Abstract
Graphene oxide (GO) nanomaterial over few decades has attracted researchers due to its various surface functional groups and its superior properties over other carbon-based nanomaterials. Graphene oxide has been intensively utilized for different environmental remediation applications, out of which wastewater treatment has been one of the main focuses. This chapter deals with the preparation of graphene oxide-based nanomaterials along with their different advanced functionalized nanocomposites. The present chapter also focuses on various applications of GO and its modified nanocomposites as adsorbents and membrane modifiers toward wastewater treatment and the removal of harmful water pollutants. Various industrial and agricultural wastewaters containing heavy metals, dyes, pesticides, and radionuclides that were treated with such advanced GO-modified nanomaterials are discussed in detail in this chapter, along with their future scope of modification and advancements for better efficiency.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
F. Pendolino, N. Armata, Graphene Oxide in Environmental Remediation Process, (Springer, Cham, 2017). https://doi.org/10.1007/978-3-319-60429-9
P.P. Das, A. Anweshan, P. Mondal, A. Sinha, P. Biswas, S. Sarkar, M.K. Purkait, Integrated ozonation assisted electrocoagulation process for the removal of cyanide from steel industry wastewater. Chemosphere 263, 128370 (2021). https://doi.org/10.1016/j.chemosphere.2020.128370
P.P. Das, P. Mondal, Anweshan, A. Sinha, P. Biswas, S. Sarkar, M.K. Purkait, Treatment of steel plant generated biological oxidation treated (BOT) wastewater by hybrid process, Sep. Purif. Technol. 258, 118013 (2021). https://doi.org/10.1016/j.seppur.2020.118013
Deepti, A. Sinha, P. Biswas, S. Sarkar, U. Bora, M.K. Purkait, Separation of chloride and sulphate ions from nanofiltration rejected wastewater of steel industry J. Water Process Eng. 33 (2020). 10110810.1016/j.jwpe.2019.101108
A. Deepti, P. Sinha, S. Biswas, U. Sarkar, M.K. Bora, Purkait, Utilization of LD slag from steel industry for the preparation of MF membrane. J. Environ. Manage. 259, 110060 (2020). https://doi.org/10.1016/j.jenvman.2019.110060
N.A. Yaranal, S. Subbiah, K. Mohanty, Environmental Technology & Innovation Identification, extraction of microplastics from edible salts and its removal from contaminated seawater. Environ. Technol. Innov. 21, 101253 (2021). https://doi.org/10.1016/j.eti.2020.101253
P. Mondal, N.S. Samanta, A. Kumar, M.K. Purkait, Recovery of H2SO4 from wastewater in the presence of NaCl and KHCO3 through pH responsive polysulfone membrane: optimization approach. Polym. Test. 86, 106463 (2020). https://doi.org/10.1016/j.polymertesting.2020.106463
M. Baláž, Eggshell membrane biomaterial as a platform for applications in materials science. Acta Biomater. 10(9), 3827–3843 (2014). https://doi.org/10.1016/j.actbio.2014.03.020
S.C. Smith, D.F. Rodrigues, Carbon-based nanomaterials for removal of chemical and biological contaminants from water: a review of mechanisms and applications. Carbon 91, 122–143 (2015). https://doi.org/10.1016/j.carbon.2015.04.043
A.D. Sontakke, P.P. Das, P. Mondal, M.K. Purkait, Thin-film composite nanofiltration hollow fiber membranes toward textile industry effluent treatment and environmental remediation applications: review. Emergent Mater. (2021). https://doi.org/10.1007/s42247-021-00261-y
X. Liu, R. Ma, X. Wang, Y. Ma, Y. Yang, L. Zhuang, S. Zhang, R. Jehan, J. Chen, X. Wang, Graphene oxide-based materials for ef fi cient removal of heavy metal ions from aqueous solution: a review. Environ. Pollut. 252, 62–73 (2019). https://doi.org/10.1016/j.envpol.2019.05.050
