Abstract
Mechanisms of colloid-facilitated transport of radionuclides by groundwater are considered for three types of radioactive colloids: intrinsic colloids, primary colloids and pseudocolloids. Effect of elevated velocity of colloid facilitated migration is analyzed. The general characteristic is introduced for the estimation of the role of colloidal species of radionuclide migration velocity. A new probabilistic model of colloid retardation by the host rocks is developed taking into account heterogeneity of the colloid particles.
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References
Airey PL (1986) Radionuclide migration around uranium ore bodies in the Alligator Rivers region of the northern territory of Australia – analogue of radioactive waste repositories – a review. Chem Geol, 55:255–268
Amme M, Aldave de las Heras L, Betti M, Lang H, Stöckl M (2004) Effects of colloidal and dissolved silica on the dissolution of UO2 nuclear fuel in groundwater leaching tests. J Radioanalyt Nucl Chem, 261:327–336
Aoki H, Kurosaki Y, Anzai H (1979) Study on the tubular pinch effect in a pipe flow. Bull. Jpn Soc Mech Eng, 22:206–212
Artinger R, Kienzler B, Schüssler W, Kim JI (1998) Effects of humic substances on the 241Am migration in a sandy aquifer: column experiments with Gorleben ground-water/sediment systems. J Contamin Hydrol, 35:261–275
Bates JK, Bradley JP, Teetsov A, Bradley CR, Buchholtz ten Brink M (1992) Colloid formation during waste form reaction: Implication for nuclear waste disposal. Science, 256:649–651
Bochever FM, Oradovskaya AE (1972) Hydrogeological substantiation of protection of groundwater and water intakes from pollutions. Nedra, Moscow
Buck EC, Bates JK (1999) Microanalysis of colloids and suspended particles from nuclear waste glass alteration. Appl Geochem, 14:635–659
Buesseler KO, Bauer JE, Chen RF, Eglinton TI, Gustafsson O, Landing W, Mopper K, Moran SB, Santschi PH, VernonClark R, Wells ML (1996) An intercomparison of cross-flow filtration techniques used for sampling marine colloids: Overview and organic carbon results. Mar Chem, 55:1–31
Champ DR, Schroeter J (1988) Bacterial transport in fractured rock – a field-scale tracer test at the Chalk River nuclear laboratories. Water Sci Technol, 20:81–87
Davis JA (1982) Adsorption of natural dissolved organic matter at the oxide/water interface. Geochim Cosmochim Acta, 46:2381–2393
Davis JA, Gloor R (1981) Adsorption of dissolved organics in lake water by aluminum oxide. Effect of molecular weight. Environ Sci Technol, 15:1223–1229
deMarsily G (1986) Quantitative hydrogeology. Academic, Orlando
Ebert WL, Bates JK (1993) A comparison of glass reaction at high and low glass surface/solution volume. Nucl Tech, 104:372–384
Eichholz GG, Wahlig BG, Powell GF, Craft TF (1982) Subsurface migration of radioactive waste materials by particulate transport. Nucl Tech, 58:511–520
Elimelech M, Nagai M, Ko CH, Ryan JN (2000) Relative insignificance of mineral grain zeta potential to colloid transport in geochemically heterogeneous porous media. Environ Sci Technol, 34:2143–2148
Fairhurst AJ, Warwick P, Richardson S (1995) The influence of humic acid on the absorption of europium onto inorganic colloids as a function of pH. Coll Surf A, 99:187–199
Fane AG, Fell CJD, Waters AG (1981) The relationship between membrane surface pore characteristics and flux for ultrafiltration membranes. J Membr Sci, 9:245–262
Finn PA, Buck EC, Gong M, Hoh JC, Emery JW, Hafenrichter LD, Bates JK (1994) Colloidal products and actinide species in leachate from spent nuclear fuel. Radiochim Acta, 66/67:189–195
