Abstract
In this review, the terms Copolymerization and Copolymers include not only the simultaneous polymerization of two or more monomers, but also polymerizations in multiple stages. Only a few homopolymers are actually compatible; hence it should be expected that copolymerization leads to complex behaviours since the covalent bond will constrain the partners to associate more or less stably. On the other hand, copolymer characteristics and properties depend on the sequence distribution of monomer units along the main chains (microstructure) and this can lead to a particle structure which may result in a more or less complex morphology of the latex particles and of the films cast from them. As a consequence, it is necessary to control the synthesis in that heterogeneous process.
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Guillot, J., Guyot, A., Pichot, C. (1990). Copolymer Latex Morphology. In: Candau, F., Ottewill, R.H. (eds) An Introduction to Polymer Colloids. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0521-4_4
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DOI: https://doi.org/10.1007/978-94-009-0521-4_4
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