tejada, J. and Guisnet, M., Bull. Soc. Chim. France, 1982, 1–5.
Martens, J.A., Tielen, M., Jacobs, P.A. and Weitkamp, J., Zeolites, 4, 1984, 98.
Breck, D.W., Zeolite Molecular Sieves, Wiley, New York, London, Sydney, Toronto, 1974, 593.
Weitkamp, J., Erdöl, Kohle, Erdgas, Petrochemie und Brennstoff Chemie, 31, 1978, 13.
Vaughn, P.A., Acta Chrystallogr., 21, 1966, 983.
Kerr, I.S., Nature, 210, 1966, 294.
Wadlinger, R.L., Kerr, G.T., Rosinski, E.J., U.S.P. 3,308,069 (1967), assigned to Mobil Oil Corp.
Maugé, F., Auroux, A, Courcelle, J.C., Engelhard, Ph., Gallezot, P., and Grosmangin, J., in “Catalysis by Acids and Bases”, B. Imelik et al., Eds., Elsevier, Amsterdam, 1985, Stud. Surf. Sci. Catal., 20, 1985, 91.
Plank, C.J., Rosinski, E.J. and Rubin, M.K., U.S.P. 4,016,245 (1977), assigned to Mobil Oil Corp.
Nanne, J.M., Post, M.F.M. and Stork, W.H.J., E.P. 12,473 (1980), assigned to Shell Int. Res.
Martens, J.A., Perez-Pariente, J. and Jacobs, P.A., Proceed. Int. Symp. Zeolite Catalysis, Siofok, Hungary, 1985, 487.
Valyocsik, E.W., E.P.A. 0,012,572 (1980), assigned to Mobil Oil Corp.
Steijns, M., Froment, G., Jacobs, P., Uytterhoeven, J. and Weitkamp, J., Ind. Eng. Chem. Prod. Res. Dev., 20, 1981, 654.
Jacobs, P.A., Martens, J.A., Weitkamp, J. and Beyer, H.K., Faraday Disc. chem. Soc., 72, 1982, 353.
Stull, R.D., Westrum, E.F. and Suike, G.C., “The Thermodynamics of Organic Compounds”, Wiley, New York, 1969.
Martens, J.A., Jacobs, P.A. and Weitkamp, J., paper submitted to Applied Catalysis.
Steijns, M. and Froment, G., Ind. Eng. Chem. Prod. Res. Dev., 20, 1981, 660.
Jacobs, P.A., Martens, J.A., Beyer, H.K., in “Catalysis by Acids and Bases”, B. Imelik et al., Eds., Elsevier, Amsterdam, 1985, Stud. surf. Sci. Catal., 20, 1985, 399.
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© 1986 D. Reidel Publishing Company, Dordrecht, Holland
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Martens, J.A., Perez-Pariente, J., Jacobs, P.A. (1986). Selectivity Induced by the Void Structure of Zeolite Beta and Ferrierite in the Hydroconversion Reaction of N-Decane. In: Setton, R. (eds) Chemical Reactions in Organic and Inorganic Constrained Systems. NATO ASI Series, vol 165. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4582-1_9
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DOI: https://doi.org/10.1007/978-94-009-4582-1_9
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