Part of the book series: Springer Handbooks ((SHB))

  • 3938 Accesses

Abstract

Molecular photodissociation is the photoinitiated fragmentation of a bound molecule 1 . The purpose of this chapter is to outline the ways in which molecular photodissociation is studied in the gas phase 2 . The results are particularly relevant to the investigation of the species involved in combustion and atmospheric reactions 3 .

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
EUR 29.95
Price includes VAT (France)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
EUR 277.13
Price includes VAT (France)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
EUR 348.14
Price includes VAT (France)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free ship** worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  • Schinke, R.: Photodissociation Dynamics. Cambridge University Press, Cambridge (1993)

    Google Scholar 

  • Okabe, H.: Photochemistry of Small Molecules. Wiley, New York (1978)

    Google Scholar 

  • Wayne, R.P.: Chemistry of Atmospheres, 2nd edn. Oxford University Press, New York (1991)

    Google Scholar 

  • Herzberg, G.: Molecular Spectra and Molecular Structure III, Electronic Spectra and Electronic Structure of Polyatomic Molecules. Van Nostrand, New York (1967)

    Google Scholar 

  • Hall, G.E., Houston, P.L.: Ann. Rev. Phys. Chem. 40, 375 (1989)

    ADS  Google Scholar 

  • Zare, R.N.: Angular Momentum. Wiley, New York (1988)

    Google Scholar 

  • Grunewald, A.U., Gericke, K.-H., Comes, F.J.: J. Chem. Phys. 87, 5709 (1987)

    ADS  Google Scholar 

  • Grunewald, A.U., Gericke, K.-H., Comes, F.J.: J. Chem. Phys. 89, 345 (1988)

    ADS  Google Scholar 

  • Ashfold, M.N.R., Baggott, J.E. (eds.): Molecular Photodissociation Dynamics. Royal Society of Chemistry, London (1987)

    Google Scholar 

  • Scoles, G. (ed.): Atomic and Molecular Beams Methods. Oxford University Press, New York (1988)

    Google Scholar 

  • Crim, F.F.: Ann. Rev. Phys. Chem. 44, 397 (1993)

    ADS  Google Scholar 

  • Manz, J., Wöste, L. (eds.): Femtosecond Chemistry. VCH, Weinheim (1995)

    Google Scholar 

  • Ashfold, M.N.R., Lambert, I.R., Mordaunt, D.H., Morley, G.P., Western, C.M.: J. Phys. Chem. 96, 2938 (1992)

    Google Scholar 

  • Nesbet, R.K.: Variational Methods in Electron–Atom Scattering Theory. Plenum, New York (1980)

    Google Scholar 

  • Zhang, J.Z.H., Miller, W.H.: J. Phys. Chem. 92, 1811 (1990)

    Google Scholar 

  • Lefebvre, R.: J. Phys. Chem. 89, 4201 (1985)

    Google Scholar 

  • Reinhardt, W.P.: Ann. Rev. Phys. Chem. 33, 223 (1982)

    ADS  Google Scholar 

  • Kosloff, R.: J. Phys. Chem. 92, 2087 (1988)

    Google Scholar 

  • Hase, W.L., Cho, S., Lu, D., Swamy, K.N.: Chem Phys 139, 1 (1989)

    Google Scholar 

  • Robinson, P.J., Holbrook, K.A.: Unimolecular Reactions. Wiley, London (1972)

    Google Scholar 

  • Pechukas, P., Light, J.C.: J Chem Phys 42, 3285 (1965)

    ADS  Google Scholar 

  • Pechukas, P., Light, J.C., Rankin, C.: J Chem Phys 44, 794 (1966)

    ADS  Google Scholar 

  • Brody, T.A., Flores, J., French, J.B., Mello, P.A., Pandey, A., Wong, S.S.M.: Rev. Mod. Phys. 53, 385 (1981)

    ADS  Google Scholar 

  • Dixon, R.N.: Chem. Soc. Rev. 23, 375 (1994)

    Google Scholar 

  • Schinke, R.: Quantum mechanical studies of photodissociation dynamics using accurate global potential energy surfaces. In: Domcke, W., Yarkony, D.R., Köppel, H. (eds.) Conical Intersections. World Scientific, Singapore (2004)

    Google Scholar 

  • van Harrevelt, R., van Hemert, M.C.: J Chem Phys 112, 5777 (2000)

