Abstract
This study provides baseline concentrations of major, trace (TE), and rare-earth elements (REEs) in the tropical lake bottom sediments and links the spatial variability of the elements to the controlling geochemical factors. The surface bottom sediment samples were collected in 10 water reservoirs in the Dak Lak Province of Central Vietnam. The concentrations of 57 elements were determined by atomic emission and inductively coupled plasma mass spectrometry (ICP-AES; ICP-MS). The potential contamination of bottom sediments was evaluated by calculating the geo-accumulation index (Igeo) and enrichment factor (EFAl and EFFe). The special goal of this study was the calculation of the local enrichment factor (LEF). Cluster analysis (CA) and principal component analysis (PCA) were applied to the enrichment factor distribution in order to indicate the element associations and their geochemical sources in various lakes. The values of the geochemical indices suggest low pollution of the lake bottom sediments. The found LEF values may be used as a background for long-term monitoring of potential hazardous elements in the region. Multivariate analysis shows that high spatial variability of element concentrations in lake bottom sediments is related to mineralogical provenance rather than to the age of the water reservoir, organic matter, and granulometric fraction content. The results suggest that application of the selected multivariate analyses (CA and PCA) to enrichment factor (EFFe) distribution has potential as a tool for identifying risk-elements and fingerprinting geochemical provenance even if applied to the limited geochemical data set.
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References
Koukina, S. E., Lobus, N. V., & Shatravin, A. V. (2021a). Multi-element signatures in solid and solution phases in a tropical mixing zone: A case study in the Cai River estuary, Vietnam. Chemosphere, 280, 130951. https://doi.org/10.1016/j.chemosphere.2021.130951
Koukina, S. E., Lobus, N. V., & Shatravin, A. V. (2021b). Dataset on the abundance, enrichment and partitioning of chemical elements between the filtered, particulate and sedimentary phases in the Cai River estuary (South China Sea). Data in Brief, 38. https://doi.org/10.1016/j.dib.2021.107412
Lobus, N. V., Peresypkin, V. I., Shulga, N. A., Drozdova, A. N., & Gusev, E. S. (2015). Dissolved, particulate, and sedimentary organic matter in the Cai River basin (Nha Trang bay of the south China sea). Oceanology, 55, 339–346. https://doi.org/10.1134/S0001437015030121
Matys Grygar, T., & Popelka, J. (2016). Revisiting geochemical methods of distinguishing natural concentrations and pollution by risk elements in fluvial sediments. Journal of Geochemical Exploration, 170, 39–57. https://doi.org/10.1016/j.gexplo.2016.08.003
Milnes, E., Negro, F., & Perrochet, P. (2015). Hydrogeological study of the Basaltic Plateau in Dak Lak province, Vietnam. CHYN—Baseline hydrogeological study.
Saleh, A. H., Gad, M., Khalifa, M. M., Elsayed, S., Moghanm, F. S., Ghoneim, A. M., Danish, S., Datta R., Moustapha, M. E., Abou El-Safa, M. M. (2021). Environmental pollution indices and multivariate modeling approaches for assessing the potentially harmful elements in bottom sediments of Qaroun Lake, Egypt. Journal of Marine Science and Engineering, 9, 1443. https://doi.org/10.3390/jmse9121443
Sojka, M., Choiński, A., Ptak, M., & Siepak, M. (2021). Causes of variations of trace and rare earth elements concentration in lakes bottom sediments in the Bory Tucholskie National Park, Poland. Scientific Reports, 11(244), 1–18. https://doi.org/10.1038/s41598-020
Talukder, R., Rabbi, H., Bakhiah, N. B., & Carnicelli, S. (2021). Source identification and ecological risk assessment of heavy metal pollution in sediments of Setiu wetland, Malaysia. Environmental Forensics. https://doi.org/10.1080/15275922.2021.1892871
Varol, M., Ustaoglu, F., & Tokatlı, C. (2022). Ecological risks and controlling factors of trace elements in sediments of dam lakes in the Black Sea Region (Turkey). Environmental Research, 205, 112478. https://doi.org/10.1016/j.envres.2021.112478
Wang, S., Wang, W., Chen, J., Zhaoa, L., Zhanga, B., & Jiang, X. (2019). Geochemical baseline establishment and pollution source determination of heavy metals in lake sediments: A case study in Lihu Lake, China. Science of the Total Environment, 657, 978–986.
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This data was collected within the framework of the state assignment of the IO RAS (theme no. 0128-2021-0005).
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Koukina, S., Lobus, N., Bolotov, S. (2024). Spatial Variations of Trace and Rare Earth Elements in Tropical Lake Sediments. In: Çiner, A., et al. Recent Research on Environmental Earth Sciences, Geomorphology, Soil Science and Paleoenvironments. MedGU 2022. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-031-48754-5_30
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DOI: https://doi.org/10.1007/978-3-031-48754-5_30
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