Synonyms
Chemical Formula
CH2NH
Definition
The organic molecule methanimine is not terribly stable under terrestrial conditions, being a minor equilibrium product of the reaction of ammonia and formaldehyde. It has been suggested as a possible precursor to the amino acid glycine in some astrophysical settings (e.g., Godfrey et al. 1973).
Overview
Methanimine was one of the first relatively complex organic molecules detected in the interstellar medium (Godfrey et al. 1973), towards the Galactic Center molecular cloud SgrB2. It has subsequently been found in several “hot core” sources, interstellar molecular clouds where massive stars are forming (Dickens et al. 1997). Methanimine may also be present in the atmosphere of Saturn’s satellite Titan (Vuitton et al. 2006).
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References and Further Reading
Dickens JE, Irvine WM, DeVries CH, Ohishi M (1997) Hydrogenation of interstellar molecules: a survey for Methylenimine (CH2NH). Astrophys J 479:307–312
Godfrey PD, Brown RD, Robinson BJ, Sinclair MW (1973) Discovery of interstellar Methanimine (Formaldimine). Astrophys Lett 13:119–121
Halfen DT, Ilyushin VV, Ziurys LM (2013) Insights into surface hydrogenation in the interstellar medium: observations of Methanimine and methyl amine. Astrophys J 767:66–77
Vuitton V, Yelle RV, Anicich VG (2006) The nitrogen chemistry of Titan’s upper atmosphere revealed. Astrophys J 647:L175–L178
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Irvine, W.M. (2023). Methanimine (CH2NH). In: Gargaud, M., et al. Encyclopedia of Astrobiology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-65093-6_5322
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