Y. Zhu, S. Murali, W. Cai, X. Li, J.W. Suk, J.R. Potts, R.S. Ruoff, Graphene and graphene oxide: synthesis, properties, and applications. Adv. Mater. 22(35), 3906–3924 (2010). https://doi.org/10.1002/adma.201001068
W. Ren, H.-M. Cheng, The global growth of graphene. Nat. Nanotechnol. 9, 726–730 (2014). https://doi.org/10.1038/nnano.2014.229
P. Dhar, S.S. Gaur, A. Kumar, V. Katiyar, Cellulose nanocrystal templated graphene nanoscrolls for high performance supercapacitors and hydrogen storage: an experimental and molecular simulation study. Sci. Rep. 8, 1–15 (2018). https://doi.org/10.1038/s41598-018-22123-0
S.B. Singh, M. De, Scope of doped mesoporous (<10 nm) surfactant-modified alumina templated carbons for hydrogen storage applications. Int. J. Energy Res. 43, 4264–4280 (2019). https://doi.org/10.1002/er.4552
P. Jha, A. Sontakke, Application of crop-residue biomass as a catalyst for bio-diesel production from waste cooking oil, in Proceedings of the International Conference on Advances in Chemical Engineering (AdChE) 2020. University of Petroleum and Energy Studies, the Engineering Research Network (EngRN), February 5, 2020. Available at SSRN: https://ssrn.com/abstract=3705099 or http://dx.doi.org/https://doi.org/10.2139/ssrn.3705099
H.M. Hegab, L. Zou, Graphene oxide-assisted membranes: fabrication and potential applications in desalination and water purification. J. Memb. Sci. 484, 95–106 (2015). https://doi.org/10.1016/j.memsci.2015.03.011
S.I. Siddiqui, S.A. Chaudhry, A review on graphene oxide and its composites preparation and their use for the removal of As3+and As5+ from water under the effect of various parameters: application of isotherm, kinetic and thermodynamics. Process Saf. Environ. Prot. 119, 138–163 (2018). https://doi.org/10.1016/j.psep.2018.07.020
A.D. Sontakke, M.K. Purkait, Fabrication of ultrasound-mediated tunable graphene oxide nanoscrolls. Ultrason. Sonochem. 63, 104976 (2020). https://doi.org/10.1016/j.ultsonch.2020.104976
B.C. Brodie, On the atomic weight of graphite. Philos. Trans. R. Soc. Lond. 149, 249–259 (1859). https://doi.org/10.1098/rstl.1859.0013
L. Staudenmaier, Verfahren zur Darstellung der Graphitsäure. Ber. Der Dtsch. Chem. Gesellschaft. 31(2), 1481–1487 (1898). https://doi.org/10.1002/cber.18980310237
W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958). https://doi.org/10.1021/ja01539a017
D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L.B. Alemany, W. Lu, J.M. Tour, Improved synthesis of graphene oxide. ACS Nano 4(8), 4806–4814 (2010). https://doi.org/10.1021/nn1006368
L. Sun, B. Fugetsu, Mass production of graphene oxide from expanded graphite. Mater. Lett. 109, 207–210 (2013). https://doi.org/10.1016/j.matlet.2013.07.072
L. Peng, Z. Xu, Z. Liu, Y. Wei, H. Sun, Z. Li, X. Zhao, C. Gao, An iron-based green approach to 1-h production of single-layer graphene oxide. Nat. Commun. 6, 5716 (2015). https://doi.org/10.1038/ncomms6716
X. Pan, J. Ji, N. Zhang, M. **ng, Research progress of graphene-based nanomaterials for the environmental remediation. Chin. Chem. Lett. 31, 1462–1473 (2020). https://doi.org/10.1016/j.cclet.2019.10.002
F. Perreault, A.F. De Faria, M. Elimelech, Environmental applications of graphene-based nanomaterials. Chem. Soc. Rev. 44, 5861–5896 (2015). https://doi.org/10.1039/c5cs00021a
S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7), 1558–1565 (2007). https://doi.org/10.1016/j.carbon.2007.02.034
K. Mohanapriya, N. Jha, Fabrication of one dimensional graphene nanoscrolls for high performance supercapacitor application. Appl. Surf. Sci. 449, 461–467 (2018). https://doi.org/10.1016/j.apsusc.2017.12.186
A.D. Sontakke, M.K. Purkait, A brief review on graphene oxide nanoscrolls: structure, synthesis, characterization and scope of applications. Chem. Eng. J. 420, 129914 (2021). https://doi.org/10.1016/j.cej.2021.129914
