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Conformation of Conjugated Polymers and Their Relation to Electron Délocalisation

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Electronic Properties of Conjugated Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 76))

Abstract

The notion of “conjugation length” has been commonly used in the interpretation of Resonance Raman Scattering spectra from solid polyacetylene [1] or conjugated polymer solutions [2,3]. This “length” ξ is usually of the order of 30 to 200 Å. A simple way of interrupting electronic derealization is by introducing a strong defect : a chemical impurity like a -CH2- group into the CH)X chain, or a physical defect of unspecified nature. Several papers in this volume consider the influence of such defects theoretically and experimentally.

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References

  1. There is a very abundant literature on that subject. Several papers can be found in the proceedings of this and the previous IWEPP “Electronic Properties of Polymers and Related Compounds”, H. Kuzmany, M Mehring and S. Roth eds., Springer Series in Solid State Sciences 63 (1985) as well as those of the conferences at Abano Terme, Les Arcs, etc… Mol. Cryst. Liq. Cryst. 117 (1985) J. Physique Coll. 44 C3 (1983).

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Author information

Authors and Affiliations

  1. Groupe de Physique des Solides de l’E.N.S, Université Paris VII, 2, place Jussieu, F-75251, Paris, Cedex 05, France

    J. P. Aimé & M. Schott

  2. Laboratoire de Physique des Solides, 91405, Orsay, France

    M. Rawiso

Authors
  1. J. P. Aimé
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  2. M. Rawiso
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  3. M. Schott
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, Wien, Kopernikusgasse 15, A-1090, Wien, Austria

    Hans Kuzmany

  3. Physikalisches Institut II, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  4. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1987 Springer-Verlag Berlin Heidelberg

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Aimé, J.P., Rawiso, M., Schott, M. (1987). Conformation of Conjugated Polymers and Their Relation to Electron Délocalisation. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_11

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  • DOI: https://doi.org/10.1007/978-3-642-83284-0_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83286-4

  • Online ISBN: 978-3-642-83284-0

  • eBook Packages: Springer Book Archive

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