Photocatalytic H2 Production under Visible Light Irradiation on Novel Heterostructure Nis/Zns Nanosheet Photocatalyst

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Characterization of Minerals, Metals, and Materials 2015

Abstract

The sheet-like NiS-ZnS heterostructured composites were prepared by the microwave hydrothermal. The fabrication of the heterojunctions broadened the range of light response of ZnS. The photoexcited electrons of ZnS migrated to the redox potential of NiS/Ni2S under visible light irradiation, which can facilitate the effective separation of photogenerated electrons and holes in space. The visible photocatalytic activity towards hydrogen production for NiS/ZnS nanosheet heterostructed composites without co-catalyst achieved 0.28 mmol h−1, and the quantum efficiency was up to 18.6% under the wavelength with 420 nm visible light irradiation.

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References

  1. R.D. Cortright, R.R. Davda, and J.A. Dumesic. “Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water,” Nature, 418(6901)(2002), 964–967.

    Article  Google Scholar 

  2. Turner and A. John. “Sustainable hydrogen production,” Science, 305(5686) (2004), 972–974.

    Article  Google Scholar 

  3. Kasuga, Tomoko, et al. “Formation of titanium oxide nanotube,” Langmuir, 14(12) (1998), 3160–3163.

    Article  Google Scholar 

  4. Kudo, Akihiko, and Yugo Miseki. “Heterogeneous photocatalyst materials for water splitting,” Chemical Society Reviews, 38(1) (2009), 253–278.

    Article  Google Scholar 

  5. Kim, Hyun Gyu, Dong Won Hwang, and Jae Sung Lee. “An undoped, single-phase oxide photocatalyst working under visible light,” Journal of the American Chemical Society, 126(29) (2004), 8912–8913.

    Article  Google Scholar 

  6. J.G.. Yu, L.F. Qi, and Mietek Jaroniec. “Hydrogen production by photocatalytic water splitting over Pt/TiO2 nanosheets with exposed (001) facets,” The Journal of Physical Chemistry, 114(30) (2010), 13118–13125.

    Google Scholar 

  7. X.B. Chen, and Samuel S. Mao. “Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications,” Chemical reviews, 107(7) (2007), 2891–2959.

    Article  Google Scholar 

  8. Linsebigler, L. Amy, G..Q. Lu, and T. John Yates Jr. “Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results.” Chemical reviews 95.3 (1995): 735–758.

    Article  Google Scholar 

  9. J.G. Yu, J. Zhang and S.W. Liu. “Ion-exchange synthesis and enhanced visible-light photoactivity of CuS/ZnS nanocomposite hollow spheres.” The Journal of Physical Chemistry, 114(32) (2010), 13642–13649.

    Google Scholar 

  10. J.G. Yu, and J. Zhang. “A simple template-free approach to TiO2 hollow spheres with enhanced photocatalytic activity,” Dalton Transactions, 39(25) (2010), 5860–5867.

    Article  Google Scholar 

  11. Matsumura, Michio, et al. “Cadmium sulfide photocatalyzed hydrogen production from aqueous solutions of sulfite: effect of crystal structure and preparation method of the catalyst,” The Journal of Physical Chemistry, 89(8) (1985), 1327–1329.

    Article  Google Scholar 

  12. Reber, Jean Francois, and Milos Rusek. “Photochemical hydrogen production with platinized suspensions of cadmium sulfide and cadmium zinc sulfide modified by silver sulfide,” The Journal of Physical Chemis y C , 90(5) (1986), 824–834.

    Article  Google Scholar 

  13. Frank, Arthur J., and Kenji Honda. “Visible-light-induced water cleavage and stabilization of n-type cadmium sulfide to photocorrosion with surface-attached polypyrrole-catalyst coating,” The Journal of Physical Chemistry C , 86(11)(1982), 1933–1935.

    Article  Google Scholar 

  14. N.Z. Bao, et al. “Facile Cd-thiourea complex thermolysis synthesis of phase-controlled CdS nanocrystals for photocatalytic hydrogen production under visible light,” The Journal of Physical Chemistry C, 111(47) (2007), 17527–17534.

    Article  Google Scholar 

  15. Maeda, Kazuhiko, and Kazunari Domen. “New non-oxide photocatalysts designed for overall water splitting under visible light,” The Journal of Physical Chemistry C, 111(22) (2007), 7851–7861.

    Article  Google Scholar 

  16. Ohno, Tomoyuki, et al. “Photocatalytic water splitting using modified GaN: ZnO solid solution under visible light: long-time operation and regeneration of activity,” Journal of the American Chemical Society, 134(19) (2012), 8254–8259.

    Article  Google Scholar 

  17. Kato, Hideki, Kiyotaka Asakura, and Akihiko Kudo. “Highly efficient water splitting into H2 and O2 over lanthanum-doped NaTaO3 photocatalysts with high crystallinity and surface nanostructure,” Journal of the American Chemical Society 125(10)(2003), 3082–3089.