P.D.P. Swetha, H. Manisha, K. Sudhakaraprasad, Graphene and graphene-based materials in biomedical science. Part. Syst. Charact. 35(8), 1–29 (2018). https://doi.org/10.1002/ppsc.201800105
V.B. Mohan, K-tak Lau, D. Hui, D. Bhattacharyya, Graphene-based materials and their composites: A review on production, applications and product limitations. Compos. B. Eng. 142, 200–220 (2018). https://doi.org/10.1016/j.compositesb.2018.01.013
Q. Wang, L. Lei, X. Kang, X. Su, F. Wang, C. Wang, J. Zhao, Z. Chen, Preparation of the crosslinked GO/PAA aerogel and its adsorption properties for Pb(II) ions. Mater. Res. Express 7(2), 025514 (2020). https://doi.org/10.1088/2053-1591/ab726a
N. Gupta, S. Bhagat, M. Singh, A.K. Jangid, V. Bansal, S. Singh, D. Pooja, H. Kulhari, Site-specific delivery of a natural chemotherapeutic agent to human lung cancer cells using biotinylated 2D rGO nanocarriers. Mater. Sci. Eng. C. 112, 110884 (2020). https://doi.org/10.1016/j.msec.2020.110884
M. Kumar, Z. Gholamvand, A. Morrissey, K. Nolan, M. Ulbricht, J. Lawler, Preparation and characterization of low fouling novel hybrid ultrafiltration membranes based on the blends of GO-TiO2 nanocomposite and polysulfone for humic acid removal. J. Memb. Sci. 506, 38–49 (2016). https://doi.org/10.1016/j.memsci.2016.02.005
E. Perim, L.D. Machado, D.S. Galvao, A brief review on syntheses, structures, and applications of nanoscrolls. Front. Mater. 1, 31 (2014). https://doi.org/10.3389/fmats.2014.00031
Y.E. Shin, Y.J. Sa, S. Park, J. Lee, K.H. Shin, S.H. Joo, H. Ko, An ice-templated, pH-tunable self-assembly route to hierarchically porous graphene nanoscroll networks. Nanoscale 6(16), 9734–9741 (2014). https://doi.org/10.1039/c4nr01988a
C. Zhao, X. Song, Y. Liu, Y. Fu, L. Ye, N. Wang, F. Wang, L. Li, M. Mohammadniaei, M. Zhang, Q. Zhang, J. Liu, Synthesis of graphene quantum dots and their applications in drug delivery. J. Nanobiotechnol. 18, 142 (2020). https://doi.org/10.1186/s12951-020-00698-z
S. Chung, R.A. Revia, M. Zhang, Graphene quantum dots and their applications in bioimaging, biosensing, and therapy. Adv. Mater. 33(22), 1904362 (2021). https://doi.org/10.1002/adma.201904362
A. Boretti, S. Al-Zubaidy, M. Vaclavikova, M. Al-Abri, S. Castelletto, S. Mikhalovsky, Outlook for graphene-based desalination membranes. Npj Clean Water. 1, 5 (2018). https://doi.org/10.1038/s41545-018-0004-z
J. Song, X. Wang, C-T. Chang, Preparation and characterization of graphene oxide. J. Nanomater. 276143 (2014). https://doi.org/10.1155/2014/276143
E. Starodub, N.C. Bartelt, K.F. Mccarty, Oxidation of graphene on metals. J. Phys. Chem. C 114(11), 5134–5140 (2010). https://doi.org/10.1021/jp912139e
C. Bosch-Navarro, F. Busolo, E. Coronado, Y. Duan, C. MartÃ-Gastaldo, H. Prima-Garcia, Influence of the covalent grafting of organic radicals to graphene on its magnetoresistance. J. Mater. Chem. C. 1, 4590–4598 (2013). https://doi.org/10.1039/c3tc30799a
V. Panwar, A. Kumar, R. Singh, P. Gupta, S.S. Ray, S.L. Jain, Nickel-decorated graphene oxide/polyaniline hybrid: a robust and highly efficient heterogeneous catalyst for hydrogenation of terminal alkynes. Ind. Eng. Chem. Res. 54(45), 11493–11499 (2015). https://doi.org/10.1021/acs.iecr.5b02888
A.T. Smith, A. Marie, S. Zeng, B. Liu, L. Sun, Nano materials science synthesis, properties, and applications of graphene oxide/reduced graphene oxide and their nanocomposites. Nano Mater. Sci. 1, 31–47 (2019). https://doi.org/10.1016/j.nanoms.2019.02.004
K.K.H. De Silva, H. Huang, R.K. Joshi, M. Yoshimura, Chemical reduction of graphene oxide using green reductants. Carbon 119, 190–199 (2017). https://doi.org/10.1016/j.carbon.2017.04.025
