Abstract
Polyurethane foams are one of the versatile commercial materials ranging from solvent-based polyurethane foams to waterborne polyurethane foams (WPU). Waterborne polyurethanes are eco-friendly and exhibit excellent mechanical characteristics such as strength, flexibility, ease of moulding into required shapes, durability, lightweight and resistance to heat and moisture. Waterborne polyurethane foams have become anĀ essential part of our daily life; we cannot even imagine the future without these foams. These foams are used in almost all industries viz. construction, automobile, footwear, leather, textile, pharmaceutical and furniture, etc. Foams are also used in packaging industries for safeguarding delicate and fragile valuable goods during storage and transportation in addition to their use in applications in filtration, insulation and fashion designing. Waterborne polyurethanes also contribute to sustainable energy through their excellent heat and water insulating characteristics. Recent advancements in technology allowing the preparation of special-purpose WPU foams provide tailor-made solutions to all applications. New eco-friendly composite materials being developed in this area have ample opportunities for the growth of the WPU market in the near future.
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References
Aniceto, J. P. S., Portuga, I., & Silva, C. M. (2012). Biomass-based polyols through oxypropylation reaction. ChemSusChem, 5(8), 1358ā1368.
Badri, K. H. (2012). Biobased polyurethane from palm kernel oil-based polyol. Intech.
Biron, M. (2004). The plastics industry: Economic overview. Thermosets and Composites.
Boffito, M., Sartori, S., Mattu, C., & Ciardelli, G. (2016). Polyurethanes for cardiac applications. Advances in Polyurethane Biomaterials 387ā416.
Chattopadhyay, D. K., & Raju, K. V. S. N. (2007). Structural engineering of polyurethane coatings for high performance applications. Progress in Polymer Science, 32, 352ā418.
Chuayjuljit, S., Maungchareon, A., & Saravari, O. (2010). Preparation and properties of palm oil-based rigid polyurethane nanocomposite foams. Journal of Reinforced Plastics and Composites, 29, 218ā225. https://doi.org/10.1177/0731684408096949
Deng, R., Davies, P., & Bajaj, A. (2003). Flexible polyurethane foam modelling and identification of viscoelastic parameters for automotive seating applications. Journal of Sound and Vibration, 262, 391ā417.
Eaves, D. (2004). Handbook of Polymer Foams (p. 289). Rapra Technology Ltd.
EI-Wahab, H. A., EI-Fattah, M. A., Ayman, H. A., Elhenawy, A. A., & Alian, N. A. (2015). Synthesis and characterisation of some arylhydrazone ligand and its metal complexes and their potential application as flame retardant and antimicrobial additives in polyurethane for surface coating. Journal of Organometallic Chemistry, 791, 99ā106.
Filardo, G., Zaffagnini, S., Di Martino, A., Di Matteo, B., Muccioli, G. M. M., Busacca, M., & Marcacci, M. (2012). Biodegradable polyurethane meniscal scaffold for isolated partial lesions or as combined procedure for knees with multiple comorbidities: Clinical results at 2 years. Knee Surgery, Sport Traumatology Arthroscopy, 22, 128ā134. https://doi.org/10.1007/s00167-012-2328-4
Fridrihsone, A., Stirna, U., Lazdin, B., Misane, M., & Vilsone, D. (2013). Characterisation of polyurethane networks structure and properties based on rapeseed oil derived polyol. European Polymer Journal, 49, 1204ā1214.
Gama, N. V., Ferreira, A., & Barros-Timmons, A. (2018). Polyurethane foams: Past, present, and future materials 11, 1841.
Gandini, A., Pinto, C., Costa, J. J., & Pascoal, N. C. (2010). Process for the production of liquid polios of renewable origin by the liquefaction of agro-forestry and agro-food biomass. WO Patent 2010020903 A1, February 25.
Gandini, A., & Belgacem, M. N. (2002). Recent contributions to the preparation of polymers derived from renewable resources. Journal of Polymers and the Environment, 10, 105ā114.
Garrido, M., Correia, J. R., & Keller, T. (2016). Effect of service temperature on the shear creep response of rigid polyurethane foam used in composite sandwich floor panels. Construction Building and Materials, 118, 235ā244.
