Abstract
In situ remedies refer to processes that treat mine drainage at the source, whether directly adding amendments as in-pit treatments or backfilling old mining pits to create in situ bioreactors (e.g., saturated rock fills). In-pit treatments can be further subdivided by the following amendment types and removal mechanisms: alkaline; adsorptive; biological, or mixed treatments. This section will outline the mechanisms of each technique, current research in their subfield, literature gaps and potential methods to advance each field, with a focus on waste by-products.
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References
G.M.C.M. Janssen, E.J.M. Temminghoff, In situ metal precipitation in a zinc-contaminated, aerobic sandy aquifer by means of biological sulfate reduction. Environ. Sci. Technol. 38, 4002–4011 (2004). https://doi.org/10.1021/es030131a
J. Dong, B. Li, Q. Bao, In situ reactive zone with modified Mg(OH)2 for remediation of heavy metal polluted groundwater: immobilization and interaction of Cr(III), Pb(II) and Cd(II). J. Contam. Hydrol. 199, 50–57 (2017). https://doi.org/10.1016/j.jconhyd.2017.02.005
L.J.J. Catalan, G. Yin, Comparison of calcite to quicklime for amending partially oxidized sulfidic mine tailings before flooding, 6
G. Kaur, S.J. Couperthwaite, B.W. Hatton-Jones, G.J. Millar, Alternative neutralisation materials for acid mine drainage treatment. J. Water Process Eng. 22, 46–58 (2018). https://doi.org/10.1016/j.jwpe.2018.01.004
Z. Diao, T. Shi, S. Wang et al., Silane-based coatings on the pyrite for remediation of acid mine drainage. Water Res. 47, 4391–4402 (2013). https://doi.org/10.1016/j.watres.2013.05.006
J.L. Huisman, G. Schouten, C. Schultz, Biologically produced sulphide for purification of process streams, effluent treatment and recovery of metals in the metal and mining industry. Hydrometallurgy 83, 106–113 (2006). https://doi.org/10.1016/j.hydromet.2006.03.017
D.B. Johnson, K.B. Hallberg, Acid mine drainage remediation options: a review. Sci. Total Environ. 338, 3–14 (2005). https://doi.org/10.1016/j.scitotenv.2004.09.002
G.B. Douglas, Contaminant removal from acidic mine pit water via in situ hydrotalcite formation. Appl. Geochem. 51, 15–22 (2014). https://doi.org/10.1016/j.apgeochem.2014.09.005
A. Othman, A. Sulaiman, S.K. Sulaiman, Carbide lime in acid mine drainage treatment. J. Water Process Eng. 15, 31–36 (2017). https://doi.org/10.1016/j.jwpe.2016.06.006
M. Mahedi, A.Y. Dayioglu, B. Cetin, S. Jones, Remediation of acid mine drainage with recycled concrete aggregates and fly ash. Environ. Geotech. 1–14 (2020). https://doi.org/10.1680/jenge.19.00150
Z.T. Abd Ali, L.A. Naji, S.A.A.A.N. Almuktar et al., Predominant mechanisms for the removal of nickel metal ion from aqueous solution using cement kiln dust. J. Water Process Eng. 33, 101033 (2020). https://doi.org/10.1016/j.jwpe.2019.101033
B.J. Priatmadi, M. Septiana, R. Mulyawan, A.R. Saidy, Increases in pH of acid mine drainage with coal fly-ash application. IOP Conf. Ser. Earth Environ. Sci. 976 (2022). https://doi.org/10.1088/1755-1315/976/1/012020
M. Roulia, D. Alexopoulos, G. Itskos, C. Vasilatos, Lignite fly ash utilization for acid mine drainage neutralization and clean-up. Cleaner Mater. 6, 100142 (2022). https://doi.org/10.1016/J.CLEMA.2022.100142
A.A.S. Tigue, J.M.S. Catapang, C.S.N. Chang et al., Synthesis of pervious geopolymer from coal fly ash and bagasse fly ash for copper removal. Chem. Eng. Trans. 88 (2021). https://doi.org/10.3303/CET2188136
J.N. Zvimba, N. Siyakatshana, M. Mathye, Passive neutralization of acid mine drainage using basic oxygen furnace slag as neutralization material: experimental and modelling. Water Sci. Technol. 75, 1014–1024 (2017). https://doi.org/10.2166/wst.2016.579
