Abstract
In addition to measuring the crystallization temperatures of supercooled melts, supercooling studies suppose obtaining information on the kinetics of phase transitions and the effect of successive heating and cooling series on the behavior of melts. Nanocomposite systems, in particular, structures of the “small particles in a more refractory matrix” type, are currently attracting special interest. The study of such objects requires the development of special methods that provide data on the kinetics of phase transitions and allow the carrying out of multiple thermal cycling of nanocomposite samples. Effective techniques to investigate these aspects and systems are based on observing the resistance of the films or the resonant frequency of the piezoelectric crystal on which the films are deposited. In the first case, the criterion for melting and crystallization of the layer is a jump in the electrical resistance of the film. In the second case, it is a jump in the quartz resonator’s quality factor. Using these techniques, studies of supercooling during crystallization of the fusible component in multilayer films have been carried out. It is shown that for contact pairs containing bismuth, the temperature and kinetics of crystallization depend on the condensation mechanism of the fusible metal. The observed differences are explained by the different morphology of samples obtained by condensation of bismuth into liquid and solid phases. Bismuth layers deposited into the solid phase form a connected system of inclusions, which is preserved even during thermal cycling. Such a system crystallizes as a single unit, and its formation is provided by grain boundaries of the more refractory layer.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
S. Bhatt, M. Kumar, J. Phys. Chem. Solids 106, 112 (2017)
W. Kauzmann, Chem. Rev. 43(2), 219 (1948)
H.J. Fetch, W.L. Johnson, Nature 334(6177), 50 (1988)
J.L. Tallon, Nature 342(6250), 658 (1989)
D. Ma, Y. Li, D. Ma, J. Phys. Condens. Matter 12(43), 9123 (2000)
B. Rethfeld, K. Sokolowski-Tinten, D. Von der Linde, S.I. Anisimov, Phys. Rev. B 65(9), 092103 (2002)
J. Daeges, H. Gleiter, J.H. Perepezko, Phys. Lett. A 119(2), 79 (1986)
J. Zhong, L.H. Zhang, Z.H. **, M.L. Sui, K. Lu, Acta mater. 49(15), 2897 (2001)
H. Wang, H. Zhu, Nanoscale Res. Lett. 10(1), 487 (2015)
E. Johnson, C.R.H. Bahl, V.S. Touboltsev, A. Johansen, MRS Online Proc. Libr. 580, 177 (1999)
S. Chaubey, Indian J. Eng. Mater. Sci. 15(3), 241 (2008)
G. Dybkj, N. Kruse, A. Johansen, E. Johnson, L. Sarholt-Kristensen, K.K. Bourdelle, Surf. Coat. Technol. 83(1–3), 82 (1996)
H.W. Sheng, K. Lu, E. Ma, Acta mater. 46(14), 5195 (1998)
H.F. Degenhardt, G. Kellermann, A.F. Craievich, J. Appl. Crystallogr. 50(9), 1590 (2017)
J.M. Dereppe, B.F. Borisov, E.V. Charnaya, A.V. Shelyapin, M.M. Nassar, Y.A. Kumzerov, Phys. Solid State 42, 193 (2000)
I.G. Sorina, E.V. Charnaya, L.A. Smirnov, Y.A. Kumzerov, C. Tien, Phys. Solid State 40, 1407 (1998)
A. VanHook, F. Frulla, Ind. Eng. Chem. 44(6), 1305 (1952)
S.I. Bogatyrenko, A.V. Voznyi, N.T. Gladkikh, A.P. Kryshtal, Phys. Met. Metallogr. 97(3), 273 (2004)
N.T. Gladkikh, S.V. Dukarov, A.P. Kryshtal, V.I. Larin, V.N. Sukhov, S.I. Bogatyrenko, Poverkhnostnye yavleniya i fazovye prevrashcheniya v tonkikh plenkakh (Surface Phenomena and Phase Transformations in Thin Films) (Kharkiv University Press, Kharkiv, 2004)
N.T. Gladkikh, S.V. Dukarov, V.N. Sukhov, Z. Metallkd. 87(3), 233 (1996)