R.K. Singh, R. Kumar, D.P. Singh, Graphene oxide: strategies for synthesis, reduction and frontier applications. RSC Adv. 6, 64993–65011 (2016). https://doi.org/10.1039/c6ra07626b
B.H. Shin, K.K. Kim, A. Benayad, S.-M. Yoon, H.K. Park, I.-S. Jung, M.H. **, H.-K. Jeong, J.M. Kim, J.-Y. Choi, Y.H. Lee, Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv. Funct. Mater. 19(12), 1987–1992 (2009). https://doi.org/10.1002/adfm.200900167
W. Yu, Li Sisi, Y. Haiyan, L. Jie, Progress in the functional modification of graphene/graphene oxide: a review. RSC Adv. 10, 15328–15345 (2020). https://doi.org/10.1039/d0ra01068e
C.-I. Wang, A.P. Periasamy, H.-T. Chang, Photoluminescent C-dots@RGO probe for sensitive and selective detection of acetylcholine. Anal. Chem. 85(6), 3263–3270 (2013). https://doi.org/10.1021/ac303613d
E.N. Zare, A. Mudhoo, M.A. Khan, M. Otero, Z.M.A. Bundhoo, C. Navarathna, M. Patel, A. Srivastava, C.U. Pittman, T. Mlsna, D. Mohan, P. Makvandi, M. Sillanpää, Water decontamination using bio-based, chemically functionalized, doped, and ionic liquid-enhanced adsorbents: review. Environ. Chem. Lett. 19(4), 3075–3114 (2021). https://doi.org/10.1007/s10311-021-01207-w
Y. Cao, Z., J. Feng, P. Wu, Graphene oxide sheets covalently functionalized with block copolymersvia click chemistry as reinforcing fillers. J. Mater. Chem. 21(25), 9271–9278 (2011). https://doi.org/10.1039/C1JM10420A
C. Meng, Q. Chen, X. Li, H. Liu, Controlling covalent functionalization of graphene oxide membranes to improve enantioseparation performances. J. Memb. Sci. 582, 83–90 (2019). https://doi.org/10.1016/j.memsci.2019.03.087
I.A. Vacchi, Jésus Raya, A. Bianco, C. Ménard-Moyon, Controlled derivatization of hydroxyl groups of graphene oxide in mild conditions. 2D Mater. 5, 035037 (2018)
M. Namvari, C.S. Biswas, Q. Wang, W. Liang, F.J. Stadler, Journal of colloid and interface science crosslinking hydroxylated reduced graphene oxide with RAFT-CTA: a nano-initiator for preparation of well-defined amino acid-based polymer nanohybrids. J. Colloid Interface Sci. 504, 731–740 (2017). https://doi.org/10.1016/j.jcis.2017.06.007
Z. **, T.P. Mcnicholas, C. Shih, Q.H. Wang, G.L.C. Paulus, A.J. Hilmer, S. Shimizu, M.S. Strano, Click chemistry on solution-dispersed graphene and monolayer CVD graphene. Chem. Mater. 23(14), 3362–3370 (2011). https://doi.org/10.1021/cm201131v
B. Zhao, P. Liu, D. Liu, T.J. Kolibaba, C. Zhang, Functionalized graphene oxide based on hydrogen- bonding interaction in water : preparation and flame-retardation on epoxy resin. Macromol. Mater. Eng. 304(8), 1900164 (2019) 1–10. https://doi.org/10.1002/mame.201900164
M. Sahli, A. Kamari, S. Abu, S. Najiah, M. Yusoff, I. Fatimah, E. Phillip, S. Mohammad, Chitosan-graphene oxide nanocomposites as water-solubilising agents for rotenone pesticide. J. Mol. Liq. 318(114066), 114066 (2020). https://doi.org/10.1016/j.molliq.2020.114066
M. He, R. Zhang, K. Zhang, Y. Liu, Y. Su, Z. Jiang, Reduced graphene oxide aerogel membranes fabricated through hydrogen bond mediation for highly efficient oil/water separation. J. Mater. Chem. A 7(18), 11468–11477 (2019). https://doi.org/10.1039/c9ta01700c
B.A.J. Patil, J.L. Vickery, T.B. Scott, S. Mann, Aqueous stabilization and self-assembly of graphene sheets into layered bio-nanocomposites using DNA. Adv. Mater. 21(31), 3159–3164 (2009). https://doi.org/10.1002/adma.200803633
G. Liu, H. Ye, A. Li, C. Zhu, H. Jiang, Y. Liu, Graphene oxide for high-efficiency separation membranes: role of electrostatic interactions. Carbon 110, 56–61 (2016). https://doi.org/10.1016/j.carbon.2016.09.005
X. Ge, H. Li, L. Wu, P. Li, X. Mu, Y. Jiang, Improved mechanical and barrier properties of starch film with reduced graphene oxide modified by SDBS. Appl. Polym. 134(22), 44910 (2017). https://doi.org/10.1002/app.44910
