SpringerLink
Log in

Inorganic, Hybrid and Functional Pigments

  • Living reference work entry
  • Latest version View entry history
  • First Online:
Encyclopedia of Color Science and Technology

Synonyms

Biopolymers; Catalysts; Coatings; Dyes; Paints

Definition

Pigments, which have been widely used since prehistoric times, include naturally occurring substances prepared from minerals or their combustion products as well as synthetic compounds produced from appropriate raw materials and also hybrid pigment types derived from organic and/or natural dyes and selected mineral supports including metal oxides, biopolymers, and others. Pigments are insoluble in the surrounding medium and their optical effect arises from selective light absorption. They are classified according to their color, origin, method of production, and the character of the pigment material. Hybrid pigment technology is directly related to the development of new synthesis methods, preparation of functional and also environmentally friendly colorants.

Introduction

This entry presents the main aspects of classification and production technology, broadly understood, for the most common inorganic pigments. It...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

References

  1. Garo, D.: Pigments – a growth market. Europ. Coat. J. 1, 10–13 (2012)

    Google Scholar 

  2. Endriβ, H.: Inorganic Coloured Pigments Today. Vincentz Verlag, Hannover (1998)

    Google Scholar 

  3. Golgschmidt, A., Streitberger, H.J.: BASF-Handbuch Lackiertechnik. Vincentz Verlag, Hannover (2002)

    Google Scholar 

  4. Lambournle, R., Strivens, T.A. (eds.): Paint and Surface Coatings Theory and Practice, 2nd edn. Woodhead Publishing Ltd., Cambridge (1999)

    Google Scholar 

  5. Oyarzún, J.M.: Pigment Processing Physico-Chemical Principles. Vincentz Verlag, Hannover (2000)

    Google Scholar 

  6. Bauxbaum, G. (ed.): Industrial Inorganic Pigments. WILEY-VCH Verlag GmbH, Weinheim (1998)

    Google Scholar 

  7. Chen, X., Mao, S.S.: Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891–2959 (2007)

    Article  Google Scholar 

  8. Moezzi, A., McDonagh, A.M., Cortie, M.B.: Zinc oxide particles: synthesis, properties and application. Chem. Eng. J. 185–186, 1–22 (2012)

    Article  Google Scholar 

  9. Klapiszewska, B., Krysztafkiewicz, A., Jesionowski, T.: Highly dispersed green silicate and oxide pigments precipitated from model systems of postgalvanic waste. Environ. Sci. Technol. 37, 4811–4818 (2003)

    Article  ADS  Google Scholar 

  10. Krysztafkiewicz, A., Klapiszewska, B., Jesionowski, T.: Precipitated green pigments: products of chromate postgalvanic waste utilization. Environ. Sci. Technol. 42, 7482–7488 (2008)

    Article  ADS  Google Scholar 

  11. Wypych, G.: Handbook of Fillers, 3rd edn. ChemTec Publishing, Toronto (2010)

    Google Scholar 

  12. Geddes, C.D., Apperson, K., Birch, D.J.S.: New fluorescent quinolinium dyes – applications in nanometer particle sizing. Dyes Pigments. 44, 69–74 (2000)

    Article  Google Scholar 

  13. Malinge, J., Allain, C., Brosseau, A., Audebert, P.: White fluorescence from core-shell silica nanoparticles. Angew. Chem. Int. Ed. 51, 8534–8537 (2012)

    Article  Google Scholar 

  14. Jesionowski, T., Przybylska, A., Kurc, B., Ciesielczyk, F.: The preparation of pigment composites by adsorption of C.I. Mordant Red 11 and 9-aminoacridine on both unmodified and aminosilane-grafted silica supports. Dyes Pigments. 88, 116–124 (2011)

    Article  Google Scholar 

  15. Jesionowski, T., Przybylska, A., Kurc, B., Ciesielczyk, F.: Hybrid pigments preparation via adsorption of C.I. Mordant Red 3 on both unmodifeid and aminosilane-functionalised silica supports. Dyes Pigments. 89, 127–136 (2011)