N.T. Gladkikh, S.V. Dukarov, V.N. Sukhov, Fiz. Met. Metalloved. 78(3), 87 (1994)
S.I. Petrushenko, S.V. Dukarov, V.N. Sukhov, Probl. At. Sci. Technol. 104(4), 118 (2016)
M.M. Kolendovskii, S.I. Bogatyrenko, A.P. Kryshtal, N.T. Gladkikh, Tech. Phys. 57(6), 849 (2012)
S.I. Petrushenko, S.V. Dukarov, V.N. Sukhov, Vacuum 122, 208 (2015)
S.V. Dukarov, S.I. Petrushenko, V.N. Sukhov, R.V. Sukhov, Funct. Mater. 25(3), 601 (2018)
S.I. Petrushenko, S.V. Dukarov, V.N. Sukhov, J. Nano- Electron. Phys. 8(4), 04073 (2016)
J.P. Mastandrea, J.W. Ager III., D.C. Chrzan, J. Appl. Phys. 122(10), 105304 (2017)
S. Petrushenko, S. Dukarov, V. Sukhov, in 2022 IEEE 12th International Conference Nanomaterials: Applications & Properties (NAP) (Krakow, Poland, 2022), p. 1. https://doi.org/10.1109/NAP55339.2022.9934108
N.T. Gladkikh, S.V. Dukarov, A.P. Kryshtal, V.I. Larin, V.N. Sukhov, Kapillyarnye svojstva ostrovkovykh plenok i malykh chastits (Capillary Properties of Island Films and Small Particles) (Kharkiv University Press, Kharkiv, 2015)
N.T. Gladkikh, S.V. Dukarov, V.I. Farenik, Smachivanie v ostrovkovykh plenkakh (Wetting in Island Films) (Kharkiv University Press, Kharkiv, 2003)
R.I. Bigun, M.D. Buchkovska, V.M. Gavrylyukh, Z.V. Stasyuk, D.S. Leonov, Nanosistemi. Nanomateriali, Nanotehnologii 14(2), 285 (2016)
R.I. Bihun, Z.V. Stasyuk, O.A. Balitskii, Physica B 487, 73 (2016)
R.I. Bihun, Z.V. Stasiuk, O.V. Strohanov, M.D. Buchkovska, V.M. Havryliukh, I.A. Pastyrskyi, D.S. Leonov, Nanosistemi. Nanomateriali, Nanotehnologii 15(1), 15 (2017)
R. Sinclair, T.J. Konno, Ultramicroscopy 56(1–3), 225 (1994)
T.J. Konno, R. Sinclair, Phil. Mag. B 71(2), 163 (1995)
T.J. Konno, R. Sinclair, Phil. Mag. B 71(2), 179 (1995)
Z. Tan, S.M. Heald, M. Rapposch, C.E. Bouldin, J.C. Woicik, Phys. Rev. B Condens. Matter 46(15), 9505 (1992)
N.T. Gladkikh, S.P. Chizhik, V.I. Larin, L.K. Grigoryeva, S.V. Dukarov, Phys. Chem. Mech. Surf. 4(11), 3465 (1987)
P. Villars, L.D. Calvert, in Pearson’s Handbook of Crystallographic Data (ASM International, Materials Park, Ohio, 1991), p. 2873
H. Okamoto (ed.), Desk Handbook: Phase Diagrams for Binary Alloys (ASM International, USA, 2000)
S.I. Petrushenko, Z.V. Bloshenko, O.I. Skryl, in Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications & Properties (NAP-2017) Part 1 (Zatoka, Ukraine, 2017), p. 01PCSI13
S. Fürtauer, D. Li, D. Cupid, H. Flandorfer, Intermetallics 34, 142 (2013)
K.N. Tu, R.D. Thompson, Acta Metall. 30(5), 947 (1982)
D. Mu, J. Read, Y. Yang, K. Nogita, J. Mater. Res. 26(20), 2660 (2011)
R.A. Gagliano, G. Ghosh, M.E. Fine, J. Electron. Mater. 31(11), 1195 (2002)
D.K. Mu, S.D. McDonald, J. Read, H. Huang, K. Nogita, Curr. Opin. Solid State Mater. Sci. 20(2), 55 (2016)
R.A. Lord, A. Umantsev, J. Appl. Phys. 98(6), 063525 (2005)
T. Studnitzky, R. Schmid-Fetzer, Z. Metallkd. 93(9), 894 (2002)
L. Brewer, R.H. Lamoreaux, Bulletin of Alloy Phase Diagrams 1(2), 96 (1980)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Dukarov, S., Petrushenko, S., Bogatyrenko, S., Sukhov, V. (2024). Phase Transitions in Layered Film Systems. In: Formation and Temperature Stability of the Liquid Phase in Thin-Film Systems. Springer, Cham. https://doi.org/10.1007/978-3-031-46061-6_3
Download citation
DOI: https://doi.org/10.1007/978-3-031-46061-6_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-46060-9
Online ISBN: 978-3-031-46061-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)