D. Zhao, Construction of a different polymer chain structure to study π - π interaction between polymer and reduced graphene oxide. Polymers 10(7), 716 (2018). https://doi.org/10.3390/polym10070716
Y. Shudo, M.R. Karim, R. Ohtani, M. Nakamura, S. Hayami, Hybrids from the π-π stacking of graphene oxide and aromatic sulfonic compounds for improved proton conductivity. ChemElectroChem, 5(2), 238–241 (2018). https://doi.org/10.1002/celc.201701026
J. Zhang, Y. Xu, L. Cui, A. Fu, W. Yang, C. Barrow, J. Liu, Mechanical properties of graphene films enhanced by homo-telechelic functionalized polymer fillers via π – π stacking interactions. Compos. Part A Appl. Sci. 71, 1–8 (2015). https://doi.org/10.1016/j.compositesa.2014.12.013
X. Liu, R. Ma, X. Wang, Y. Ma, Y. Yang, L. Zhuang, S. Zhang, R. Jehan, J. Chen, X. Wang, Graphene oxide-based materials for efficient removal of heavy metal ions from aqueous solution: a review. Environ. Pollut. 252, 62–73 (2019). https://doi.org/10.1016/j.envpol.2019.05.050
E.N. Zare, M.M. Lakouraj, N. Kasirian, Development of effective nano-biosorbent based on poly m-phenylenediamine grafted dextrin for removal of Pb(II) and methylene blue from water. Carbohydr. Polym. 201, 539–548 (2018). https://doi.org/10.1016/j.carbpol.2018.08.091
G.Z. Kyzas, E.A. Deliyanni, K.A. Matis, Graphene oxide and its application as an adsorbent for wastewater treatment. J. Chem. Technol. Biotechnol. 89(2), 196–205 (2014). https://doi.org/10.1002/jctb.4220
F. Li, X. Jiang, J. Zhao, S. Zhang, Graphene oxide: a promising nanomaterial for energy and environmental applications. Nano Energy 16, 488–515 (2015). https://doi.org/10.1016/j.nanoen.2015.07.014
M. Zarenezhad, M. Zarei, M. Ebratkhahan, M. Hosseinzadeh, Synthesis and study of functionalized magnetic graphene oxide for Pb2+ removal from wastewater. Environ. Technol. Innov. 22, 101384 (2021). https://doi.org/10.1016/j.eti.2021.101384
M. Majdoub, A. Amedlous, Z. Anfar, A. Jada, N. El Alem, Engineering of amine-based binding chemistry on functionalized graphene oxide/alginate hybrids for simultaneous and efficient removal of trace heavy metals: towards drinking water. J. Colloid Interface Sci. 589, 511–524 (2021). https://doi.org/10.1016/j.jcis.2021.01.029
J. Huo, G. Yu, J. Wang, Efficient removal of Co(II) and Sr(II) from aqueous solution using polyvinyl alcohol/graphene oxide/MnO2 composite as a novel adsorbent. J. Hazard. Mater. 411, 125117 (2021). https://doi.org/10.1016/j.jhazmat.2021.125117
R. Mukherjee, P. Bhunia, S. De, Impact of graphene oxide on removal of heavy metals using mixed matrix membrane. Chem. Eng. J. 292, 284–297 (2016). https://doi.org/10.1016/j.cej.2016.02.015
H. Ravishankar, J. Christy, V. Jegatheesan, Graphene oxide (GO) -blended polysulfone (PSf) ultrafiltration membranes for lead ion rejection. Membranes 8(3), 77 (2018). https://doi.org/10.3390/membranes8030077
Y. Zhang, H. Chi, W. Zhang, Y. Sun, Q. Liang, Y. Gu, R. **g, Highly efficient adsorption of copper ions by a PVP-reduced graphene oxide based on a new adsorptions mechanism. Nano-Micro Lett. 6, 80–87 (2014). https://doi.org/10.1007/BF03353772
C.J. Madadrang, H.Y. Kim, G. Gao, N. Wang, J. Zhu, H. Feng, M. Gorring, M.L. Kasner, S. Hou, Adsorption behavior of EDTA-graphene oxide for Pb(II) removal. ACS Appl. Mater. Interfaces. 4(3), 1186–1193 (2012). https://doi.org/10.1021/am201645g
S. Kumar, R.R. Nair, P.B. Pillai, S.N. Gupta, M.A.R. Iyengar, A.K. Sood, Graphene oxide-MnFe2O4 magnetic nanohybrids for efficient removal of lead and arsenic from water. ACS Appl. Mater. Interfaces. 6(20), 17426–17436 (2014). https://doi.org/10.1021/am504826q
X. Luo, C. Wang, S. Luo, R. Dong, X. Tu, G. Zeng, Adsorption of As(III) and As(V) from water using magnetite Fe3O4-reduced graphite oxide-MnO2 nanocomposites. Chem. Eng. J. 187, 45–52 (2012). https://doi.org/10.1016/j.cej.2012.01.073
