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Potential Effects of Short-Range Order on Hydrogen Embrittlement of Stable Austenitic Steels—A Review

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Advances in Hydrogen Embrittlement Study

Part of the book series: Advanced Structured Materials ((STRUCTMAT,volume 143))

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Abstract

Here, we present a review of the hydrogen embrittlement behavior of face-centered cubic (FCC) alloys with short-range order (SRO) of solute atoms. In this paper, three types of FCC alloys are introduced: Fe–Mn–C austenitic steels, high-nitrogen steels, and CoCrFeMnNi high-entropy alloys. The Fe–Mn–C austenitic steels show dynamic strain aging associated with Mn–C SRO, which causes deformation localization and acceleration of premature fracture even without hydrogen effects. The disadvantageous effect of dynamic strain aging on ductility, which is associated with the deformation localization, amplify plasticity-assisted hydrogen embrittlement. Cr–N and Co–Cr–Ni SRO effects in high-nitrogen austenitic steels and high-entropy alloys enhance the dislocation planarity, which causes stress concentration in the grain interior and near the grain boundaries. The stress concentration coupled with hydrogen effects causes quasi-cleavage and intergranular fractures.

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Notes

  1. 1.

    Currently, the effect of Mn–C interaction is still under debate. A recent work pointed out a type of dynamic strain aging is triggered by a pipe diffusion of carbon without Mn–C SRO [27].

  2. 2.

    When the hydrogen gas pressure was 15 MPa, the HEA showed no degradation of elongation and strength [67] .

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Acknowledgements

This work was financially supported by JSPS KAKENHI (JP16H06365 and JP20H02457) and the Japan Science and Technology Agency (JST) (Grant no. 20100113) under the Industry-Academia Collaborative R&D Program.

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Authors and Affiliations

  1. Institute for Materials Research, Tohoku University, Katahira 2–1–1, Aoba–ku, 980-8577, Sendai, Miyagi, Japan

    Motomichi Koyama & Eiji Akiyama

  2. Elements Strategy Initiative for Structural Materials (ESISM), Kyoto University, Yoshida-honmachi, Sakyo–ku, 606–8501, Kyoto, Japan

    Motomichi Koyama & Kaneaki Tsuzaki

  3. Department of Mechanical Engineering, Abdullah Gül University, 38080, Kayseri, Turkey

    Burak Bal

  4. Department of Mechanical Engineering, Koc University, 34450, Sariyer, Istanbul, Turkey

    Dermican Canadinc

  5. Research Center for Structural Materials, National Institute for Materials Science, 1–2–1 Sengen, 305–0047, Tsukuba, Japan

    Kishan Habib & Kaneaki Tsuzaki

  6. Faculty of Engineering, Kyushu University, Motooka 744, Nishi-ku, 819-0395, Fukuoka, Japan

    Toshihiro Tsuchiyama & Kaneaki Tsuzaki

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Correspondence to Motomichi Koyama .

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Editors and Affiliations

  1. Institute for Problems in Mechanical Engineering, Russian Academy of Sciences, St. Petersburg, Russia

    Vladimir A. Polyanskiy

  2. Institute for Problems in Mechanical Engineering, Russian Academy of Sciences, St. Petersburg, Russia

    Alexander K. Belyaev

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Koyama, M. et al. (2021). Potential Effects of Short-Range Order on Hydrogen Embrittlement of Stable Austenitic Steels—A Review. In: Polyanskiy, V.A., Belyaev, A.K. (eds) Advances in Hydrogen Embrittlement Study. Advanced Structured Materials, vol 143. Springer, Cham. https://doi.org/10.1007/978-3-030-66948-5_1

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