Guan, J., Song, Y., Lin, Y., Yin, X., Zuo, M., Zhao, Y., Tao, X., & Zheng, Q. (2011). Progress in study of non-isocyanate polyurethane. Industrial and Engineering Chemistry Research, 50, 6517ā6527.
Guo, A., Javni, I., & Petrovic, Z. (1999). Rigid polyurethane foams based on soybean oil. Journal of Applied Polymer Science, 77, 467ā473.
Honarkar, H. (2018). Waterborne polyurethanes: A review. Journal of Dispersion Science and Technology, 39(4), 507ā516.
Hsu, S. H., Dai, L. G., Hung, Y. M., & Dai, N. T. (2018). Evaluation and characterisation of waterborne biodegradable polyurethane films for the prevention of tendon postoperative adhesion. International Journal of Nanomedicine, 13, 5485ā5497. https://doi.org/10.2147/IJN.S169825
Koh, E., Kim, N. K., Shin, J., & Kim, Y. M. (2014). Polyurethane microcapsules for self-healing paint coatings. RSC Advances, 4, 16214ā16223.
Konieczny, J., & Loos, K. (2019). Green polyurethanes from renewable isocyanates and biobased white dextrins. Polymers (basel), 11(2), 256. https://doi.org/10.3390/polym11020256
Krupadam, R. J., Khan, M. S., & Das, S. (2010). Adsorption of fluoride from water by surface-functionalised polyurethane foam. Water Science and Technology, 62(4), 759ā765.
Lammers, G., Stamhuis, E. J., & Beenackers, A. A. C. M. (1993). Kinetics of the hydroxypropylation of potato starch in aqueous solution. Industrial and Engineering Chemistry Research, 32, 835ā842.
Lee, S. T., & Ramesh, N. S. (2004). Polymeric foams: Mechanisms and materials. CRC Press.
Lin, Y. Y., Hung, K. C., & Hsu, S. H. (2015). Stability of biodegradable waterborne polyurethane films in buffered saline solutions.Ā Biointerphases, 10(3), 031006. https://doi.org/10.1116/1.4929357
Ljubic, D., Srinivasan, M., Szoszkiewicz, R., Javni, I., & Petrovic, Z. S. (2015). Surface modified graphene/single-pase polyurethane elastomers with improved thermo-mechanical and dielectric properties. European Polymer Journal, 70, 55ā65.
Machado, G. S. N., Centenaro, B. R., AlexsandraValĆ©rio, A. A., Souza, U., Silva, A., Oliveira, J. V., & DĆ©borade, . (2017). Oliveira application of polyurethane foam chitosan-coated as a low-cost adsorbent in the effluent treatment. Journal of Water Process Engineering, 20, 201ā206.
Mao, N., Zhou, L., Ye, Z., Zheng, W., Peng, L., & Li, Y. (2013). Preparation of waterborne polyurethane foam with active carbon and its adsorption for phenol in aqueous solution. Journal of Environmental Engineering, 139(8), 1070ā1079.
Massalha, N., Brenner, A., Sheindorf, C., Haimov, Y., & Sabban, I. (2015). Enriching composite hydrophilic polyurethane foams with PAC to enhance adsorption of phenol from aqueous solutions. Chemical Engineering Journal, 280, 283ā292.
Miao, S., Wang, P., Su, Z., & Zhang, S. (2014). Vegetable-oil-based polymers as future polymeric biomaterials. Acta Biomaterialia, 10(4), 1692ā1704.
Mishra, M. (2019). Encyclopedia of polymer applications, (Vol. 3). CRC Press.
Morral-RuĆz, G., Melgar-Lesmes, P., GarcĆa, M. L., Solans, C., & Garcia-Celma, M. L. (2014). Polyurethane and polyurea nanoparticles based on polyoxyethylene castor oil derivative surfactant suitable for endovascular applications. International Journal of Pharmaceutics, 461, 1ā13. https://doi.org/10.1016/j.ijpharm.2013.11.026
Mukherjee, M., Gurusamy-Thangavelu, S. A., Chelike, D. K., Alagumalai, A., Das, B. N., & Mandal, A. B. (2019). Biodegradable polyurethane foam as shoe insole to reduce footwear waste: Optimisation by morphological physicochemical and mechanical properties. Applied Surface Science, 499, 143966. https://doi.org/10.1016/j.apsusc.2019.143966
Niu, M., Zhao, G., & Alma, M. H. (2011). Polycondensation reaction and its mechanism during lignocellulosic liquefaction by an acid catalyst: A review. Forestry Studies in China, 13, 71ā79.
