Abstract
The influence of the measurement atmosphere, heating and cooling rate on the Curie temperature of Co0.5Zn0.5Fe2O4 cobalt-zinc ferrite was studied by thermogravimetric analysis in a magnetic field. This technique allowed determining the temperature of ferrimagnet-paramagnet transition at Curie point of magnetic materials. The method of solid-phase synthesis was used to produce the Co–Zn ferrite. Curie temperature control of the ferrite was carried out by using a Netzsch STA 449C Jupiter thermal analyzer. Measurements were performed in the temperature range of 45–400 °C with heating (cooling) rates of 10, 20, and 50 K/min. The cell of analyzer was purged with air or nitrogen. According to thermomagnetometric analysis, the Curie temperature of Co–Zn ferrite are in the range of 171–188 °C, depending on the experimental conditions. It was shown, that the Curie temperature weakly depends on both the heating and cooling rate during thermogravimetric analysis in a magnetic field. However, this parameter depends on the measurement mode.
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References
Liu, H., Ji, P., Han, X.: Rheological phase synthesis of nanosized α-LiFeO2 with higher crystallinity degree for cathode material of lithium-ion batteries. Mater. Chem. Phys. 183, 152–157 (2016)
Kurian, M., Thankachan, S.: Structural diversity and applications of spinel ferrites core–Shell nanostructures. A review, Open. Ceram. 8, 100179 (2021)
Rani, R., Mujasam Batoo, K., Sharma, P., Anand, G., Kumar, G., Bhardwaj, S., Singh, M.: Structural, morphological and temperature dependent electrical traits of Co0.9Zn0.1InxFe2−xOa spinel nano-ferrites. Ceram. Int. 47, 30902–30910 (2021)
Gauns Dessai, P.P., Verenkar, V.M.S.: Synthesis and characterization of Ni0.7−xMnxZn0.3Fe2(C4H2O4)3·6N2H4 (x = 0.1 – 0.6): a precursor for the synthesis of nickel-manganese-zinc ferrites. J. Therm. Anal. Calorim. 142, 1399–1411 (2020)
Guo, J., Zhang, H., He, Z., Li, S., Li, Z.: Electrical properties and temperature sensitivity of Mo-modified MnFe2O4 ceramics for application of NTC thermistors. J. Mater. Sci: Mater. Electron. 29, 2491–2499 (2018)
Inoue, A., Kong, F.: Soft magnetic materials, reference module in materials science and materials engineering (Elsevier) (2020). https://doi.org/10.1016/B978-0-12-803581-8.11725-4
Gao, Y., Wang, Z.: Microwave absorption and electromagnetic interference shielding properties of Li-Zn ferrite-carbon nanotubes composite. J. Magn. Magn. Mater. 528, 167808 (2021). https://doi.org/10.1016/j.jmmm.2021.167808
Hajalilou, A., Kianvash, A., Lavvafi, H., Shameli, K.: Nanostructured soft magnetic materials synthesized via mechanical alloying: a review. J. Mater. Sci.: Mater. Electron. 29, 1690–1717 (2018). https://doi.org/10.1007/s10854-017-8082-0
Sutradhar, S., Bandyopadhyay, A.: Modulation of magnetic and dielectric response of mullite coated Cu—substituted Co–Zn-ferrite multiphase nanocomposites. Mater. Sci. Eng: B 266, 115079 (2021)
Gómez-Polo, C., Recarte, V., Cervera, L., Beato-López, J.J., López-García, J., Rodríguez-Velamazán, J.A., Ugarte, M.D., Mendonça, E.C., Duque, J.G.S.: Tailoring the structural and magnetic properties of Co-Zn nanosized ferrites for hyperthermia applications. J Magn. Magn. Mater. 465, 211–219 (2018)
Andhare, D.D., Patade, S.R., Kounsalye, J.S., Jadhav, K.M.: Effect of Zn do** on structural, magnetic and optical properties of cobalt nanoparticles synthesized via. Co-precipitation method. Phys. B: Condens. Matter. 583, 412051 (2020)
Muntean, C., Bozdog, M., Duma, S., Stefanescu, M.: Study on the formation of Co1−xZnxFe2O4 system using two low-temperature synthesis methods. J. Therm. Anal. Calorim. 123, 117–126 (2016)
Mondal, R., Dey, S., Majumder, S., Poddar, A., Dasgupta, P., Kumar, S.: Study on magnetic and hyperfine properties of mechanically milled Ni0.4Zn0.6Fe2O4 nanoparticles. J. Magn. Magn. Mater. 448, 135–145 (2018)
Azouaoui, A., El haoua, M., Salmi, S., Benzakour, N., Hourmatallah, A., Bouslykhane, K.: Structural and magnetic properties of Co–Zn ferrites: density functional theory calculations and high-temperature series expansions. Comput. Condens. Matter. 23, e00454 (2020)
Lanfredi, S., Genova, D.H.M., Brito, I., Lima, A., Nobre, M.: Structural characterization and Curie temperature determination of a sodium strontium niobate ferroelectric nanostructured powder. J. Solid State Chem. 184, 990–1000 (2011). https://doi.org/10.1016/j.jssc.2011.03.001
