Abstract
Historically new innovative tools always provide new opportunities to reveal new secrets of Mother Nature. An atomic force microscope (AFM) is such an innovative tool that allows one to study the local structures and properties of material at molecular levels, which may be difficult to study by classical ensemble average techniques such as optical microscopes. For this reason, since its invention, AFM has been one of the most important tools that lead current nanoscience and nanotechnology in many diverse areas including physics, chemistry, and biology. In this chapter, for the analysis of the AFM data, some basic theoretical models are discussed.
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References
J. Hu, X. D. **ao, M. Salmeron, Scanning Polarization Force Microscopy: A Technique for Imaging Liquids and Weakly adsorbed Layers, Appl. Phys. Lett. 67 (4), 476 (1995)
Xu, L.; Lio, A.; Hu, J.; Ogletree, D. F.; Salmeron, M. Wetting and capillary phenomena of water on mica, J. Phys. Chem. B 1998, 102, 540–548.
K. Chiba, R. Ohmori, H. Tanigawa, T. Yoneoka, and S. Tanaka, H2O trap** on various materials studied by AFM and XPS, Fusion Eng. Des. 49, 791–797 (2000).
Z. Liu, Z. Li, H. Zhou, G. Wei, Y. Song, L. Wang, Observation of the mica surface by atomic force microscopy, Micron 36, 525–531 (2005).
B. I. Kim, J. A. Rasmussen, and E. J. Kim, Large oscillatory forces generated by interfacial water under lateral modulation between two hydrophilic surfaces, Appl. Phys. Lett. 99, 201902 (2011).
S. Pal, N. B. Sankaran, and A. Samanta Structure of a Self-Assembled Chain of Water Molecules in a Crystal Host Angew. Chem. Int. Ed. 2003, 42, 1741–1743
Baciou, L., and H. Michel. 1995. Interruption of the water chain in the reaction center from Rb. sphaeroides reduces the rates of the proton uptake and of the second electron transfer to QB. Biochemistry. 34: 7967–7972.
Pomes R and Roux B. Molecular Mechanism of H+ Conduction in the Single-File Water Chain of the Gramicidin Channel Biophys J 2002, 82, 2304–2316.
Jones, R. A. L. Soft Condensed Matter. New York, USA: Oxford University Press, 2002.
J. N. Israelachvili, Intermolecular and Surface Forces, 2nd ed. (Academic Press, Inc., San Diego, CA, (1991).
P. Nelson, Biological Physics. W.H. Freeman & Co., New York, (2008).
S. Kwon, B. Kim, S. An, W. Lee, H. Kwak, and W. Jhe, Sci. Rep 8, 8462 (2018).
M. V. Vitorino, A. Vieira, C. A. Marques, and M. S. Rodrigues, Sci. Rep. 8, 13848 (2018).
R. C. Major, J. E. Houston, M. J. McGrath, J. I. Siepmann, and X.-Y. Zhu, Phys, Rev, Lett. 96, 177803 (2006)
J. Freund, J. Halbritter and J. K. H. Horber, Microsc. Res. Technol. 44, 327 (1999).
H. J. Butt and M. Kappl, Normal Capillary Forces, Adv. Colloid Interface Sci. 146, 48 (2009).
A. Marin, J. Warbrick, and A. Cammarata, Physical Pharmacy 3rd Ed. Lea & Febiger, Philadelphia (1983)
Kim, B. I.; Boehm, R. D.; Bonander, J. R. Direct observation of self-assembled chain-like water structures in a nanoscopic water meniscus, J. Chem. Phys. 2013, 139, 054701–7.
Phillips, R.; Kondev, J.; Theriot, J. Physical Biology of the Cell, Garland Science, New York, (2009).
B. I. Kim, R. D. Boehm, and H. Agrusa, Coil-to-Bridge Transitions of Self-Assembled Chain-like Water Observed in a Nanoscopic Meniscus, Langmuir, 38, 4538−4546 (2022).
H. J. Butt and M. Kappl, Normal Capillary Forces, Adv. Colloid Interface Sci. 146, 48 (2009).
Andrienko D., Patricio P., and Vinogradova O. I., Capillary bridging and long-range attractive forces in a mean-field approach, J. Chem. Phys. 121, 4414–4423 (2004)
E. Barthel, X. Y. Lin and J. L. Loubet, Adhesion Energy Measurements in the Presence of Adsorbed Liquid Using a Rigid Surface Force Apparatus, J. Colloid Interface Sci. 177, 401 (1996).
S. Biggs, R. G. Cain, R.R. Dagastine, N. W. Page, Direct measurements of the adhesion between a glass particle and a glass surface in a humid atmosphere, J. Adhes. Sci. Technol. 16, 869 (2002).
B. L. Weeks, M. W. Vaughn, and J. J. DeYoreo, Direct imaging of meniscus formation in atomic force microscopy using environmental scanning electron microscopy, Langmuir 21, 8096–8098 (2005).
M. Schenk, M. Futing, and R. Reichelt, Direct visualization of the dynamic behavior of a water meniscus by scanning electron microscopy J. Appl. Phys. 84, 4880–4884 (1998).
B. I. Kim, J. R. Bonander, and J. A. Rasmussen, Simultaneous measurement of normal and frictional forces using a cantilever-based optical interfacial force microscope, Rev. Sci. Instrum. 82, 053711 (2011).
Kim, S.; Kim, D.; Kim, J.; An, S.; Jhe, W. Direct Evidence for Curvature-Dependent Surface Tension in Capillary Condensation: Kelvin Equation at Molecular Scale Phys. Rev. X 2018, 8, 041046–14.
Q. Yang, P. Z. Sun, L. Fumagalli, Y. V. Stebunov, S. J. Haigh, Z. W. Zhou, I. V. Grigorieva, F. C. Wang, and A. K. Geim, Capillary condensation under atomic-scale confinement, Nature 588, 250 (2020).
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Kim, B.I. (2023). Self-Assembly, Entropy Forces, and Kelvin Equation. In: Self-Assembled Water Chains. Springer, Cham. https://doi.org/10.1007/978-3-031-19087-2_2
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DOI: https://doi.org/10.1007/978-3-031-19087-2_2
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