Omrani, I., Babanejad, N., Shendi, H. K., & Nabid, M. R. (2017). Fully glutathione degradable waterborne polyurethane nanocarriers: Preparation, redox-sensitivity, and triggered intracellular drug release. Materials Science and Engineering, C: Materials for Biological Applications, 70(1), 607ā616. https://doi.org/10.1016/j.msec.2016.09.036
Panda, S. S., Panda, B. P., Nayak, S. K., & Mohanty, S. (2018). A review on waterborne thermosetting polyurethane coatings based on castor oil: Synthesis, characterisation, and application 500ā522.
Petrovi'c, Z. S., & Cvetkovi'c, I. (2012). Vegetable oil-based hyperbranchedpolyols in flexible foams. Contemporary Materials, 1, 63ā71.
Philipp, C., & Eschig, S. (2012). Waterborne polyurethane wood coatings based on rapeseed fatty acid methyl esters. Progress in Organic Coatings, 74, 705ā711. https://doi.org/10.1016/j.porgcoat.2011.09.028
Plasticsinsight.com. (2018). Polyurethane production, pricing and market demand. Available online: https://www.plasticsinsight.com/resin-intelligence/resin-prices/polyurethane/. Accessed on September 13, 2018.
Qu, R. J., Gao, J. J., Tang, B., Ma, Q. L., Qu, B. H., & Sun, C. M. (2014). Preparation and property of polyurethane/nanosilver complex fibers. Applied Surface Science, 294, 81ā88.
Rapra, S. (2018). High-performance polymer foams to 2021āMarket reports. SmitherRapra.
Rapra, S. (2019). Polymer foams market forecast to 2019. SmithersRapra.
RomaÅ”keviÄ, T., BudrienÄ, S., Pielichowski, K., & Pielichowski, J. (2006). Application of polyurethane-based materials for immobilisation of enzymes and cells: a review. CHEMIJA, 17, 74ā89.
Serrano, A. M., Borreguero, I., Garrido, J. F., & RodrĆguez and M. Carmona, . (2016). Reducing heat loss through the building envelope by using polyurethane foams containing thermoregulating microcapsules. Applied Thermal Engineering, 103, 226ā232.
Sheikhy, H., Shahidzadeh, M., Ramezanzadeh, B., & Noroozi, F. (2013). Studying the effects of chain extenders chemical structures on the adhesion and mechanical properties of a polyurethane adhesive. Journal of Industrial and Engineering Chemistry, 19, 1949ā1955.
Singhal, P., Small, W., Cosgriff-Hernandez, E., Maitland, D. J., & Wilson, T. S. (2014). Low density biodegradable shape memory polyurethane foams for embolic biomedical applications. Acta Biomaterialia, 10(1), 67ā76. https://doi.org/10.1016/j.actbio.2013.09.027
Somani, K. K., Patel, S., Rakshit, N., & Animesh, . (2003). Castor oil based polyurethane adhesives for wood-to-wood bonding. International Journal of Adhesion and Adhesives, 23, 269ā275. https://doi.org/10.1016/S0143-7496(03)00044-7
Szycher, M. (1999). Handbook of polymers (1st edn, pp. 13ā34). CRC Press.
Tamami, B., Sohn, S., & Wilkes, G. L. (2004). Incorporation of carbon dioxide into soybean oil and subsequent preparation and studies of nonisocyanate polyurethane networks. Journal of Applied Polymer Science, 92, 883ā891.
Tanzi, M. C., FarĆØ, S., Petrini, P., Tanini, A., Piscitelli, E., Zecchi Orlandini, S., & Brandi, M. L. (2003). Cytocompatibility of polyurethane foams as biointegrable matrices for the preparation of scaffolds for bone reconstruction. Journal of Applied Biomaterials and Biomechanics, 1(1), 58ā66.