A. Navarro, M.I. Martínez da Matta, Application of magnesium oxide for metal removal in mine water treatment. Sustainability 14, 15857 (2022). https://doi.org/10.3390/SU142315857
V. Masindi, M.M. Ramakokovhu, M.S. Osman, M. Tekere, Advanced application of BOF and SAF slags for the treatment of acid mine drainage (AMD): a comparative study. Mater. Today Proc. 38, 934–941 (2021). https://doi.org/10.1016/j.matpr.2020.05.422
N.T. Sithole, F. Ntuli, F. Okonta, Synthesis and evaluation of basic oxygen furnace slag based geopolymers for removal of metals and sulphates from acidic industrial effluent-column study. J. Water Process Eng. 37, 101518 (2020). https://doi.org/10.1016/j.jwpe.2020.101518
G. Kaur, S.J. Couperthwaite, G.J. Millar, Enhanced removal of Mn (II) from solution by thermally activated Bayer precipitates. Miner. Eng. 134, 166–175 (2019). https://doi.org/10.1016/j.mineng.2019.01.023
F. Frau, R. Atzori, C. Ardau et al., A two-step pH control method to remove divalent metals from near-neutral mining and metallurgical waste drainages by inducing the formation of layered double hydroxide. J. Environ. Manage. 271, 111043 (2020). https://doi.org/10.1016/j.jenvman.2020.111043
A. Kastyuchik, A. Karam, M. Aïder, Effectiveness of alkaline amendments in acid mine drainage remediation. Environ. Technol. Innov. 6, 49–59 (2016). https://doi.org/10.1016/j.eti.2016.06.001
I.L. Calugaru, S. Etteieb, S. Magdouli, K. Kaur Brar, Efficiency of thermally activated eggshells for acid mine drainage treatment in cold climate. J. Environ. Sci. Health A Tox. Hazard. Subst. Environ. Eng. (2022). https://doi.org/10.1080/10934529.2022.2027699
A.A. Bogush, C. Dabu, V.D. Tikhova et al., Biomass ashes for acid mine drainage remediation. Waste Biomass Valorization 11, 4977–4989 (2020). https://doi.org/10.1007/s12649-019-00804-9
P.T. Abongwa, E.A. Atekwana, J.O. Puckette, Hydrogeochemical investigation of metal evolution in circum-neutral mine discharge. Water Air Soil Pollut. 231 (2020). https://doi.org/10.1007/s11270-020-04542-w
V. Masindi, M.W. Gitari, H. Tutu, M. de Beer, Fate of inorganic contaminants post treatment of acid mine drainage by cryptocrystalline magnesite: complimenting experimental results with a geochemical model. J. Environ. Chem. Eng. 4, 4846–4856 (2016). https://doi.org/10.1016/j.jece.2016.03.020
A. García-Valero, S. Martínez-Martínez, A. Faz et al., Environmentally sustainable acid mine drainage remediation: use of natural alkaline material. J. Water Process Eng. 33, 101064 (2020). https://doi.org/10.1016/j.jwpe.2019.101064
F. Plaza, Y. Wen, H. Perone et al., Acid rock drainage passive remediation: potential use of alkaline clay, optimal mixing ratio and long-term impacts. Sci. Total Environ. 576, 572–585 (2017). https://doi.org/10.1016/j.scitotenv.2016.10.076
F. Plaza, Y. Wen, X. Liang, Acid rock drainage passive remediation using alkaline clay: hydro-geochemical study and impacts of vegetation and sand on remediation. Sci. Total Environ. 637–638, 1262–1278 (2018). https://doi.org/10.1016/j.scitotenv.2018.05.014
C.O.A. Turingan, D.J.A. Fabella, K.A.N. Sadol et al., Comparing the performance of low-grade nickel ore and limestone for treatment of synthetic acid mine drainage. Asia-Pac. J. Chem. Eng. 15, e2457 (2020). https://doi.org/10.1002/apj.2457
A. Merchichi, M.O. Hamou, M. Edahbi et al., Passive treatment of acid mine drainage from the Sidi-Kamber mine wastes (Mediterranean coastline, Algeria) using neighbouring phosphate material from the Djebel Onk mine. Sci. Total Environ. 807, 151002 (2022). https://doi.org/10.1016/J.SCITOTENV.2021.151002
K.K. Kefeni, B.B. Mamba, Charcoal ash leachate and its sparingly soluble residue for acid mine drainage treatment: waste for pollution remediation and dual resource recovery. J. Clean. Prod. 320, 128717 (2021). https://doi.org/10.1016/J.JCLEPRO.2021.128717