Y. Zhang, L. Yan, W. Xu, X. Guo, L. Cui, L. Gao, Q. Wei, B. Du, Adsorption of Pb(II) and Hg(II) from aqueous solution using magnetic CoFe2O4-reduced graphene oxide. J. Mol. Liq. 191, 177–182 (2014). https://doi.org/10.1016/j.molliq.2013.12.015
I. Khurana, A. Saxena, Bharti, J.M. Khurana, P.K. Rai, Removal of dyes using graphene-based composites: a review. Water Air Soil Pollut. 228, 180 (2017). https://doi.org/10.1007/s11270-017-3361-1
B. Mao, B. Sidhureddy, A.R. Thiruppathi, P.C. Wood, A. Chen, Efficient dye removal and separation based on graphene oxide nanomaterials. New J. Chem. 44(11), 4519–4528 (2020). https://doi.org/10.1039/c9nj05895h
F. Hanke, C. Palma, P. Samori, M. Cecchini, J. Bj, G. Monge, Adsorption of aromatic and anti-aromatic systems on graphene through π–π stacking. J. Phys. Chem. Lett. 1(23), 3407–3412 (2010). https://doi.org/10.1021/jz101360k
S. De Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sustain. Mater. Technol. 9, 10–40 (2016). https://doi.org/10.1016/j.susmat.2016.06.002
A. Rhay, B. Bayantong, Y. Shih, D.C. Ong, R. Ruffel, M. Abarca, C. Dong, M. Daniel, G. De Luna, Adsorptive removal of dye in wastewater by metal ferrite-enabled graphene oxide nanocomposites. Chemosphere 274, 129518 (2021). https://doi.org/10.1016/j.chemosphere.2020.129518
M. Hong, Y. Wang, R. Wang, Y. Sun, R. Yang, L. Qu, Z. Li, Poly ( sodium styrene sulfonate) functionalized graphene as a highly efficient adsorbent for cationic dye removal with a green regeneration strategy. J. Phys. Chem. Solids. 152, 109973 (2021). https://doi.org/10.1016/j.jpcs.2021.109973
Y. Gao, S. Yan, Y. He, Y. Fan, L. Zhang, J. Ma, A photo-Fenton self-cleaning membrane based on NH2-MIL-88B (Fe) and graphene oxide to improve dye removal performance. J. Membr. Sci. 626, 119192 (2021). https://doi.org/10.1016/j.memsci.2021.119192
S. Pashaei-Fakhri, S. Jamaleddin, R. Foroutan, Crystal violet dye sorption over acrylamide/graphene oxide bonded sodium alginate nanocomposite hydrogel. Chemosphere 270, 129419 (2021). https://doi.org/10.1016/j.chemosphere.2020.129419
J. Chen, S. Liu, H. Ge, Y. Zou, A hydrophobic bio-adsorbent synthesized by nanoparticle-modified graphene oxide coated corn straw pith for dye adsorption and photocatalytic degradation. Environ. Technol. 41(27), 3633–3645 (2020). https://doi.org/10.1080/09593330.2019.1616827
N. Li, M. Zheng, X. Chang, G. Ji, H. Lu, L. Xue, L. Pan, J. Cao, Preparation of magnetic CoFe2O4-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties. J. Solid State Chem. 184(2), 953–958 (2011). https://doi.org/10.1016/j.jssc.2011.01.014
S.-T. Yang, S. Chen, Y. Chang, A. Cao, Y. Liu, H. Wang, Removal of methylene blue from aqueous solution by graphene oxide. J. Colloid Interface Sci. 359(1), 24–29 (2011). https://doi.org/10.1016/j.jcis.2011.02.064
G.K. Ramesha, A.V. Kumara, H.B. Muralidhara, S. Sampath, Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. J. Colloid Interface Sci. 361(1), 270–277 (2011). https://doi.org/10.1016/j.jcis.2011.05.050
D. Robati, B. Mirza, M. Rajabi, O. Moradi, I. Tyagi, S. Agarwal, V.K. Gupta, Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase. Chem. Eng. J. 284, 687–697 (2016). https://doi.org/10.1016/j.cej.2015.08.131
C. Hu, A.T. Le, S.Y. Pung, L. Stevens, N. Neate, X. Hou, D. Grant, F. Xu, Efficient dye-removal via Ni-decorated graphene oxide-carbon nanotube nanocomposites. Mater. Chem. Phys. 260, 124117 (2021). https://doi.org/10.1016/j.matchemphys.2020.124117
P.K. Boruah, B. Sharma, N. Hussain, M.R. Das, Magnetically recoverable Fe3O4/graphene nanocomposite towards efficient removal of triazine pesticides from aqueous solution: investigation of the adsorption phenomenon and specific ion effect. Chemosphere 168, 1058–1067 (2017). https://doi.org/10.1016/j.chemosphere.2016.10.103