    Article  Google Scholar 

  16. Siwińska-Stefańska, K., Nowacka, M., Kołodziejczak-Radzimska, A., Jesionowski, T.: Preparation of hybryd pigemnts via adsorption of selected food dyes onto inorganic oxides based on anatase titanium dioxide. Dyes Pigments. 94, 338–348 (2012)

    Article  Google Scholar 

  17. Wu, G., Koliadima, A., Her, Y.-S., Matijević, E.: Adsorption of dyes on nanosize modified silica particles. J. Colloid Interface Sci. 195, 222–228 (1997)

    Article  ADS  Google Scholar 

  18. Parida, S.K., Mishra, B.K.: Adsorption of styryl pyridinium dyes on polyethyleneglycol-treated silica. Colloids Surf. A Physicochem. Eng. Asp. 134, 249–255 (1998)

    Article  Google Scholar 

  19. Binkowski, S., Jesionowski, T., Krysztafkiewicz, A.: Preparation of pigments on modified precipitated silicas. Dyes Pigments. 47, 247–257 (2000)

    Article  Google Scholar 

  20. Harris, R.G., Wells, J.D., Johnson, B.B.: Selective adsorption of dyes and other organic molecules to kaolinite and oxides surfaces. Colloids Surf. A Physicochem. Eng. Asp. 180, 131–140 (2001)

    Article  Google Scholar 

  21. Neumann, M.G., Gessner, F., Schmitt, C.C., Sartori, R.: Influence of the layer charge and clay particle size on the interactions between the cationic dye methylene blue and clays in an aqueous suspension. J. Colloid Interface Sci. 255, 254–259 (2002)

    Article  ADS  Google Scholar 

  22. Rytwo, G., Nir, S., Crespin, M., Margulies, L.: Adsorption and interactions of methyl green with montmorillonite and sepolite. J. Colloid Interface Sci. 222, 12–19 (2000)

    Article  ADS  Google Scholar 

  23. Hajjaji, M., Kacim, S., Alami, A., Bouadili, A.E., Mauntassir, M.E.: Chemical and mineralogical characterization of a clay taken from the Moroccan Meseta and a study of the interaction between its fine fraction and methylene blue. Appl. Clay Sci. 20, 1–12 (2001)

    Article  Google Scholar 

  24. Bujdák, J., Iyi, N., Hrobáriková, J., Fujita, T.: Aggregation and decomposition of a pseudoisocyanine dye in dispersions of layered silicates. J. Colloid Interface Sci. 247, 494–503 (2002)

    Article  ADS  Google Scholar 

  25. Bujdák, J., Iyi, N.: Visible spectroscopy of cationic dyes in dispersions with reduced-charge montmorillonites. Clays Clay Minerals. 50, 446–454 (2002)

    Article  ADS  Google Scholar 

  26. Jesionowski, T., Binkowski, S., Krysztafkiewicz, A.: Adsorption of the selected organic dyes on the functionalized surface of precipitated silica via emulsion route. Dyes Pigments. 65, 267–279 (2005)

    Article  Google Scholar 

  27. Jesionowski, T., Andrzejewska, A., Krysztafkiewicz, A.: Adsorption of basic dyes from model aqueous solutions onto novel spherical silica support. Color. Technol. 124, 165–172 (2008)

    Article  Google Scholar 

  28. Winnik, F.M., Keoshkerian, B., Fuller, J.R., Hofstra, P.G.: New water-dispersible silica-based pigments: synthesis and characterization. Dyes Pigments. 14, 101–112 (1990)

    Article  Google Scholar 

  29. Faulkner, D.J.: Marine natural products. Nat. Prod. Rep. 18, 1–49 (2001)

    Article  Google Scholar 

  30. Munro, M.H.G., Blunt, J.W., Dumdei, E.J., Hickford, S.J.H., Lill, R.E., Li, S., Battershill, C.N., Duckworth, A.R.: The discovery and development of marine compounds with pharmaceutical potential. J. Biotechnol. 70, 15–25 (1999)

    Article  Google Scholar 

  31. Lüer, S., Troller, R., Aebi, C.: Antibacterial and antiinflammatory kinetics of curcumin as a potential antimucositis agent in cancer patients. Nutr. Cancer. 64, 975–981 (2012)