S.F. Araujo, C.L. Caldeira, V.S.T. Ciminelli et al., Basic oxygen furnace sludge to treat industrial arsenic- and sulfate-rich acid mine drainage. Environ. Sci. Pollut. Res. 1, 3 (2022). https://doi.org/10.1007/s11356-021-18120-y
B. Prasad, H. Kumar, Treatment of lignite mine water with lignite fly ash and its zeolite. Mine Water Environ. 38, 24–29 (2019). https://doi.org/10.1007/s10230-018-00570-5
V. Rey, C.A. Ríos, L.Y. Vargas, T.M. Valente, Use of natural zeolite-rich tuff and siliceous sand for mine water treatment from abandoned gold mine tailings. J. Geochem. Explor. 220, 106660 (2021). https://doi.org/10.1016/j.gexplo.2020.106660
R. Carrillo-González, B.G. Gatica García, M. Del et al., Trace elements adsorption from solutions and acid mine drainage using agricultural by-products. Soil Sed. Contam. Int. J. 31, 348–366 (2021). https://doi.org/10.1080/15320383.2021.1942430
R. Barthen, M.L.K. Sulonen, S. Peräniemi et al., Removal and recovery of metal ions from acidic multi-metal mine water using waste digested activated sludge as biosorbent. Hydrometallurgy 207, 105770 (2022). https://doi.org/10.1016/J.HYDROMET.2021.105770
T.A. Hughes, N.F. Gray, O. Sánchez Guillamón, Removal of metals and acidity from acid mine drainage using liquid and dried digested sewage sludge and cattle slurry. Mine Water Environ. 32, 108–120 (2013). https://doi.org/10.1007/s10230-013-0217-9
D. Richard, A. Mucci, C.M. Neculita, G.J. Zagury, Comparison of organic materials for the passive treatment of synthetic neutral mine drainage contaminated by nickel: short- and medium-term batch experiments. Appl. Geochem. 123, 104772 (2020). https://doi.org/10.1016/j.apgeochem.2020.104772
J.S. Clemente, S. Beauchemin, Y. Thibault et al., Differentiating inorganics in biochars produced at commercial scale using principal component analysis. ACS Omega 3, 6931–6944 (2018). https://doi.org/10.1021/acsomega.8b00523
X. Tan, Y. Liu, G. Zeng et al., Application of biochar for the removal of pollutants from aqueous solutions. Chemosphere 125, 70–85 (2015)
P. He, Y. Liu, L. Shao et al., Particle size dependence of the physicochemical properties of biochar. Chemosphere 212, 385–392 (2018). https://doi.org/10.1016/j.chemosphere.2018.08.106
A.G. Alghamdi, A. Alkhasha, H.M. Ibrahim, Effect of biochar particle size on water retention and availability in a sandy loam soil. J. Saudi Chem. Soc. 24, 1042–1050 (2020). https://doi.org/10.1016/j.jscs.2020.11.003
T. Bandara, J. Xu, I.D. Potter et al., Mechanisms for the removal of Cd(II) and Cu(II) from aqueous solution and mine water by biochars derived from agricultural wastes. Chemosphere 254, 126745 (2020). https://doi.org/10.1016/j.chemosphere.2020.126745
F.L. Braghiroli, H. Bouafif, C.M. Neculita, A. Koubaa, Performance of physically and chemically activated biochars in copper removal from contaminated mine effluents. Water Air Soil. Pollut. 230, 178 (2019). https://doi.org/10.1007/s11270-019-4233-7
D.T. Hopkins, S. Macquarrie, K.A. Hawboldt, Removal of copper from sulfate solutions using biochar derived from crab processing by-product. J. Environ. Manage. 303, 114270 (2022). https://doi.org/10.1016/j.jenvman.2021.114270
T. Falayi, F. Ntuli, Removal of heavy metals and neutralisation of acid mine drainage with un-activated attapulgite. J. Ind. Eng. Chem. 20, 1285–1292 (2014). https://doi.org/10.1016/j.jiec.2013.07.007
H.R. Chen, D.R. Zhang, Q. Li et al., Release and fate of As mobilized via bio-oxidation of arsenopyrite in acid mine drainage: Importance of As/Fe/S speciation and As(III) immobilization. Water Res. 223, 118957 (2022). https://doi.org/10.1016/J.WATRES.2022.118957