Fortner JA, Mertz CJ, Wolf SF, Jemian PR (2003) Natural groundwater colloids from the USGS J-13 well in Nye county, NV: a study using SAXS and TEM. In: Finch RJ, Bullen DB (eds) Scientific basis for nuclear waste management XXVIV. Mater Res Soc Proc, 757:483–488
Frolov YuG (1988) Colloid chemistry course. Surface effects and dispersed system. Khimiya, Moscow
Gardiner CW (1983) Handbook of stochastic methods for physics, chemistry, and the natural sciences. Springer, Berlin
Glagolenko YuV, Dzekun EG, Drozhko EG (1996) Strategy of radioactive waste management at production association “Mayak”. Voprosy radiatsionnoy bezopasnosti, 2:3–10
Gregg SJ, Sing KSW (1967) Adsorption, surface area, and porosity. Academic Press. London
Hara K, Takeda S, Masuda S (1996) Research and development program of geological disposal of high-level radioactive waste in Japan. In: Proc. Int. conf. on deep geological disposal of radioactive waste, September 16-19, 1996. Winnipeg, Canada, 1-3 – 1-21
Harrington RV, Apps JA (1982) Solidification of high-level waste. Undergr Space, 6:259–263
Harvey RW, Garabedian SP (1991) Use of colloid filtration theory in modeling movement of bacteria through contaminated sandy aquifer. J Contamin Hydrol, 25:178–185
Harvey RW, George LH, Smith R, LeBlanc DR (1989) Transport of microspheres and indigenous bacteria through a sandy aquifer: results of natural- and forced-gradient tracer experiments. Environ Sci Technol, 23:51–56
Inagaki Y, Sakata H, Idemitsu K, Arima T, Banda T, Maeda T, Matsumoto S, Tamura Y, Kikkawa S (1998) Effects of eatwr redox conditions and presence of magnetite on leaching of Pu and Np from HLW glass. In: McKinley IG, McCombie C (eds) Scientific basis for nuclear waste management XXI. Mater Res Soc Proc 506:177–184
Kersting AB, Efurd DW, Finnegan DL, Rokop DJ, Smith DK, Thompson JL (1999) Migration of plutonium in ground water at the Nevada Test Site. Nature, 397:56–59
Keswick BH, Gerba CP (1980) Viruses in groundwater. Environ Sci Technol 14:1290–1297
Kim JI, Delakowitz B, Zeh P, Klotz D, Lazik D (1994) A column experiment for the study of colloidal radionuclide migration in Gorleben aquifer system. Radiochim Acta, 66/67:165–171
Klyachko VA, Apel’tsyn IE (1971) Purification of natural water. Stroyizdat, Moscow
Knapp RB, Chiarappa ML, Durham WB (2000) An experimental exploration of the transport and capture of abiotic colloids in a single fracture. Water Resour Res, 36:3139–3149
Krauskopf KB (1988) Geology of high-level nuclear waste disposal. Annu Rev Earth Planet Sci, 16:173–200
Kretzschmar R, Schðfer Th (2005) Metal retention and transport on colloidal particles in the environment. Elements 1:205–210
Laverov NP (2006) Fuel-energy resources: state and conservation. In: National reference book “Fuel and energy complex of Russia”. Center of strategic programs, Moscow
Laverov NP, Kantsel AV, Lisitsyn AK (1991) Main problems of radiogeoecology concerning disposal of radioactive waste. Atomnaya Energiya, 71:523–534
Laverov NP, Omelyanenko BI, Velichkin VI (1994) Geoecological aspects of radioactive waste disposal. Geoecologiya, 6:3–20
Laverov NP, Velichkin VI, Omel’yanenko BI, Yudintsev SV (2003) Geochemistry of actinides during the long-term storage and disposal of spent nuclear fuel. Geol Ore Depos, 45:1–18
Ledin A, Karlsson S, Dücker A, Allard B (1994) The adsorption of Europium to colloidal iron oxyhydroxides and quartz – the impact of pH and an aquatic fulvic acid. Radiochim Acta, 66/67:213–230
Loitsiansky LG (1973) Mechanics of fluids and gases. Nauka, Moscow.