K. Shrivas, A. Ghosale, N. Nirmalkar, A. Srivastava, S.K. Singh, S.S. Shinde, Removal of endrin and dieldrin isomeric pesticides through stereoselective adsorption behavior on the graphene oxide-magnetic nanoparticles. Environ. Sci. Pollut. Res. 24, 24980–24988 (2017). https://doi.org/10.1007/s11356-017-0159-z
M. Cruz, C. Gomez, C.J. Duran-Valle, L.M. Pastrana-MartÃnez, J.L. Faria, A.M.T. Silva, M. Faraldos, A. Bahamonde, Bare TiO2 and graphene oxide TiO2 photocatalysts on the degradation of selected pesticides and influence of the water matrix. Appl. Surf. Sci. 416, 1013–1021 (2017). https://doi.org/10.1016/j.apsusc.2015.09.268
Y. Tian, Y. Wang, Z. Sheng, T. Li, X. Li, A colorimetric detection method of pesticide acetamiprid by fine-tuning aptamer length. Anal. Biochem. 513, 87–92 (2016). https://doi.org/10.1016/j.ab.2016.09.004
K.L. Klarich, N.C. Pflug, E.M. Dewald, M.L. Hladik, D.W. Kolpin, D.M. Cwiertny, G.H. Lefevre, Occurrence of neonicotinoid insecticides in finished drinking water and fate during drinking water treatment. Environ. Sci. Technol. Lett. 4(5), 168–173 (2017). https://doi.org/10.1021/acs.estlett.7b00081
G. Liu, L. Li, D. Xu, X. Huang, X. Xu, S. Zheng, Y. Zhang, H. Lin, Metal-organic framework preparation using magnetic graphene oxide–β-cyclodextrin for neonicotinoid pesticide adsorption and removal. Carbohydr. Polym. 175, 584–591 (2017). https://doi.org/10.1016/j.carbpol.2017.06.074
G. Liu, X. Yang, T. Li, Y. She, S. Wang, J. Wang, M. Zhang, F. **, M. **, H. Shao, M. Shi, Preparation of a magnetic molecularly imprinted polymer using g-C3N4–Fe3O4 for atrazine adsorption. Mater. Lett. 160, 472–475 (2015). https://doi.org/10.1016/j.matlet.2015.07.157
L.P. Lingamdinne, J.R. Koduru, H. Roh, Y.-L. Choi, Y.-Y. Chang, J.-K. Yang, Adsorption removal of Co(II) from waste-water using graphene oxide. Hydrometallurgy 165, 90–96 (2016). https://doi.org/10.1016/j.hydromet.2015.10.021
L.P. Lingamdinne, J.R. Koduru, R.R. Karri, A comprehensive review of applications of magnetic graphene oxide based nanocomposites for sustainable water purification. J. Environ. Manage. 231, 622–634 (2019). https://doi.org/10.1016/j.jenvman.2018.10.063
P. Misaelides, A. Godelitsas, A. Filippidis, D. Charistos, I. Anousis, Thorium and uranium uptake by natural zeolitic materials. Sci. Total Environ. 173–174, 237–246 (1995). https://doi.org/10.1016/0048-9697(95)04748-4
G. Zhao, T. Wen, X. Yang, S. Yang, J. Liao, J. Hu, D. Shao, X. Wang, Preconcentration of U(VI) ions on few-layered graphene oxide nanosheets from aqueous solutions. Dalton Trans. 41, 6182–6188 (2012). https://doi.org/10.1039/c2dt00054g
P. Zong, S. Wang, Y. Zhao, H. Wang, H. Pan, C. He, Synthesis and application of magnetic graphene/iron oxides composite for the removal of U(VI) from aqueous solutions. Chem. Eng. J. 220, 45–52 (2013). https://doi.org/10.1016/j.cej.2013.01.038
Y. Zhao, J. Li, S. Zhang, H. Chen, D. Shao, Efficient enrichment of uranium(vi) on amidoximated magnetite/graphene oxide composites. RSC Adv. 3(41), 18952–18959 (2013). https://doi.org/10.1039/c3ra42236d
Y. Sun, C. Ding, W. Cheng, X. Wang, Simultaneous adsorption and reduction of U(VI) on reduced graphene oxide-supported nanoscale zerovalent iron. J. Hazard. Mater. 280, 399–408 (2014). https://doi.org/10.1016/j.jhazmat.2014.08.023
Z. Fallah, E.N. Zare, M. Ghomi, F. Ahmadijokani, M. Amini, M. Tajbakhsh, M. Arjmand, G. Sharma, H. Ali, A. Ahmad, P. Makvandi, E. Lichtfouse, M. Sillanpää, R.S. Varma, Toxicity and remediation of pharmaceuticals and pesticides using metal oxides and carbon nanomaterials. Chemosphere 275, 130055 (2021). https://doi.org/10.1016/j.chemosphere.2021.130055