**e, Y., Fan, J., Xu, L., Zhang, X., Xu, R., Zhu, Y., Tang, R., Wang, C., Ma, C., Pi, L., Zhang, Y., Yang, H.: Unambiguous determining the Curie point in perovskite manganite with second-order phase transition by scaling method. Phys. Lett. A. 383, 125843 (2019). https://doi.org/10.1016/j.physleta.2019.125843
Chen, D., Harward, I., Baptist, J., Goldman, S., Celinski, Z.: Curie temperature and magnetic properties of aluminum doped barium ferrite particles prepared by ball mill method. J. Magn. Magn. Mater. 395, 350–353 (2015). https://doi.org/10.1016/j.jmmm.2015.07.076
Lysenko, E.N., Nikolaev, E.V., Surzhikov, A.P., Nikolaeva, S.A.: Kinetic analysis of lithium-titanium ferrite formation from mechanically milled reagents. J. Therm. Anal. Calorim. 239, 122055 (2020). https://doi.org/10.1016/j.matchemphys.2019.122055
Lysenko, E.N., Nikolaev, E.V., Vlasov, V.A., Surzhikov, A.P.: Microstructure and reactivity of Fe2O3–Li2CO3–ZnO ferrite system ball-milled in a planetary mill. Thermochim. Acta 664, 100–107 (2018). https://doi.org/10.1016/j.tca.2018.04.015
Lysenko, E.N., Surzhikov, A.P., Vlasov, V.A., Malyshev, A.V., Nikolaev, E.V.: Thermal analysis study of solid-phase synthesis of zinc- and titanium-substituted lithium ferrites from mechanically activated reagents. J. Therm. Anal. Calorim. 122, 1347–1353 (2015). https://doi.org/10.1007/s10973-015-4849-9
Fischer, H.: Calibration of micro-thermal analysis for the detection of glass transition temperatures and melting points. J. Therm. Anal. Calorim. 92, 625–630 (2008)
Weddle, B.J., Robbins, S.A., Gallagher, P.K.: Further studies on the use of simultaneous TM/DTA to establish magnetic transition temperatures. Pure Appl. Chem. 67, 1843–1847 (1995)
Luciani, G., Costantini, A., Branda, F., Scardi, P., Lanotte, L.: Thermal evolution of ferromagnetic metallic glasses. A study using TG(M) technique. J. Therm. Anal. Calorim. 72, 105–111 (2003)
Astafyev, A.L., Lysenko, E.N., Surzhikov, A.P., Nikolaev, E.V., Vlasov, V.A.: Thermomagnetometric analysis of nickel-zinc ferrites. J. Therm. Anal. Calorim. 142, 1775–1781 (2020)
Gallagher, P.K.: Thermomagnetometry. J. Therm. Anal. Calorim. 49, 33–44 (1997)
Lin, D.M., Wang, H.S., Lin, M.L., Lin, M.H., Wu, Y.C.: TG(M) and DTG(M) techniques and some of their applications on material study. J. Therm. Anal. Calorim. 58, 347–353 (1999)
Arulmurugan, R., Vaidyanathan G., Sendhilnathan S., Jeyadevan, B.: Preparation and properties of temperature-sensitive magnetic fluid having Co0.5Zn0.5Fe2O4 and Mn0.5Zn0.5Fe2O4 nanoparticles. Phys. B: Condens. Mater. 368, 223–230 (2005)
Arulmurugan, R., Vaidyanathan G., Sendhilnathan S., Jeyadevan, B.: Thermomagnetic properties of Co1−xZnxFe2O4 (x = 0.1–0.5) nanoparticles. J. Magn. Magn. Mater. 303, 131–137 (2006)
Veverka, M., Jirák, Z., Kaman, K., Maryško, M., Pollert, E., Lančok, A., Dlouhá, M., Vrastislav, S.: Distribution of cations in nanosize and bulk Co–Zn ferrites. Nanotechnology 22, 345701 (2011). https://doi.org/10.1088/0957-4484/22/34/345701
Ramana Reddy, A.V., Ranga Mohan, G., Ravinder, D., Boyanov, B.S.: High-frequency dielectric behaviour of polycrystalline zinc substituted cobalt ferrites. J. Mater. Sci. 34, 3169–3176 (1999)
Lee, S.W., Ryu, Y.G., Yang, K.J.: Magnetic properties of Zn2+ substituted ultrafine Co-ferrite grown by a sol-gel method. J. Appl. Phy. 91, 7610 (2002). https://doi.org/10.1063/1.1452215
Lysenko, E.N., Astafyev, A.L., Vlasov, V.A., Surzhikov, A.P.: Analysis of phase composition of LiZn and LiTi ferrites by XRD and thermomagnetometric analysis. J. of Magn. Magn. Mater. 465, 457–461 (2018)
Teo, M.L.S., Kong, L.B., Li, Z.W., Lin, G.Q., Gan, Y.B.: Development of magneto-dielectric materials based on Li-ferrite ceramics I. Densification behavior and microstructure development. Alloys Compd 459, 557–566 (2008)
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This research was supported by the Russian Science Foundation (Grant no. 19-72-10078-P).
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Nikolaev, E., Lysenko, E., Surzhikov, A., Bobuyok, S. (2023). The Influence of Thermomagnetometric Measurement Conditions on the Recorded Curie Temperature of Cobalt-Zinc Ferrite. In: Lysenko, E., Rogachev, A., Galtseva, O. (eds) Emerging Trends in Materials Research and Manufacturing Processes. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-38964-1_1
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