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Halogen-Rich Minerals: Crystal Chemistry and Geological Significances

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The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes

Part of the book series: Springer Geochemistry ((SPRIGEO))

Abstract

Halogen-rich minerals containing at least one halogen (F, Cl, Br or I) on a dominant crystallographic site can be divided into three broad groups: (1) halides, (2) halogenates, and (3) native halogens. There are approximately 700 halogen-rich minerals in the 09/2014 list of species approved by the International Mineralogical Association (IMA), accounting for ~15% of the entire mineral kingdom known to date. Still scores of other minerals contain significant amounts of F and/or Cl, especially in many hydrous minerals via the copious substitution (F,Cl)− = OH−. Amphiboles, micas and apatites are the dominant carriers of halogens in most rocks, whereas scapolites and sodalites serve as important hosts of these elements in some exotic lithologies. These minerals not only play important roles in controlling the halogen geochemical cycles but also are useful for calcuating the halogen composition and evolution of fluids/melts from which they crystallized.

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Acknowledgements

We thank Dr. Daniel Harlov for invitation to write this chapter and Drs. John M. Hughes and Andrew M. McDonald for constructive reviews and many helpful suggestions. YMP also thanks Dr. Wei Sun for assistance with drafting of four figures as well as CAS/SAFEA IPP for CRT project 20140491534 and NSERC for financial support.

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Authors and Affiliations

  1. Fujian Provincial Key Laboratory of Advanced Materials, Department of Materials Science and Engineering College of Materials, **amen University, 361005, **amen, People’s Republic of China

    **-**ao Mi

  2. Department of Geological Sciences, University of Saskatchewan, 114 Science Place, SK S7N 5E2, Saskatoon, Canada

    Yuanming Pan

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  1. **-**ao Mi
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  1. Deutsches GeoForschungsZentrum, Potsdam, Germany

    Daniel E. Harlov

  2. Institute of Ore Geology, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Moscow, Russia

    Leonid Aranovich

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Mi, JX., Pan, Y. (2018). Halogen-Rich Minerals: Crystal Chemistry and Geological Significances. In: Harlov, D., Aranovich, L. (eds) The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes. Springer Geochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-61667-4_3

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