    Article  Google Scholar 

  32. Bonarska-Kujawa, D., Cyboran, S., Żyłka, R., Oszmiański, J., Kleszczyńska, H.: Biological activity of blackcurrant extracts (Ribes nigrum L.) in relation to erythrocyte membranes. Biomed Res. Int. 2014, 1–14 (2014)

    Article  Google Scholar 

  33. Cavalcanti, R.N., Santos, D.T., Meireles, M.A.: Non-thermal stabilization mechanisms of anthocyanins in model and food systems-an overview. Food Res. Int. 44, 499–509 (2011)

    Article  Google Scholar 

  34. Shahid, M., Mohammad, F.: Recent advancements in natural dye applications: a review. J. Clean. Prod. 53, 310–331 (2013)

    Article  Google Scholar 

  35. Hug, H., Bader, M., Mair, P., Glatzel, T.: Biophotovoltaics: natural pigments in dye-sensitized solar cells. Appl. Energy. 115, 216–225 (2014)

    Article  Google Scholar 

  36. Borges, M.E., Tejera, R.L., Díaz, L., Esparza, P., Ibáñez, E.: Natural dyes extraction from cochineal (Dactylopius coccus). New extraction methods. Food Chem. 132, 1855–1860 (2012)

    Article  Google Scholar 

  37. Paulsen, N., Johnson, R., Coffee, M.: Process for manufacturing chewable dosage forms for drug delivery and products thereof. U.S. 20070128251 A1 patent, (2007)

    Google Scholar 

  38. Park, K.H., Kim, T.Y., Park, J.Y., **, E.M., Yim, S.H., Choi, D.Y., Lee, J.W.: Adsorption characteristics of gardenia yellow as natural photosensitizer for dye-sensitized solar cells. Dyes Pigments. 96, 595–601 (2013)

    Article  Google Scholar 

  39. Friedman, M.: Antibacterial, antiviral, and antifungal properties of wines and winery byproducts in relation to their flavonoid content. J. Agric. Food Chem. 62, 6025–6042 (2014)

    Article  Google Scholar 

  40. Thomasset, S., Berry, D.P., Cai, H., West, K., Marczylo, T.H., Marsden, D., Brown, K., Dennison, A., Garcea, G., Miller, A., Hemingway, D., Steward, W.P., Gescher, A.J.: Pilot study of oral anthocyanins for colorectal cancer chemoprevention. Cancer Prev. Res. 2, 625–633 (2009)

    Article  Google Scholar 

  41. Hayatsu, H., Sugiyama, C., Arimoto-Kobayashi, S., Negishi, T.: Porphyrins as possible preventers of heterocyclic amine carcinogenesis. Cancer Lett. 143, 185–187 (1999)

    Article  Google Scholar 

  42. Aozasa, O., Tetsumi, T., Ohta, S., Nakao, T., Miyata, H., Nomura, T.: Fecal excretion of dioxin in mice enhanced by intake of dietary fiber bearing chlorophyllin. Bull. Environ. Contam. Toxicol. 70, 359–366 (2003)

    Article  Google Scholar 

  43. Yamazaki, H., Fujieda, M., Togashi, M., Saito, T., Preti, G., Cashman, J.R., Kamataki, T.: Effects of the dietary supplements, activated charcoal and copper chlorophyllin, on urinary excretion of trimethylamine in Japanese trimethylaminuria patients. Life Sci. 74, 2739–2747 (2004)

    Article  Google Scholar 

  44. Falabella, A.: Debridement and wound bed preparation. Dermatol. Ther. 19, 317–325 (2006)

    Article  Google Scholar 

  45. Wohrle, D., Schnurpfeil, G., Makarov, S.G., Kazarin, A., Suvorova, O.N.: Practical applications of phthalocyanines – from dyes and pigments to materials for optical, electronic and photo-electronic devices. Macroheterocycles. 5, 191–202 (2012)

    Article  Google Scholar 

  46. Yao, Y., Chen, W., Lu, S., Zhao, B.: Binuclear metallophthalocyanine supported on treated silk fibres as a novel air-purifying material. Dyes Pigments. 73, 217–223 (2007)

