Abstract
Geochemical data for the organic matter (OM) in the Fore-Sudetic copper-bearing shales have been collected and evaluated. They were also compared with those for OM from the German Kupferschiefer. The organic matter (up to 20wt.%) has been one of the principal agents in the formation and transformations of the Kupferschiefer deposit. Bitumens represent about 3% of the whole OM. The organic matter is mainly of sapropelic origin (phytoplankton, algae, bacteria) and was deposited under highly reducing conditions. The specific composition of OM in the mineralized areas might be attributed to mineralization processes, e.g., microbial reduction of metal ions and sulphates. The OM of the “Rote Faule” areas has been secondarily oxidized by different processes, connected not only with ore mineralization. Some metals (V, Ni, noble metals) are still present in bitumens and probably also in kerogen in the form of organometallic compounds. The organic matter could take part in metal accumulation, reduction, precipitation and remobilization of sulphides, and also transformations of clay minerals. It is shown that some typical maturation parameters can be of dubious value in the case of organic matter from the ore deposits.
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References
Bailey NJL, Jonson AM, Rogers MA (1973) Bacterial degradation of crude oil: comparison of field and experimental data. Chem Geol 11: 203–221
Baukov SS, Kotlukov VA (1973) Oil shales. Valgus, Tallin (in Russian)
Bein A, Sandler A (1983) Early diagenetic oxidation and maturation trends in organic matter extracted from Eocene chalks and cherts. Chem Geol 38: 213–224
Beveridge TJ, Meloche JD, Fyfe WS, Murray RGE (1983) Diagenesis of metals chemically complexed to bacteria: Laboratory formation of metal phosphates, sulfides, and organic condensates. Appl Environ Microbiol 45: 1094–1108
Borchert H, Krejci-Graf K (1959) Spurenmetalle in Sedimenten und ihren Derivaten. Bergbauwissenchaften 6: 205–215
Boulegue J, Lord CJ III, Church TM (1982) Sulfur speciation and associated trace metals (Fe, Cu) in the pore waters of Great Marsh, Delaware, Geochim Cosmochim Acta 46: 453–464
Calikowski J, Rzepkowska Z (1984) Geochemistry of organic matter from the copper-bearing shales. Arch PIG Warszawa (unpubl ) (in Polish)
Cane RF (1976) The origin and formation of oil shale. In: Yen TF (ed) Oil shale. Elsevier, Amsterdam, pp 27–60
Cheshire MV, Berrow ML, Goodmann BA, Mundie CM (1977) Metal distribution and nature of some Cu, Mn and V complexes in humic and fulvic acid fractions of soil organic matter. Geochim Cosmochim Acta 41: 1131–1138
Claypool GE, Love AH, Maughan EK (1978) Organic geochemistry, incipient metamorphism and oil generation in black shale members of the Phosphoria Formation of Western Interior USA. Bull AAPG 62: 98–112
Connan J, Orgeval JJ (1976) Un exemple du relation hydrocarbures mineralisations: cas du filon de barytine de St. -Privat ( Bassin de Lodève, France). Bull Cent Rech Pau-SNPA 10: 359–374
Didyk BM, Simoneit BRT, Brassell SC, Eglinton G (1978) Organic geochemical indicators of palaeoenvironmental conditions of sedimentation. Nature 272: 216–222
Disnar JR (1981) Etude experimentale de la fixation de metaux par un materiau sedimentaire actuel d’origine algaire-II. Fixation in vitro de UO2+, Cu2+, Ni2+, Pb2+, Co2+, Mn2+, ainsi que de VO3 -, MoO42 -, et GeO32 -. Geochim Cosmochim Acta 45: 363–379
Disnar JR, Trichet J (1983) Simulation experimentale de la diagenese de complexes organometalliques, Implications metallogeniques. CR Acad Sci ser 2, 296: 631–634
Douglas AG, Mair BJ (1965) Sulphur: role in genesis of petroleum. Science 147: 499–501
Evans WD (1964) The organic solubilization of minerals in sediments. In: Colombo U, Hobson GD (eds) Advances in organic geochemistry, vol 1. Pergamon Press, Oxford, pp 263–270
Geissler G (1971) Zur Isotopenanalyse des organischen Kohlenstoffs geologischer Proben. Zangew Geol 17: 484–488
Gondek B (1979) Investigations of the structures of aromatic hydrocarbons in oils and dispersed bitumen. Biul Inst Geol 315: 5–40 (in Polish)
Hammer J, Roesler HJ, Gleisberg B (1988) Neutronenaktivierungs analytische, säulenchromatographische und IR-spektroskopische Untersuchungen der Bitumensubstanz des Kupferschiefers der Sangerhäuser Mulde ( DDR ). Chem Erde 48: 61–78