    Article  Google Scholar 

  18. J. Bandara, C. P. K. Udawatta, and C. S. K. Rajapakse. “Highly stable CuO incorporated TiO2 catalyst for photocatalytic hydrogen production from H2O,” Photochemical & Photobiological Sciences, 4(11) (2005), 857–861.

    Article  Google Scholar 

  19. J.G. Yu, J. Zhang, and Mietek Jaroniec. “Preparation and enhanced visible-light photocatalytic H 2-production activity of CdS quantum dots-sensitized Zn 1- x Cd x S solid solution,” Green Chemistry 12(9) (2010), 1611–1614.

    Article  Google Scholar 

  20. Innocenti, M., et al. “Ternary cadmium and zinc sulfides: composition, morphology and photoelectrochemistry,” Electrochimica acta, 49(8) (2004), 1327–1337.

    Article  Google Scholar 

  21. Yoshimura, Joji, et al. “Visible Light Induced Hydrogen Evolution on CdS/K4Nb6O17 Photocatalyst,” Bulletin of the chemical society of Japan, 68(8) (1995), 2439–2445.

    Article  Google Scholar 

  22. H. Zhang, and Y.F. Zhu. “Significant visible photoactivity and antiphotocorrosion performance of CdS photocatalysts after monolayer polyaniline hybridization,” The Journal of Physical Chemistry C, 114(13) (2010), 5822–5826.

    Article  Google Scholar 

  23. Jang, Jum Suk, et al. “Role of platinum-like tungsten carbide as cocatalyst of CdS photocatalyst for hydrogen production under visible light irradiation,” Applied Catalysis A: General, 346(1)(2008), 149–154.

    Article  Google Scholar 

  24. Bataille, Frédéric, et al. “Alkyldibenzothiophenes hydrodesulfurization-promoter effect, reactivity, and reaction mechanism,” Journal of catalysis,191(2)(2000), 409–422.

    Article  Google Scholar 

  25. Chianelli, Russell R., et al. “Catalytic properties of single layers of transition metal sulfide catalytic materials,” Catalysis Reviews , 48(1) (2006), 1–41.

    Article  Google Scholar 

  26. Moses, Poul Georg, et al. “Corrigendum to The hydrogenation and direct desulfurization reaction pathway in thiophene hydrodesulfurization over MoS2 catalysts at realistic conditions: A density functional study,” Journal of Catalysis, 260(1)(2008), 202–203.

    Article  Google Scholar 

  27. Y.P. Bi, et al. “Facile synthesis of rhombic dodecahedral AgX/Ag 3 PO 4 (X= Cl, Br, I) heterocrystals with enhanced photocatalytic properties and stabilities,” Physical Chemistry Chemical Physics, 13(21) (2011), 10071–10075.

    Article  Google Scholar 

  28. Z. Xu, et al. “Photocatalytic H2 evolution on MoS2/CdS catalysts under visible light irradiation,” The Journal of Physical Chemistry C, 114(4) (2010), 1963–1968.

    Article  Google Scholar 

  29. H. J. Yan, J. H. Yang, G. J. Ma, G. P. Wu, X. Zong, Z. B. Lei, J. Y. Shi, C. Li, Visible-lightdriven hydrogen production with extremely high quantum efficiency on Pt–PdS/CdS photocatalyst. Journal of catalysis, 266(2009), 165–168.

    Article  Google Scholar 

  30. Reber, Jean Francois, and Milos Rusek. “Photochemical hydrogen production with platinized suspensions of cadmium sulfide and cadmium zinc sulfide modified by silver sulfide,” The Journal of Physical Chemistry , 90(5) (1986), 824–834.

    Article  Google Scholar 

  31. S.H. Shen, et al. “Effect of Ag2 S on solar-driven photocatalytic hydrogen evolution of nanostructured CdS,” international journal of hydrogen energy, 35(13) (2010), 7110–7115.

    Article  Google Scholar 

  32. H.P. Liu, et al. “SrS/CdS composite powder as a novel photocatalyst for hydrogen production under visible light irradiation,” International Journal of Hydrogen Energy, 35(13) (2010), 7080–7086.

    Article  Google Scholar 

  33. J. Zhang, J. G. Yu, M. Jaroniec. “Noble metal-free reduced graphene oxide-ZnxCd1-xS nanocomposite with enhanced solar photocatalytic H2-production performance,”. Nano Letter., 12 (2012),: 4584–4589.

    Article  Google Scholar 

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Li, L., Chen, J., Hwang, JY., Liu, J., Zhou, Y., Lu, L. (2015). Photocatalytic H2 Production under Visible Light Irradiation on Novel Heterostructure Nis/Zns Nanosheet Photocatalyst. In: Carpenter, J.S., et al. Characterization of Minerals, Metals, and Materials 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48191-3_98

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