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Solid-Phase Microextraction

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Microextraction Techniques

Part of the book series: Integrated Analytical Systems ((ANASYS))

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Abstract

Sample preparation represents a pivotal stage within the analytical workflow. This chapter delves into the latest advancements in solid-phase microextraction (SPME), a technology renowned for its ability to facilitate uncomplicated, highly sensitive, swift, and solvent-free extraction of analytes from gaseous, liquid, and solid samples. This versatile approach extends its utility to trace-level analysis of compounds even within intricate matrices. Consequently, SPME has emerged as a preeminent sample preparation technique in the past decade, frequently employed in the form of an automated fiber-injection system in conjunction with chromatographic separation modules. Its primary application pertains to the extraction of volatile and semi-volatile organic compounds.

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Abbreviations

SPME:

Solid-phase microextraction

GC:

Gas chromatography

LC:

Liquid chromatography

MS:

Mass spectrometry

FID:

Flame ionization detector

HS:

Headspace

DI:

Direct immersion

LOD:

Limit of detection

MOF:

Metal organic framework

COF:

Covalent organic framework

PDMS:

Polydimethylsiloxane

PAN:

Polyacrylonitrile

DVB:

divinylbenzene

MWCNTs:

Multiwalled carbon nanotubes

Car:

Carboxen

GO:

Graphene oxide

HLB:

Hydrophilic-lipophilic balance

NPs:

Nanoparticles

OPPs:

Organophosphorous pesticides

PAHs:

Polycyclic aromatic hydrocarbons

PAEs:

Phthalate esters

PCBs:

Polychlorinated biphenyls

PFASs:

Per- and polyfluorinated alkyl substances

PPY:

Polypyrrole

PANI:

Polyaniline

PAN:

Polyacrylonitrile

PEG:

Polyethylene glycol

PA:

Polyacrylate

TF-SPME:

Thin-film solid-phase microextraction

VOCs:

Volatile organic compounds

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Acknowledgements

The authors would like to thank the Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grant program and Canada Research Chairs program for their support.

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  1. Department of Chemistry, University of Waterloo, Waterloo, ON, Canada

    Khaled Murtada & Janusz Pawliszyn

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  1. Khaled Murtada
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Correspondence to Khaled Murtada or Janusz Pawliszyn .

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  1. Department of Chemistry, University of La Laguna, San Cristóbal de La Laguna, Spain

    Miguel Ángel Rodríguez-Delgado

  2. Department of Chemistry, University of La Laguna, San Cristóbal de La Laguna, Spain

    Bárbara Socas-Rodríguez

  3. Department of Chemistry, University of La Laguna, San Cristóbal de La Laguna, Spain

    Antonio V. Herrera-Herrera

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Murtada, K., Pawliszyn, J. (2024). Solid-Phase Microextraction. In: Rodríguez-Delgado, M.Á., Socas-Rodríguez, B., Herrera-Herrera, A.V. (eds) Microextraction Techniques. Integrated Analytical Systems. Springer, Cham. https://doi.org/10.1007/978-3-031-50527-0_4

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