Hammer J, Junge F, Stiehl G (1989) Isotopengeochemische (C, N, O) Untersuchungen an Kupferschieferprofilen unterschiedlicher fazieller Position. Chem Erde 49: 137–153
Haranczyk C (1972) Ore mineralization in the euxinic Lower Zechstein sediments of the ForeSudetic Monocline. Arch Miner 30: 13–173 (in Polish)
Jackson TA (1977) A relationship between crystallographic properties of illite and chemical properties of extractable organic matter in pre-Phanerozoic and Phanerozoic sediments. Clays Clay Minerals 25: 187–195
Kinghorn RRF (1983) An introduction to the physics and chemistry of petroleum. J Wiley and Sons, Chichester, 420 pp
Kodina LA, Galimov EM (1982) Isotopic composition of the carbon (humic and sapropelic) of organic matter from marine sediments. In: IX Symp Stable Isotopes in Geochemistry. Vernadski Institute, Moscow. pp 23–25 (in Russian)
Kucha H (1976) Organic matter, Au, Ni and Co in the Zechstein sediments of the Fore-Sudetic Monocline. Ann Pol Geol Soc 46: 363–410 (in Polish)
Kucha H (1981) Precious metal alloys and organic matter in the Zechstein copper deposits, Poland. Tschermaks Min Pet Mitt 28: 1–16
Kucha H (1982) Platinum-group metals in the Zechstein copper deposits, Poland. Econ Geol 77: 1578–1591
Kucha H (1985) Feldspar, clay, organic and carboanate receptors of heavy metals in Zechstein deposits (Kupferschiefer-type), Poland. Trans Inst Min Metall (Sect B) 94: B133 — B146
Leventhal JS (1985) Roles of organic matter in ore deposits. Proc Denver Region Explor Geol Soc Symp, 7–20
Lewan MD (1986) Stable carbon isotopes of amorphous kerogens from Phanerozic sedimentary rocks. Geochim Cosmochim Acta 50: 1583–1591
MacQueen RW, Powell TG (1983) Organic geochemistry of the Pine Point lead-zinc ore field and region, Northwest Territories, Canada. Econ Geol 78: 1–25
Malashkina VT (1979) Application of IR spectroscopy for determination of bitumen from metasediments of Western part of Pechenga ore deposit. Geochimia 10: 550–554 (in Russian)
Manskaya SM, Drozdova TV (1968) Geochemistry of organic substances. Pergamon Press, New York
Marowsky G (1969) Schwefel-, Kohlenstoff-and Sauerstoffisotopen Untersuchungen aus Kupferschiefer als Beitrag zur genetischen Deutung. Contrib Mineral Pet 22: 290–334
Nissenbaum A, Swaine DJ (1976) Organic matter-metal interactions in recent sediments: the role of humic substances. Geochim Cosmochim Acta 40: 804–816
Orr WL (1974a) Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation — study of Big Horn Basin paleozoic oils. Bull AAPG 50: 2295–2318
Orr WL (1974b) Sulfur. In: Wedepohl KH (ed) Handbook of Geochemistry, vol 2. Springer, Berlin Heidelberg New York
Oszczepalski S (1986) On the Zechstein copper shale lithofacies and palaeoenvironments in SW Poland. In: Harwood GM, Smith DB (eds) The English Zechstein and related topics. Geol Soc Spec Publ 22, pp 171–182
Palmberg AH (1964) Bitumen des Kupferschiefers. Unveröff. Bericht ZGI Berlin
Palmer SE, Baker EW (1978) Copper porphyrins in deep-sea sediments: a possible indicator of oxidized terrestrial organic matter. Science 201: 49–51
Parnell J (1988) Metal enrichment in solid bitumens: A review. Mineral Deposita 23:191–199 Pauli FW (1975) Heavy metal humates and their behaviour against hydrogen sulfide. Soil Sci 119: 98–105
Pelet R, Debyser J (1977) Organic geochemistry of Black Sea cores. Geochim Cosmochim Acta 41: 1575–1586
Puttmann W, Gossel W (1990) The Permian Kupferschiefer of southwest Poland: a geochemical trap for migrating, metal-bearing solutions. Appl Geochem 5: 227–235
Puttmann W, Hagemann HW, Merz C, Speczik S (1987) Influence of organic material on mineralization processes in the Permian Kupferschiefer Formation, Poland. Org Geochem 13: 357–363
Ramdohr P (1969) The ore minerals and their intergrowths. Pergamon Press, Oxford
Rashid MA (1971) Role of humic acids of marine origin and their different molecular weight fractions in complexing di-and tri-valent metals. Soil Sci 111: 298–306
Rashid MA (1972) Role of quinone groups in solubility and complexing metals in sediments and soils. Chem Geol 9: 241–248
Reed WE (1977) Molecular compositions of weathered petroleum and comparison with its possible source. Geochim Cosmochim Acta 41: 237–247
