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Experimental Determination of Liquid-Liquid Equilibrium Data on Ternary Water Systems

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Experimental Research and Numerical Simulation in Applied Sciences (CNNTech 2022)

Part of the book series: Lecture Notes in Networks and Systems ((LNNS,volume 564))

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Abstract

Due to the increase in energy consumption at the global level, it is necessary to examine new possibilities of substitution of classical energy-intensive separation processes based on evaporation of more volatile components, separation processes based on liquid-liquid equilibria (LLE), i.e. extraction of components from liquid solutions. This procedure would also include the replacement of standard industrial solvents with environmentally harmful characteristics with new, green solvents. Diethyl adipate can be used for these purposes because it is relatively non-toxic, obtained from renewable sources and is biodegradable. In order to examine the possibilities of using green solvents, the possibilities of adequate replacement and process design, it is necessary to know thermodynamic data such as liquid-liquid equilibria data, the corresponding binodal curve and equilibrium lines. The liquid-liquid equilibria data of the ternary system water + ethanol + diethyl adipate will be determined experimentally at a temperature of 298.15 K and atmospheric pressure. Binodal curves will be determined using the synthetic blur method using both the titration technique and the equilibrium lines via the refractive index. The obtained experimental data will be used in determining the complete phase diagram of the mentioned system.

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Acknowledgment

The authors gratefully acknowledge the financial support received from the Research Fund of Ministry of Education, Science and Technological of the Republic of Serbia Development (Contract No. 451–03-68/2022–14/200135)), the Faculty of Technology and Metallurgy, University of Belgrade.

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Authors and Affiliations

  1. Innovation Center of the Faculty of Technology and Metallurgy Belgrade, Karnegijeva 4, 11120, Belgrade, Republic of Serbia

    Zoran Simić

  2. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120, Belgrade, Serbia

    Ivona Radović & Mirjana Kijevčanin

Authors
  1. Zoran Simić
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  2. Ivona Radović
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  3. Mirjana Kijevčanin
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Corresponding author

Correspondence to Zoran Simić .

Editor information

Editors and Affiliations

  1. Faculty of Mechanical Engineering, Department for Process Engineering and Environmental Protection, University of Belgrade, Belgrade, Serbia

    Nenad Mitrovic

  2. Faculty of Mechanical Engineering, Department for Production Engineering, University of Belgrade, Belgrade, Serbia

    Goran Mladenovic

  3. Faculty of Information Technology and Engineering, University Union - Nikola Tesla, Belgrade, Serbia

    Aleksandra Mitrovic

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Simić, Z., Radović, I., Kijevčanin, M. (2023). Experimental Determination of Liquid-Liquid Equilibrium Data on Ternary Water Systems. In: Mitrovic, N., Mladenovic, G., Mitrovic, A. (eds) Experimental Research and Numerical Simulation in Applied Sciences. CNNTech 2022. Lecture Notes in Networks and Systems, vol 564. Springer, Cham. https://doi.org/10.1007/978-3-031-19499-3_10

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