Titow, W. V. (2001). PVC Technology (pp. 146). Rapra Technology Ltd. ISBN 1859572405.
Trang, D. T., & Zenitova, L. A. (2019). Study on the sorption capacity of the adsorbent based on polyurethane and chitin to remove oil spills Y. Earth and Environmental Science, 337, 012008.
Tu, Y.-C., Kiatsimkul, P., Suppes, G., & Hsieh, F.-H. (2007). Physical properties of water-blown rigid polyurethane foams from vegetable oil-based polyols. Journal of Applied Polymer Science, 105, 453ā459.
VĆ”squez, L., Campagnolo, L., Athanassiou, A., & Fragouli, D. (2019). ACS Applied Materials and Interfaces, 11(33), 30207ā30217. https://doi.org/10.1021/acsami.9b07907
Vincent, B. J., & Natarajan, B. (2014). Waterborne polyurethane from polycaprolactone and tetramethylxylene diisocyanate: Synthesis by varying NCO/OH ratio and its characterisation as wood coatings. Open Journal of Organic Polymer Materials, 4, 37ā42.
Wan, T., & Chen, D. (2017). Synthesis and properties of self-healing waterborne polyurethanes containing disulfide bonds in the main chain. Journal of Material Science, 52, 197ā207.
Wang, T., Sun, W., Zhang, X., Xu, H., & Xu, F. (2017). Waterborne polyurethane coatings with covalently linked black dye Sudan Black B. Materials (basel), 10(11), 1247. https://doi.org/10.3390/ma10111247
Wu, G. M., Chen, J., Huo, S. P., Liu, G. F., & Kong, Z. W. (2014). Thermoset nanocomposites from two-component waterborne polyurethanes and cellulose whiskers. Carbohydrate Polymers, 105, 207ā213. https://doi.org/10.1016/j.carbpol.2014.01.095
**nrong, S., Nanfang, W., Kunyang, S., Sha, D., & Zhen, C. (2014). Synthesis and characterisation of waterborne polyurethane containing UV absorption group for finishing of cotton fabrics. Journal of Industrial and Engineering Chemistry, 20, 3228ā3233.
Yang, D., Han, L., & Zhang, H. (2011). Monocomponent waterborne polyurethane adhesives: Influence of crosslinking agent on their properties. Journal of Macromolecular Science, Part A Pure and Applied Chemistry, 48, 277ā283.
Yari, A., Yeganeh, H., & Bakhshi, H. (2012). Synthesis and evaluation of novel absorptive and antibacterial polyurethane membranes as wound dressing. Journal of Materials Science. Materials in Medicine, 23, 2187ā2202. https://doi.org/10.1007/s10856-012-4683-6
Zhang, C., & Kessler, M. R. (2015). Bio-based polyurethane foam made from compatible blends of vegetable-oil-based polyol and petroleum-based polyol. ACS Sustainable Chemical Engineering, 3(4), 743ā749. https://doi.org/10.1021/acssuschemeng.5b00049
Zhang, S., Li, Y., Peng, L., Li, Q., Chen, S., & Hou, K. (2013). Synthesis and characterisation of novel waterborne polyurethane nanocomposites with magnetic and electrical properties. Composites. Part A, Applied Science and Manufacturing, 55, 94ā101.
Zhao, B., Qian, Y., Qian, X., Fan, J., & Feng, Y. (2019). Fabrication and characterization of waterborne polyurethane/silver nanocomposite foams 40(4), 1492ā1498.
Zhou, X., Fang, C., Li, S., Cheng, Y., & Lei, W. (2015). Recent advances in synthesis of waterborne polyurethane and their application in water-based ink: A review. Journal of Materials Science & Technology, 31(7), 708ā722.
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Narayana Saibaba, K.V. (2021). Applications of Waterborne Polyurethanes Foams. In: Inamuddin, Boddula, R., Khan, A. (eds) Sustainable Production and Applications of Waterborne Polyurethanes. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-030-72869-4_9
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