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Infrared Spectroscopic Characterization of the Crystallinity and the Hydrocarbon Chain Packing of the Polyethylene Segments in Poly(ethylene-co-dimethylaminoethyl Methacrylate)

  • Conference paper
Progress in Fourier Transform Spectroscopy

Part of the book series: Mikrochimica Acta Supplement ((MIKROCHIMICA,volume 14))

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Abstract

The multicrystalline behaviour and the crystallinity of poly(ethylene-co-dimethylaminoethyl methacrylate) were investigated by infrared spectroscopy. The metastable monoclinic packing structure of the polyethylene segments of the copolymers usually co-exists with the stable orthorhombic form in the isotropic samples. The reason for the occurrence of this multicrystalline structure is discussed. The relative content of the monoclinic form in the crystalline regions changed greatly with the co-unit contents and the crystallization conditions. The crystallinity of the samples was also estimated by spectroscopic methods.

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Author information

Authors and Affiliations

  1. Institute of Chemistry, Academia Sinica, Bei**g, 100080, Peoples Republic of China

    Hui** Zhang & Duanfu Xu

  2. Department of Chemistry, Peking University, Bei**g, 100871, Peoples Republic of China

    Yizhuang Xu, Shifu Weng & **guang Wu

Authors
  1. Hui** Zhang
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  2. Duanfu Xu
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  3. Yizhuang Xu
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  4. Shifu Weng
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  5. **guang Wu
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Editor information

Editors and Affiliations

  1. Department of Analytical Chemistry, University of Veszprém, Veszprém, Hungary

    János Mink

  2. Institute of Isotopes, Hungarian Academy of Sciences, Budapest, Hungary

    János Mink

  3. Central Research Institute of Chemistry, Hungarian Academy of Sciences, Budapest, Hungary

    Gábor Keresztury

  4. Institut für Analytische Chemie, Technische Universität Wien, Wien, Austria

    Robert Kellner

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© 1997 Springer-Verlag Wien

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Zhang, H., Xu, D., Xu, Y., Weng, S., Wu, J. (1997). Infrared Spectroscopic Characterization of the Crystallinity and the Hydrocarbon Chain Packing of the Polyethylene Segments in Poly(ethylene-co-dimethylaminoethyl Methacrylate). In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_100

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  • DOI: https://doi.org/10.1007/978-3-7091-6840-0_100

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-211-82931-8

  • Online ISBN: 978-3-7091-6840-0

  • eBook Packages: Springer Book Archive

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