W. Xu, H. Yang, Q. Mao et al., Removal of heavy metals from acid mine drainage by red mud-based geopolymer pervious concrete: batch and long-term column studies. Polymers (Basel) 14, 5355 (2022). https://doi.org/10.3390/POLYM14245355/S1
M. Levio-Raiman, G. Briceño, H. Schalchli et al., Alternative treatment for metal ions removal from acid mine drainage using an organic biomixture as a low cost adsorbent. Environ. Technol. Innov. 24, 101853 (2021). https://doi.org/10.1016/j.eti.2021.101853
S. Park, M. Lee, Removal of copper and cadmium in acid mine drainage using Ca-alginate beads as biosorbent. Geosci. J. 21, 373–383 (2017). https://doi.org/10.1007/s12303-016-0050-9
M. Li, Y. Huang, Y. Yang et al., Heavy metal ions removed from imitating acid mine drainages with a thermoacidophilic archaea: acidianus manzaensis YN25. Ecotoxicol. Environ. Saf. 190, 110084 (2020). https://doi.org/10.1016/j.ecoenv.2019.110084
S.K. Hwang, E.H. Jho, Heavy metal and sulfate removal from sulfate-rich synthetic mine drainages using sulfate reducing bacteria. Sci. Total Environ. 635, 1308–1316 (2018). https://doi.org/10.1016/j.scitotenv.2018.04.231
C.D. McCullough, M.A. Lund, Bioremediation of acidic and metalliferous drainage (AMD) through organic carbon amendment by municipal sewage and green waste. J. Environ. Manage. 92, 2419–2426 (2011). https://doi.org/10.1016/j.jenvman.2011.04.011
R.N. Kumar, C.D. McCullough, M.A. Lund, Upper and lower concentration thresholds for bulk organic substrates in bioremediation of acid mine drainage. Mine Water Environ. 32, 285–292 (2013). https://doi.org/10.1007/s10230-013-0242-8
D.G. Grubb, D.G. Landers, P.A. Guerra et al., Sugarcane bagasse as a microbial host media for the passive treatment of acid mine drainage. J. Environ. Eng. 144, 4018108 (2018). https://doi.org/10.1061/(ASCE)EE.1943-7870.0001400
G.J. Zagury, V.I. Kulnieks, C.M. Neculita, Characterization and reactivity assessment of organic substrates for sulphate-reducing bacteria in acid mine drainage treatment. Chemosphere 64, 944–954 (2006). https://doi.org/10.1016/j.chemosphere.2006.01.001
M. Syazwan, M. Halim, A.H. Ibrahim et al., Iron removal efficiency in synthetic acid mine drainage (AMD) treatment using peat soil. Lect. Notes Civil Eng. 214, 297–303 (2022). https://doi.org/10.1007/978-981-16-7920-9_35
C. Oporto, G. Baya, C. Vandecasteele, Efficiencies of available organic mixtures for the biological treatment of highly acidic-sulphate rich drainage of the San Jose mine. Bolivia 42, 1283–1291 (2019). https://doi-org.myaccess.library.utoronto.ca/101080/0959333020191665109. https://doi.org/10.1080/09593330.2019.1665109
S.N. Muhammad, F.M. Kusin, M.S. Md Zahar et al., Passive bioremediation technology incorporating lignocellulosic spent mushroom compost and limestone for metal- and sulfate-rich acid mine drainage. Environ. Technol. 38, 2003–2012 (2017). https://doi.org/10.1080/09593330.2016.1244568
R. Martínez-Macias M del, Ma.A. Correa-Murrieta, Y. Villegas-Peralta et al., Uptake of copper from acid mine drainage by the microalgae Nannochloropsis oculata. Environ. Sci. Pollut. Res. 26, 6311–6318 (2019). https://doi.org/10.1007/s11356-018-3963-1
L.L. Neil, C.D. McCullough, M.A. Lund et al., Toxicity of acid mine pit lake water remediated with limestone and phosphorus. Ecotoxicol. Environ. Saf. 72, 2046–2057 (2009). https://doi.org/10.1016/j.ecoenv.2009.08.013
T.C.E. Dessouki, J.J. Hudson, B.R. Neal, M.J. Bogard, The effects of phosphorus additions on the sedimentation of contaminants in a uranium mine pit-lake. Water Res. 39, 3055–3061 (2005). https://doi.org/10.1016/j.watres.2005.05.009
O. Paulsson, A. Widerlund, Algal nutrient limitation and metal uptake experiment in the Åkerberg pit lake, northern Sweden. Appl. Geochem. 11 (2021)