Malkovsky VI, Pek AA, Omelyanenko BI (1995) Influence of the inetrwell distance on the thermoconvective transport of radionuclides by groundwater from a two-well high-level nuclear waste repository. In: Slate S, Feizollahi F, Creer J (eds.) Cross-cutting issues and management of high-level waste and spent fuel, 5th International conference on radioactive waste management and environmental remediation, Berlin, September 3–7, 1995. ASME, New York
Malkovsky VI, Pek AA, Velichkin VI (1997) Transport of radionuclides from HLW repository by regional flow of groundwater. Voprosy radiatsionnoy bezopasnosti, 4:9–15
Malkovsky VI, Dikov YuP, Kalmykov SN, Buleev MI (2009) Structure of colloid particles in groundwaters on the territory of the Mayak Production Association and its impact on the colloid transport of radionuclides in subsoil environments. Geochem Int, 47:1100–1106
McCarthy J, Czerwinski KR, Sanford WE, Jardine PM, Marsh JD (1998a) Mobilization of transuranic radionuclides from disposal trenches by natural organic matter. J Contamin Hydrol, 30:49–77
McCarthy JF, Sanford WE, Stafford PL (1998b) Lanthanide field tracers demonstrate enhanced transport of transuranic radionuclides by natural organic matter. Environ Sci Technol, 32:3901–3906
McTigue DF, Givler RC, Nunziato JW (1986) Rheological effects of nonuniform particle distribution in dilute suspensions. J Rheol, 30:1053–1076
Mercier F, Moulin V, Barre N, Casanova F, Toulhoat P (2001) Study of the repartition of metallic trace elements in humic acids colloids: potentialities of nuclear microprobe and complementary technique. Anal Chim Acta, 427:101–110
Mironenko VA, Rumynin VG (1998) Problems of geoecology. Vol. 1. Moscow Mining University, Moscow
Missana T, Turrero MJ, Adell A (2000) Surface cherge and electrophoretic properties of colloids obtained from homoionic and natural bentonite. In: Smith RW, Shoesmith DW (eds). Scientific basis for nuclear waste management XXIII. Mater Res Soc Proc, 608:255–260
Morel FMM, Gschwend PM (1987) The role of colloids in the partitioning of solutes in natural waters. In: Stumm W (ed) Aquatic surface chemistry. Wiley, New York
Nyhan JW, Drennon BJ, Abeele WV, Wheeler ML, Purtymun WD, Trujillo G, Herrera WJ, Booth JW (1985) Distribution of plutonium and americium beneath a 33-yr-old liquid waste disposal site. J Environ Qual, 14:501–509
O’Melia CR (1987) Particle-particle interaction. In: Stumm W (ed) Aquatic surface chemistry. Wiley, New York
Olofsson U, Allard B, Torstenfelt B, Andersson K (1982) Properties and mobilities of actinide colloids in geologic systems. In: Lutze W (ed) Scientific basis for nuclear waste management V. Elsevier, New York
Orlandini KA, Penrose WR, Harvey BR, Lovett MB, Findlay MW (1990) Colloidal behavior of actinides in an oligotrophic lake. Environ Sci Tech, 24:706–712
Penrose WR, Polzer WL, Essington EH, Nelson DM, Orlandini KA (1990) Mobility of plutonium and americium through a shallow aquifer in a semiarid region. Environ Sci Technol, 24:228–234
Pham MK, Garnier JM (1998) Distribution of trace elements associated with dissolved compounds (<0.45 μm – 1nm) in freshwater using coupled (frontal cascade) ultrafiltration and chromatographic separations. Environ Sci Technol, 32:440–449
Puls RW, Powell RM (1992) Transport of inorganic colloids through neutral aquifer material: implications for contaminant transport. Environ Sci Technol, 26:614–621