    ADS  Google Scholar 

  • Cheng, B.-M., Chung, C.-Y., Bahou, M., Lee, Y.-P., Lee, L.C., van Harrevelt, R., van Hemert, M.C.: J. Chem. Phys. 120, 224 (2004)

    ADS  Google Scholar 

  • Fillion, J.H., van Harrevelt, R., Ruiz, J., Castillejo, M., Zanganeh, A.H., Lemaire, J.L., van Hemert, M.C., Rostas, F.: J. Phys. Chem. A. 105, 11414 (2001)

    Google Scholar 

  • Harich, S.A., Yang, X.F., Yang, X., van Harrevelt, R., van Hemert, M.C.: Phys. Rev. Lett. 87, 263001 (2001)

    ADS  Google Scholar 

  • Zhu, H., Qu, Z.-W., Tashiro, M., Schinke, R.: Chem Phys Lett 384, 45 (2004)

    ADS  Google Scholar 

  • Matsumi, Y., Kawasaki, M.: Chem. Rev. 103, 4767 (2003)

    Google Scholar 

  • Schinke, R., Keller, H.-M., Stumpf, M., Dobbyn, A.J.: J. Phys. B 28, 3081 (1995)

    ADS  Google Scholar 

  • Neyer, D.W., Houston, P.L.: The HCO potential energy surface; probes using molecular scattering and photodissociation. In: Liu, K., Wagner, A. (eds.) The Chemical Dynamics and Kinetics of Small Radicals. World Scientific, Singapore (1994)

    Google Scholar 

  • Weiß, J., Schinke, R., Mandelshtam, V.A.: J Chem Phys 113, 4588 (2000)

    ADS  Google Scholar 

  • Weiß, J., Schinke, R.: J Chem Phys 115, 3173 (2001)

    ADS  Google Scholar 

  • Grebenshchikov, S.Y., Schinke, R., Hase, W.L.: State-specific dynamics of unimolecular dissociation. In: Green, N. (ed.) Unimolecular Kinetics. Elsevier, Amsterdam (2003)

    Google Scholar 

  • Moiseyev, N.: Phys Rep 302, 211 (1998)

    ADS  Google Scholar 

  • Mandelshtam, V.A., Taylor, H.S.: J Chem Phys 102, 7390 (1995)

    ADS  Google Scholar 

  • Mandelshtam, V.A., Taylor, H.S.: J Chem Phys 106, 5085 (1997)

    ADS  Google Scholar 

  • Delon, A., Reiche, F., Abel, B., Grebenshchikov, S.Yu., Schinke, R.: J. Phys. Chem. A 104, 10374 (2000)

    Google Scholar 

  • Skokov, S., Bowman, J.M.: J Chem Phys 110, 9789 (1999)

    ADS  Google Scholar 

  • Hauschildt, J., Weiß, J., Beck, C., Grebenshchikov, S. Yu., Düren, R., Schinke, R., Koput, J.: Chem. Phys. Lett. 300, 569 (1999)

    ADS  Google Scholar 

  • Hippler, H., Krasteva, N., Striebel, F.: Phys. Chem. Chem. Phys. 6, 3383 (2004)

    Google Scholar 

  • Sun, L., Hase, W.L.: Born–Oppenheimer direct dynamics classical trajectory simulations. In: Lipkowitz, K.B., Larter, R., Cundari, T.R. (eds.) Review in Computational Chemistry, vol. 19, Wiley-VCH, Hoboken, NJ (2003)

    Google Scholar 

  • Hase, W.L., Song, K., Gordon, M.S.: Comp. Sci. Eng. 5, 36 (2003)

    Google Scholar 

  • Bolton, K., Schlegel, H.B., Hase, W.L., Song, K.: Phys. Chem. Chem. Phys. 1, 999 (1999)

    Google Scholar 

  • Chen, W., Hase, W.L., Schlegel, H.B.: Chem Phys Lett 228, 436 (1994)

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Reinhard Schinke .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2023 Springer Nature Switzerland AG

About this chapter

Cite this chapter

Dobbyn, A.J., Mordaunt, D.H., Schinke, R. (2023). Molecular Photodissociation. In: Drake, G.W.F. (eds) Springer Handbook of Atomic, Molecular, and Optical Physics. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-030-73893-8_36

Download citation

Publish with us

Policies and ethics

Navigation