Tanneries Wastewater Treatment by Coagulation and Reverse Osmosis

  • Conference paper
  • First Online:
Engineering Solutions Toward Sustainable Development (IWBBIO 2023)

Part of the book series: Earth and Environmental Sciences Library ((EESL))

  • 270 Accesses

Abstract

Leather production in tanning industries is mainly done by the addition of chromium sulfate [Cr2(SO4)3]. Effective hazards occur through the disposal of chromium sulfate solutions from tanning industries directly with their wastewater in the form of Cr+3. This research aims to find a sustainable process to conserve agriculture, human health, and aquatic environment from the interaction with water containing chromium by treating this wastewater. This research was done by the pH adjustment process, coagulation–flocculation process, filtration process, and reverse osmosis (RO) membranes for the production of purified water. The neutralization process was done using alkaline solution. The coagulation–flocculation process was applied by using FeSO4 and CaO. In the filtration and purification processes, the polypropylene filter, carbon block (CB) filter, the granular activated carbon (GAC) filter were gathered in the form of a pretreatment process. Reverse osmosis (RO) membrane gave impressive results in the removal of organic matters, dissolved solids and Cr+3. Heavy metals were measured using ICP-MS spectrophotometer. Surface morphology and elemental analysis of PP filter, CB filter, GAC filter, and RO membrane were monitored by using SEM and EDX microscope respectively. Zeta potential was measured in order to identify and determine the best pH situations to remove chromium from tanneries wastewater. By applying this treatment procedure on several tanneries wastewater samples. The effectiveness of removal of COD and BOD achieved 100%. Total dissolved solids were significantly decreased up to 99.93%. Cr+3 ions were remarkably captured up to 88.57%. Suggested tanneries wastewater treatment process revealed great treatment results in comparison with commercial processes.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
EUR 29.95
Price includes VAT (Germany)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
EUR 181.89
Price includes VAT (Germany)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
EUR 235.39
Price includes VAT (Germany)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Bassyouni M, Zoromba MS, Abdel-Aziz MH, Mosly I (2022) Extraction of nanocellulose for eco-friendly biocomposite adsorbent for wastewater treatment. Polymers 14(9):1852

    Article  CAS  Google Scholar 

  2. Zoromba MS, Ismail MI, Bassyouni M, Abdel-Aziz MH, Salah N, Alshahrie A, Memic A (2017) Fabrication and characterization of poly (aniline-co-o-anthranilic acid)/magnetite nanocomposites and their application in wastewater treatment. Colloids Surf A 520:121–130

    Article  CAS  Google Scholar 

  3. Abdel-Aziz MH, Bassyouni M, Soliman MF, Gutub SA, Magram SF (2017) Removal of heavy metals from wastewater using thermally treated sewage sludge adsorbent without chemical activation. J Mater Environ Sci 8(5):1737–1747

    CAS  Google Scholar 

  4. Mansi AE, El-Marsafy SM, Elhenawy Y, Bassyouni M (2022) Assessing the potential and limitations of membrane-based technologies for the treatment of oilfield produced water. Alex Eng J 68:787–815

    Article  Google Scholar 

  5. Eteba A, Bassyouni M, Saleh M (2023) Utilization of chemically modified coal fly ash as cost-effective adsorbent for removal of hazardous organic wastes. Int J Environ Sci Technol 20(7):7589–7602

    Article  CAS  Google Scholar 

  6. Abdel-Aziz MH, El-Ashtoukhy EZ, Bassyouni M, Al-Hossainy AF, Fawzy EM, Abdel-Hamid SM, Zoromba MS (2021) DFT and experimental study on adsorption of dyes on activated carbon prepared from apple leaves. Carbon Lett 31:863–878

    Article  Google Scholar 

  7. Elminshawy NA, El-Ghandour M, Elhenawy Y, Bassyouni M, El-Damhogi DG, Addas MF (2019) Experimental investigation of a V-trough PV concentrator integrated with a buried water heat exchanger cooling system. Sol Energy 193:706–714

    Article  Google Scholar 

  8. Sandid AM, Bassyouni M, Nehari D, Elhenawy Y (2021) Experimental and simulation study of multichannel air gap membrane distillation process with two types of solar collectors. Energy Convers Manage 243:114431

    Article  Google Scholar 

  9. Fouad K, Alalm MG, Bassyouni M, Saleh MY (2020) A novel photocatalytic reactor for the extended reuse of W-TiO2 in the degradation of sulfamethazine. Chemosphere 257:127270

    Article  CAS  Google Scholar 

  10. Elhady S, Bassyouni M, Mansour RA, Elzahar MH, Abdel-Hamid S, Elhenawy Y, Saleh MY (2020) Oily wastewater treatment using polyamide thin film composite membrane technology. Membranes 10(5):84