V. Srivastava, E.N. Zare, P. Makvandi, X-qi Zheng, S. Iftekhar, A. Wu, V.V.T. Padil, B. Mokhtari, R.S. Varma, F.R. Tay, M. Sillanpaa, Cytotoxic aquatic pollutants and their removal by nanocomposite-based sorbents. Chemosphere. 258, 127324 (2020). https://doi.org/10.1016/j.chemosphere.2020.127324
M. Sarker, J.Y. Song, S.H. Jhung, Adsorptive removal of anti-inflammatory drugs from water using graphene oxide/metal-organic framework composites. Chem. Eng. J. 335, 74–81 (2018). https://doi.org/10.1016/j.cej.2017.10.138
S. Bhattacharyya, in Waste Management and Resource Efficiency: Proceedings of 6th IconSWM 2016, ed. by S. K. Ghosh (Springer, Singapore, 2019), p. 1253. https://doi.org/10.1007/978-981-10-7290-1_104
S. Bhattacharya, P. Banerjee, P. Das, A. Bhowal, S.K. Majumder, P. Ghosh, Erratum: removal of aqueous carbamazepine using graphene oxide nanoplatelets: process modelling and optimization Sustain. Environ. Res. 30, 17 (2020). https://doi.org/10.1186/s42834-020-00062-8), Sustain. Environ. Res. 30, 25 (2020). https://doi.org/10.1186/s42834-020-00066-4
C.M. El-Maraghy, O.M. El-Borady, O.A. El-Naem, Effective removal of levofloxacin from pharmaceutical wastewater using synthesized zinc oxid, graphen oxid nanoparticles compared with their combination. Sci. Rep. 10, 5914 (2020). https://doi.org/10.1038/s41598-020-61742-4
P.T.L. Huong, N. Tu, H. Lan, L.H. Thang, N.V. Quy, P.A. Tuan, N.X. Dinh, V.N. Phan, A.-T. Le, Functional manganese ferrite/graphene oxide nanocomposites: effects of graphene oxide on the adsorption mechanisms of organic MB dye and inorganic As(v) ions from aqueous solution. RSC Adv. 8(22), 12376–12389 (2018). https://doi.org/10.1039/c8ra00270c
A. Khan, J. Wang, J. Li, X. Wang, Z. Chen, A. Alsaedi, T. Hayat, Y. Chen, X. Wang, The role of graphene oxide and graphene oxide-based nanomaterials in the removal of pharmaceuticals from aqueous media: a review. Environ. Sci. Pollut. Res. 24, 7938–7958 (2017). https://doi.org/10.1007/s11356-017-8388-8
L. Ou, B. Song, H. Liang, J. Liu, X. Feng, B. Deng, T. Sun, L. Shao, Toxicity of graphene-family nanoparticles: a general review of the origins and mechanisms. Part. Fibre Toxicol. 13, 57 (2016). https://doi.org/10.1186/s12989-016-0168-y
S.G. Han, J.K. Kim, J.H. Shin, J.H. Hwang, J.S. Lee, T.-G. Kim, J.H. Lee, G.H. Lee, K.S. Kim, H.S. Lee, N.W. Song, K. Ahn, I.J. Yu, Pulmonary responses of sprague-dawley rats in single inhalation exposure to graphene oxide nanomaterials. Biomed Res. Int. 2015, 376756 (2015). https://doi.org/10.1155/2015/376756
Y. Chang, S.-T. Yang, J.-H. Liu, E. Dong, Y. Wang, A. Cao, Y. Liu, H. Wang, In vitro toxicity evaluation of graphene oxide on A549 cells. Toxicol. Lett. 200(3), 201–210 (2011). https://doi.org/10.1016/j.toxlet.2010.11.016
F. Ahmed, D.F. Rodrigues, Investigation of acute effects of graphene oxide on wastewater microbial community: a case study. J. Hazard. Mater. 256–257, 33–39 (2013). https://doi.org/10.1016/j.jhazmat.2013.03.064
E. Zanni, G.D. Bellis, M.P. Bracciale, A. Broggi, M.L. Santarelli, M.S. Sarto, C. Palleschi, D. Uccelletti, Graphite nanoplatelets and Caenorhabditis elegans: insights from an in vivo model. Nano Lett. 12(6), 2740–2744 (2012). https://doi.org/10.1021/nl204388p
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Sontakke, A.D., Mondal, P., Purkait, M.K. (2022). Graphene Oxide-Based Advanced Nanomaterials for Environmental Remediation Applications. In: Ikhmayies, S.J. (eds) Advanced Nanomaterials. Advances in Material Research and Technology. Springer, Cham. https://doi.org/10.1007/978-3-031-11996-5_6
Download citation
DOI: https://doi.org/10.1007/978-3-031-11996-5_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-11995-8
Online ISBN: 978-3-031-11996-5
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)