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The Phase Diagram Si-C-O

  • Chapter
Si Silicon

Part of the book series: Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie ((2074,volume S-i / B / 1-5 / 3))

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Abstract

Due to the importance of the Acheson reaction between SiO2 and C, the Si-C-O phase diagram has been investigated several times, with systematic experimental investigations being performed by [1, 2]. Commonly only the well-known binary compounds have been found.— In phase diagram investigations no solid ternary phases have been detected, stated otherwise [3 to 5]. On oxidation of SiC under 1 atm O2.a phase with the probable composition Si4O4C4 was detected, existing mainly between 675 and 1425 K. Its existence was verified by physical methods, and a structural model was developed [6 to 8], see also [9].

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Authors and Affiliations

  1. NUKEM GmbH, Hanau, Germany

    Vera Haase, Gerhard Kirschstein, Hildegard List, Sigrid Ruprecht, Raymond Sangster, Friedrich Schröder, Wolfgang Töpper, Hans Vanecek & Hartmut Katscher

  2. Universität Karlsruhe, Germany

    Jürgen Schlichting

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  1. Vera Haase
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  2. Gerhard Kirschstein
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  3. Hildegard List
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Hartmut Katscher Raymond Sangster Friedrich Schröder

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© 1985 Springer-Verlag Berlin Heidelberg

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Haase, V. et al. (1985). The Phase Diagram Si-C-O. In: Katscher, H., Sangster, R., Schröder, F. (eds) Si Silicon. Gmelin Handbook of Inorganic Chemistry / Gmelin Handbuch der Anorganischen Chemie, vol S-i / B / 1-5 / 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06994-3_4

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  • DOI: https://doi.org/10.1007/978-3-662-06994-3_4

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