NQRS Data for Cl₁₁IrS₃ [Cl₈IrS₂·Cl₃S] (Subst. No. 1942)

Abstract

This document is part of Subvolume B 'Substances Containing C₁₀H₁₆ … Zn' of Volume 48 'Nuclear Quadrupole Resonance Spectroscopy Data' of Landolt-Börnstein - Group III 'Condensed Matter'. It contains an extract of Section '3.2 Data tables' of the Chapter '3 Nuclear quadrupole resonance data' providing the NQRS data for Cl₁₁IrS₃ [Cl₈IrS₂·Cl₃S] (Subst. No. 1942)

Subst. No.	1942
Formula	Cl11IrS3 [Cl8IrS2·Cl3S]
Name	Sulfur(1+), trichloro-, (OC-6-22)-tetrachlorobis(monosulfur dichloride)iridate(1−)
CASRN	146995-66-6

Meth.	Nucl.	T [K]	QCC [MHz]	η	ν [MHz]	Rem.	Ref.
P	Cl-35	77			42.015	1	[1]
P	Cl-35	77			41.125	1	[1]
X	Cl-35	N.S.			42.015		[2]
X	Cl-35	N.S.			41.125		[2]
X	Cl-35	N.S.			40.835		[2]
X	Cl-35	N.S.			40.205		[2]
X	Cl-35	N.S.			39.945		[2]
X	Cl-35	N.S.			39.593		[2]
X	Cl-35	N.S.			24.542		[2]
X	Cl-35	N.S.			22.054		[2]
X	Cl-35	N.S.			18.720		[2]

Remark

• 1 Nine Cl-35 NQR lines are reported for a mixture of [IrCl₃(SCl₂)₂]₂ and (SCl₃)[IrCl₄(SCl₂)₂]. Frequencies are assigned to the latter compound and correspond to Cl-35 in Cl-S bonds.