    Article  CAS  Google Scholar 

  11. Abdel-Aziz MH, Bassyouni M, Zoromba MS, Alshehri AA (2018) Removal of dyes from waste solutions by anodic oxidation on an array of horizontal graphite rods anodes. Ind Eng Chem Res 58(2):1004–1018

    Article  Google Scholar 

  12. Maddah HA, Alzhrani AS, Bassyouni M, Abdel-Aziz MH, Zoromba M, Almalki AM (2018) Evaluation of various membrane filtration modules for the treatment of seawater. Appl Water Sci 8:1–13

    Article  CAS  Google Scholar 

  13. Rodríguez MC, Barsanti L, Passarelli V, Evangelista V, Conforti V, Gualtieri P (2007) Effects of chromium on photosynthetic and photoreceptive apparatus of the alga Chlamydomonas reinhardtii. Environ Res 105(2):234–239. https://doi.org/10.1016/j.envres.2007.01.011

    Article  CAS  Google Scholar 

  14. Wang Y (2019) Release of chrome in chrome tanning and post tanning processes (July 2012)

    Google Scholar 

  15. Oliveira H (2012) Chromium as an environmental pollutant: insights on induced plant toxicity. J Bot 2012:1–8. https://doi.org/10.1155/2012/375843

    Article  CAS  Google Scholar 

  16. Stearns DM, Belbruno JJ, Wetterhahn KE (2018) A prediction of chromium(III) accumulation in humans from chromium dietary supplements. FASEB J 9(15):1650–1657. https://doi.org/10.1096/fasebj.9.15.8529846

    Article  Google Scholar 

  17. Kolomaznik K, Adamek M, Andel I, Uhlirova M (2008) Leather waste-Potential threat to human health, and a new technology of its treatment. J Hazard Mater 160(2–3):514–520. https://doi.org/10.1016/j.jhazmat.2008.03.070

    Article  CAS  Google Scholar 

  18. Khan SA, Ibrahim M, Jamil Y, Islam MS, Abbas F (2013) Spectrochemical analysis of soil around leather tanning industry using laser induced breakdown spectroscopy. J Chem. https://doi.org/10.1155/2013/894020

    Article  Google Scholar 

  19. Cheng S, Grosse W, Karrenbrock F, Thoennessen M (2002) Efficiency of constructed wetlands in decontamination of water polluted by heavy metals. Ecol Eng 18(3):317–325

    Article  Google Scholar 

  20. Eastlick BK (1995) Wetlands wastewater treatment for the Canadian prairies. Master, Environmental Design, University of Calgary

    Google Scholar 

  21. El-Hadek MA (2018) Dynamic equivalence of ultrasonic stress wave propagation in solids. Ultrasonics 83:214–221

    Article  Google Scholar 

  22. El-Shamy AM, El-Hadek MA, Nassef AE, El-Bindary RA (2020) Box-Behnken design to enhance the corrosion resistance of high strength steel alloy in 3.5 wt% NaCl solution. Moroccan J Chem 8(4):4–8

    Google Scholar 

  23. Bassyouni M, Mansi AE, Elgabry A, Ibrahim BA, Kassem OA, Alhebeshy RJAPA (2020) Utilization of carbon nanotubes in removal of heavy metals from wastewater: a review of the CNTs’ potential and current challenges. Appl Phys A 126:1–33

    Article  Google Scholar 

  24. Nassef A, El-Hadek M (2016) Microstructure and mechanical behavior of hot pressed Cu-Sn powder alloys. Adv Mater Sci Eng 2016:1–10

    Google Scholar 

  25. Sobolewski A (1996) Metal species indicate the potential of constructed wetlands for long-term treatment of metal mine drainage. Ecol Eng 6(4):259–271

    Article  Google Scholar 

  26. Wang L, Hung Y-T, Shammas N (2005) Physiochemical treatment processes. Human Press, New Jersey

    Book  Google Scholar 

  27. Almuktar SAAAN, Abed SN, Scholz M (2017) Recycling of domestic wastewater treated by vertical-flow wetlands for irrigation of two consecutive Capsicum annuum generations. Ecol Eng 107:82–98

    Article  Google Scholar 

Download references

Acknowledgements

The researchers would like to acknowledge the assistance provided by the Science and Technology Development Fund (STDF) for funding the project, No. 41902 (Center of Excellence in Membrane-based Water Desalination Technology for Testing and Characterization.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Bassyouni .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Essam, A., Bassyouni, M., Gadalla, M.A., Ashour, F.H. (2024). Tanneries Wastewater Treatment by Coagulation and Reverse Osmosis. In: Negm, A.M., Rizk, R.Y., Abdel-Kader, R.F., Ahmed, A. (eds) Engineering Solutions Toward Sustainable Development. IWBBIO 2023. Earth and Environmental Sciences Library. Springer, Cham. https://doi.org/10.1007/978-3-031-46491-1_17

Download citation

Publish with us

Policies and ethics

Navigation