Rentzsch J (1974) The Kupferschiefer in comparison with the deposits of the Zambian Copperbelt. In: Bartholome P (ed) Gisements stratiformes et provinces cuprifères. Soc Geol Belg, Liege, pp 395–418
Sawlowicz Z (1983) Kerogen from the copper-bearing shales from the Fore-Sudetic Monocline — preliminary data. Rudy Metale 7: 245–250 (in Polish)
Sawlowicz Z (1984) Investigations of the organic matter from the copper-bearing shales from the Fore-Sudetic Monocline. Przegl Geol 7: 383–386 (in Polish)
Sawlowicz Z (1985) Significance of metalloporphyrins for the metal accumulation in the copper bearing shales from the Zechstein copper deposits (Poland). ineral Pol 16: 35–42
Sawlowicz Z (1989a) Organic matter in the Zechstein Kupferschiefer from the Fore-Sudetic Monocline (Poland). I. Bitumen. Mineral Pol 20: 69–86
Sawlowicz Z (1989b) Isotopic composition of C, O, S from the organic-rich copper-bearing shale from the Kupferschiefer in Poland. Arch Miner 44: 5–19
Sawlowicz Z (1991) Organic matter in the Zechstein Kupferschiefer from the Fore-Sudetic Monocline (Poland). II. Kerogen. Mineral Pol 22: 49–67
Saxby JD (1969) Metal-organic chemistry of the geochemical cycle. Rev Pure Appl Chem 19: 131–150
Saxby JD (1970) Technique for the isolation of kerogen from sulfide ores. Geochim Cosmochim Acta 34: 1317–1326
Saxby JD (1973) Diagenesis of metal-organic complexes in sediments. Formation of metal sulphides from cystine complexes. Chem Geol 12: 241–248
Saxby JD (1976) The significance of organic matter in ore genesis. In: Wolf KH (ed) Handbook of
strata-bound and stratiform ore deposits, vol 2. Elsevier, Amsterdam, pp 111–133
Saxby JD (1981) Organic matter in ancient ores and sediments. BMR J Aust Geol Geophys 6: 287–291
Schueller A (1959) Metallisation und Genese des Kupferschiefers von Mansfeld. Abh Dtsch Akad Wiss Berl 6: 1–9
Stahl WJ (1977) Carbon and nitrogen isotopes in hydrocarbon research and exploration. Chem Geol 20: 121–149
Staplin FL (1969) Sedimentary organic matter, organic metamorphism, and oil and gas occurrences. Bull Can Pet Geol 17: 47–66
Szczepkowska-Mamczarczyk I (1971) Organic matter in the copper-bearing shales from the Zechstein of the Fore-Sudetic Zone. Kwartalnik Geol 15: 41–55 (in Polish)
Szpanier K (1979) Determination of genetical links between oils and bitumen on the basis of the investigation of structure of asphaltenes. Bull Inst Geol 315: 45–70 (in Polish)
Tissot BP, Welte DH (1984) Petroleum formation and occurrences, 2nd edn. Springer, Berlin Heidelberg New York
Tissot B, Demaison G, Masson P, Delteil JR, Combaz A (1980) Paleoenvironment and petroleum potential of Middle Cretaceous Black Shales in Atlantic basins. AAPG Bull 64: 2051–2063
Todd TW (1963) Post-depositional history of Tensleep Sandstone (Pennsylvanian), Big Horn Basin Wyoming. AAPG Bull 47: 599–616
Tokarska K (1971) Geochemical characteristics of organic matter from the Zechstein copper-bearing shales. Kwartalnik Geol 15: 67–76 (in Polish)
Trudinger PA (1972) Microbiological processes in relation to ore genesis. In: Wolf KH (ed) Handbook of strata-bound and stratiform ore deposits, vol II. Elsevier, Amsterdam, pp 135–160
Trudinger PA, Bubela B (1967) Microorganisms and the natural environment. Mineral Deposita 2: 147–157
Trudinger PA, Lambert IB, Skyring GW (1972) Biogenic sulfide ores: a feasibility study. Econ Geol 67: 1114–1127
Tusinski S, Gasiewicz A, Gerdes G, Krumbein WE (1987) New evidence for the biogenic origin of the copper shale (T1) at Rudna mine (SW Poland). In Klare B, Schröder B (eds) Int Symp, Zechstein, Bochum (Abstr)
Wolf M, David P, Eckardt CB, Hagemann HW, Puttmann W (1989) Facies and rank of the Permian Kupferschiefer from the Lower Rhine Basin and NW Germany. Int J Coal Geol 14: 119–136
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Sawlowicz, Z. (1993). Organic Matter and its Significance for the Genesis of the Copper-Bearing Shales (Kupferschiefer) from the Fore-Sudetic Monocline (Poland). In: Parnell, J., Kucha, H., Landais, P. (eds) Bitumens in Ore Deposits. Special Publication of the Society for Geology Applied to Mineral Deposits, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-85806-2_23
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