    Article  Google Scholar 

  47. Rismayani, S., Fukushima, M., Sawada, A., Ichikawa, H., Tatsumi, K.: Effects of peat humic acids on the catalytic oxidation of pentachlorophenol using metalloporphyrins and metallophthalocyanines. J. Mol. Sci. A Chem. 217, 13–19 (2004)

    Article  Google Scholar 

  48. Wei, Z., Cao, Y., Ma, W., Wang, C., Xu, W., Guo, X., Hu, W., Zhu, D.: Langmuir–Blogett monolayer transistors of copper phthalocyanine. Appl. Phys. Lett. 95, 33304 (2009)

    Article  Google Scholar 

  49. Białek, B., Kim, I.G., Lee, J.I.: Electronic structure of copper phthalocyanine monolayer: a first-principles study. Thin Solid Films. 436, 107–114 (2003)

    Article  ADS  Google Scholar 

  50. Norman, M., Bartczak, P., Zdarta, J., Ehrlich, H., Jesionowski, T.: Anthocyanin dye conjugated with Hippospongia communis marine demosponge skeleton and its antiradical activity. Dyes Pigments. 134, 541–552 (2016)

    Article  Google Scholar 

  51. Al-Degs, Y.S., El-Barghouthi, M.I., El-Sheikh, A.H., Walker, G.M.: Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon. Dyes Pigments. 77, 16–23 (2008)

    Article  Google Scholar 

  52. Gómez, J.M., Galán, J., Rodríguez, A., Walker, G.M.: Dye adsorption onto mesoporous materials: pH influence, kinetics and equilibrium in buffered and saline media. J. Environ. Manag. 146, 355–361 (2014)

    Article  Google Scholar 

  53. Norman, M., Bartczak, P., Zdarta, J., Tomala, W., Żurańska, B., Dobrowolska, A., Piasecki, A., Czaczyk, K., Ehrlich, H., Jesionowski, T.: Sodium copper chlorophyllin immobilization onto Hippospongia communis marine demosponge skeleton and its antibacterial activity. Int. J. Mol. Sci. 17, 1–17 (2016)

    Article  Google Scholar 

  54. Norman, M., Żółtowska-Aksamitowska, S., Zgoła-Grześkowiak, A., Ehlich, H., Jesionowski, T.: Iron(III) phthalocyanine supported on a spongin scaffold as an advanced photocatalyst in a highly efficient removal process of halophenols and bisphenol A. J. Hazard. Mater. 347, 78–88 (2018)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Polish Ministry of Science and Education. Authors would like to thank Małgorzata Norman, PhD, for her participation and contribution in preparing the updated version of the subsection ‘Colored bioorganic-based hybrid pigments’.

Author information

Authors and Affiliations

  1. Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, Poznan, Poland

    Teofil Jesionowski & Filip Ciesielczyk

Authors
  1. Teofil Jesionowski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Filip Ciesielczyk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Teofil Jesionowski .

Editor information

Editors and Affiliations

  1. Color Science & Imaging Lab, North Carolina State Univ, Raleigh, NC, USA

    Renzo Shamey

Section Editor information

  1. Fiber and Polymer Science Program, North Carolina State University, Raleigh, NC, USA

    Harold S Freeman

Rights and permissions

Reprints and permissions

Copyright information

© 2021 Springer Science+Business Media LLC

About this entry

Check for updates. Verify currency and authenticity via CrossMark

Cite this entry

Jesionowski, T., Ciesielczyk, F. (2021). Inorganic, Hybrid and Functional Pigments. In: Shamey, R. (eds) Encyclopedia of Color Science and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-27851-8_180-2

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-27851-8_180-2

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-27851-8

  • Online ISBN: 978-3-642-27851-8

  • eBook Packages: Springer Reference Physics and AstronomyReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics

Chapter history

  1. Latest

    Inorganic, Hybrid and Functional Pigments
    Published:
    13 July 2021

    DOI: https://doi.org/10.1007/978-3-642-27851-8_180-2

  2. Original

    Pigment, Inorganic
    Published:
    29 October 2014

    DOI: https://doi.org/10.1007/978-3-642-27851-8_180-1

Search

Navigation