Ringwood AE (1980) Safe disposal of high-level radioactive wastes. Fortschritt in Mineralogie, 58:149–168
Roache PJ (1976) Computational fluid dynamics. Hermosa, Albuquerque
Ryan JN, Elimelech M (1996) Colloid mobilization and transport in groundwater. Coll Surf A, 107:1–56
Ryan JN, Elimelech M, Ard RA, Harvey RW, Johnson PR (1999) Bacteriophage PRD1 and silica colloid transport and recovery in an iron oxide-coated sand aquifer. Environ Sci Technol, 33:63–73
Saffman PG (1965) The lift on a small sphere in a slow shear flow. J Fluid Mech, 22:385–400
Salbu B, Bjørnstaad HE (1990) Analytical techniques for determining radionuclides associated with colloids in waters. J Radioanal Nucl Chem, 138:337–346
Schäfer Th, Artinger R, Dardenne K, Bauer A, Schuessler W, Kim JI (2003) Colloid-borne americium migration in Gorleben groundwater: significance of iron secondary phase transformation. Environ Sci Tech, 37:1528–1534
Shonnard DR, Taylor RT, Hanna ML, Boro CO, Duba AG (1994) Injection-attachment of Methylosinus trichosporium OB3b in a two-dimensional miniature sand-filled aquifer simulator. Water Resour Res, 30:25–35
Short SA, Lowson RT (1988) 234U/238U and 230Th/234U activity ratios in the colloidal phases of aquifers in lateritic weathered zones. Geochim Cosmochim Acta, 52:2555–2563
Smith PA, Degueldre C (1993) Colloid-facilitated transport of radionuclides through fractured media. J Contamin Hydrol, 13:143–166
Smith DK, Finnegan DL, Bowen SM (2003) An inventory of long-lived radionuclides residual from underground nuclear testing at the Nevada test site, 1951–1992. J Environ Rad, 67:35–51
Spielman LA (1977) Particle capture from low-speed laminar flows. In: Van Dyke M, Wehausen JV, Lumley JL (eds) Annual review of fluid mechanics. vol. 9. Annual Review, Palo Alto
Tait JC, Hayward PJ, Devgun JC (1989) Technologies for contaminant immobilization, and disposal of radioactive wastes. Can J Civ Eng, 16:444–458
Tip** E (1981) The adsorption of aquatic humic substances by iron oxides. Geochim Cosmochim Acta, 45:191–199
Vilks P, Degueldre C (1991) Sorption behaviour of 85Sr, 131I and 137Cs on colloids and suspended particles from the Grimsel test site, Switzerland. Appl Geochem, 6:553–563
Vilks P, Miller HG, Doern DC (1991) Natural colloids and suspended particles in the Whiteshell Research Area, Manitoba, Canada, and their potential effect on radiocolloid formation. Appl Geochem, 6:565–574
Voloshuk VM (1984) Kinetic theory of coagulation. Gidrometeoizdat. Moscow
Zachara JM, Smith SC, Liu Ch, McKinley JP, Serne RJ, Gassman PL (2002) Sorption of Cs+ to micaceous subsurface sediments from the Hanford site, USA. Geochim Cosmochim Acta, 66:199–211
Zhuang J, Flury M, ** Y (2003) Colloid-facilitated Cs transport through water-saturated Hanford sediment and Ottawa sand. Environ Sci Technol, 37:4905–4911
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The author acknowledges support from International Science & Technology Center under Award Number 3290 and from Russian Foundation of Basic Research under Award Number 09-05-00347.
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Malkovsky, V. (2011). Theoretical Analysis of Colloid-facilitated Transport of Radionuclides by Groundwater. In: Kalmykov, S., Denecke, M. (eds) Actinide Nanoparticle Research. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-11432-8_8
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