G.W. Poling, C.A. Pelletier, D. Muggli et al., Field studies of semi-passive biogeochemical treatment of acid rock drainage at the island copper mine pit lake (2003). https://doi.org/10.7939/r3-rgym-s881
A. Luek, D.J. Rowan, J.B. Rasmussen, N-P fertilization stimulates anaerobic selenium reduction in an end-pit lake. Sci. Rep. 7, 10502 (2017). https://doi.org/10.1038/s41598-017-11095-2
V. Preuss, M. Horn, M. Koschorreck et al., In-Lake bioreactors for the treatment of acid mine water in pit lakes. Adv. Mat. Res. 20–21, 271–274 (2007). https://doi.org/10.4028/www.scientific.net/amr.20-21.271
T. Hwang, C.M. Neculita, J.-I. Han, Biosulfides precipitation in weathered tailings amended with food waste-based compost and zeolite. J. Environ. Qual. 41, 1857–1864 (2012). https://doi.org/10.2134/jeq2011.0462
T. Hwang, C.M. Neculita, In situ immobilization of heavy metals in severely weathered tailings amended with food waste-based compost and zeolite. Water Air Soil. Pollut. 224, 1388 (2013). https://doi.org/10.1007/s11270-012-1388-x
X. Guo, Z. Hu, S. Fu et al., Experimental study of the remediation of acid mine drainage by Maifan stones combined with SRB. PLoS ONE 17, e0261823 (2022). https://doi.org/10.1371/JOURNAL.PONE.0261823
G. Chai, D. Wang, Y. Zhang et al., Effects of organic substrates on sulfate-reducing microcosms treating acid mine drainage: performance dynamics and microbial community comparison. J. Environ. Manage. 330, 117148 (2023). https://doi.org/10.1016/J.JENVMAN.2022.117148
S. Jensen, J. Foster, M.-C. Noel, M. Bartlett, Mine design for in-situ control of selenium and nitrate (2018)
L.B. Kirk, C. Hwang, C. Ertuna et al., Column tests of selenium biomineraliation in support of saturated rockfill design. in Mine Water and Circular Economy (vol. II) (2017), pp 1191–1195
S.G. Deen, V.F. Bondici, J. Essilfie-Dughan et al., Biotic and abiotic sequestration of selenium in anoxic coal waste rock. Mine Water. Environ. 37, 825–838 (2018). https://doi.org/10.1007/s10230-018-0546-9
M. Bianchin, A. Martin, J. Adams, In-situ immobilization of selenium within the saturated zones of backfilled pits at coal-mine operations
A. Luek, C. Brock, D.J. Rowan, J.B. Rasmussen, A simplified anaerobic bioreactor for the treatment of selenium-laden discharges from non-acidic, end-pit lakes. Mine Water Environ. 33, 295–306 (2014). https://doi.org/10.1007/s10230-014-0296-2
S. **, P.H. Fallgren, J.M. Morris, J.S. Cooper, Source treatment of acid mine drainage at a backfilled coal mine using remote sensing and biogeochemistry. Water Air Soil Pollut. 188, 205–212 (2008). https://doi.org/10.1007/s11270-007-9536-4
J.D. Jenkins, Role of flow and organic carbon on acid mine drainage remediation in waste rock (2001)
C. Hwang, L.B. Kirk, B. Peyton, Changes in microbial community structure in response to changing oxygen stress in column tests of denitrification and selenium reduction (2017)
L.B. Kirk, C. Hwang, C. Ertuna et al., Column tests of selenium biomineralization in support of saturated rockfill design (2017)
A. Martin, R. Goldblatt, J. Stockwell, In situ attenuation of selenium in coal mine flooded pits (2015)
L.M.B. Kirk, In Situ Microbial Reduction of Selenate in Backfilled Phosphate Mine Waste (Montana State University, S.E. IDAHO, 2014)
MARIAAN WEBB, Teck doubles water treatment capacity at Elkview, in Mining Weekly (2021). https://www.miningweekly.com/article/teck-doubles-water-treatment-capacity-at-elkview-2021-02-17/rep_id:3650. Accessed 29 Nov 2022
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Chidiac, C., Bleasdale-Pollowy, A., Holmes, A., Gu, F. (2024). In-Situ Remedies. In: Passive Treatments for Mine Drainage. SpringerBriefs in Applied Sciences and Technology. Springer, Cham. https://doi.org/10.1007/978-3-031-32049-1_3
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