Recovery of Precious Metal Silver from Scrap Computer Keyboards

  • Conference paper
  • First Online:
REWAS 2022: Develo** Tomorrow’s Technical Cycles (Volume I)

Abstract

Silver (Ag) is extensively used in manufacturing of electronic goods due to its low cost and conductivity. In view of the escalating demand, stringent, environment rules, and limited sources of Ag, the present paper is focused on the development of hydrometallurgical process flow-sheet to extract Ag from scrap computer keyboards. These keyboards contain ~0.4% of Ag. Initially, keyboards were dismantled to separate the Mylar sheets scontaining Ag. The same were pyrolyzed at 300 °C for 2 h to get enriched metallic part. About 99.99% Ag was leached using 2 M HNO3 at 60 °C within 30 min in close and proper condensed system. Separation techniques (precipitation/cementation) could be used to obtain pure Ag salt/metal. Based on the laboratory-scale experiments, the process flow-sheet developed is economical, eco-friendly, and has potential to be translated to industry for commercial exploitation after scale up/pilot trial.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
EUR 29.95
Price includes VAT (Spain)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
EUR 160.49
Price includes VAT (Spain)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
EUR 207.99
Price includes VAT (Spain)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info
Hardcover Book
EUR 207.99
Price includes VAT (Spain)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Syed S (2016) Silver recovery aqueous techniques from diverse sources: hydrometallurgy in recycling. Waste Manag 50:234–256

    Article  Google Scholar 

  2. Tang B, Yu G, Fang J, Shi T (2010) Recovery of high-purity silver directly from dilute effluents by an emulsion liquid membrane-crystallization process. J Hazard Mater 177:377–383

    Article  Google Scholar 

  3. Alexander C, Always B, Litosh S, Wiebe J, Yao W, Saha D, Norton K (2019) World silver survey 2019

    Google Scholar 

  4. Forti V, Baldé CP, Kuehr R, Bel G (2020) The global E-waste monitor 2020 quantities, flows, and the circular economy potential

    Google Scholar 

  5. Birloaga I, Vegliò F (2018) Overview on hydrometallurgicprocedures for silver recovery from various wastes. J Environ Chem Eng 6:2932–2938

    Article  Google Scholar 

  6. **ng WD, Lee MS (2019) Development of a hydrometallurgical process for the recovery of gold and silver powders from anode slime containing copper, nickel, tin, and zinc. Gold Bull 52:69–77

    Article  Google Scholar 

  7. Samson SO, Muzenda E (2014) Review of silver recovery techniques from radiographic effluent and x-ray film waste. In: Proceedings of the world congress on engineering and computer science 2014 Vol II WCECS 2014, 22–24 Oct 2014, San Francisco, USA

    Google Scholar 

  8. Liu F, Wang J, Peng C, Liu Z, Wilson BP, Lundström M (2019) Recovery and separation of silver and mercury from hazardous zinc refinery residues produced by zinc oxygen pressure leaching. Hydrometallurgy 185:38–45

    Article  Google Scholar 

  9. Li JY, Xu XL, Liu WQ (2012) Thiourea leaching gold and silver from the printed circuit boards of waste mobile phones. Waste Manage 32(6):1209–1212

    Article  Google Scholar 

  10. Yoo J, So H, Yang MH, Lee KJ (2019) Effect of chloride ion on synthesis of silver nanoparticle using retrieved silver chloride as a precursor from the electronic scrap. Appl Surf Sci 475:781–784

    Article  Google Scholar 

  11. Gámez S, Garcés K, Torre EL, Guevara A (2019) Precious metals recovery from waste printed circuit boards using thiosulfate leaching and ion exchange resin

    Google Scholar 

  12. Gurung M, Adhikari BB, Kawakita H, Ohto K, Inoue K, Alam S (2013) Recovery of gold and silver from spent mobile phones by means of acidothiourea leaching followed by adsorption using biosorbent prepared from persimmon tanin. Hydrometallurgy 133:84–93

    Article  Google Scholar 

  13. Kumari A, Parween R, Chakravarty S, Parmar K, Pathak DD, Lee J-C, Jha MK (2019) Novel approach to recover rare earth metals (REMs) from Indian coal bottom ash. Hydrometallurgy 187:1–7

    Article  Google Scholar 

  14. Kumari A, Jha MK, Singh RP (2016) Recovery of metals from pyrolysed PCBs by hydrometallurgical techniques. Hydrometallurgy 165:97–105

    Article  Google Scholar 

Download references

Acknowledgements

Authors are thankful to Director, CSIR-National Metallurgical Laboratory, Jamshedpur, India, for giving permission to publish this paper. One of the authors Ms. Rekha Panda would like to extend her sincere gratitude to CSIR, New Delhi, for providing Senior Research Fellowship (Grant: 31/10(64)/2017-EMR-I) to carry out this research work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Manis Kumar Jha .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Panda, R., Dinkar, O.S., Choubey, P.K., Parween, R., Jha, M.K., Pathak, D.D. (2022). Recovery of Precious Metal Silver from Scrap Computer Keyboards. In: Lazou, A., Daehn, K., Fleuriault, C., Gökelma, M., Olivetti, E., Meskers, C. (eds) REWAS 2022: Develo** Tomorrow’s Technical Cycles (Volume I). The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-92563-5_9

Download citation

Publish with us

Policies and ethics

Navigation