Abstract
Rapeseed oil is currently the third source of vegetable oils. Crude oils generally contain undesirable substances which need to be removed to produce a stable and edible product. So, rapeseed oil is subjected to industrial treatments such as extraction, degumming, bleaching, deodorization, and subsequently produces large quantities of byproducts like hull and fibers, rapeseed meal, rapeseed cake, deodorizer distillate, acid oil, soapstock, etc. If these byproducts are not used for any beneficial activity, they can harm the environment. At the same time, they can be a promising source of high-value products and uses. For example, rapeseed cake and rapeseed meal is a protein-rich ingredient widely used to feed all classes of livestock. Moreover, they can be used as fuel, biogas substrate or fertilizer, or a source of natural antioxidants. Soapstock usually uses in animal feed, biodiesel synthesis, and producing soaps and detergents. Deodorizer distillate is potentially utilized to produce biodiesel as raw material and is a source of highly valuable phytochemicals. As a result, the wastes of rapeseed oil that may be considered commercially insignificant are useful for extracting or isolating valuable industrial compounds with broad applications. This chapter reviewed the various byproducts resulting from the industrial extraction process of rapeseed oil and up-to-date data. In addition, the phytochemicals of rapeseed oil’s byproducts and the technologies applied for the revalorization of rapeseed oil byproducts have been discussed. Finally, the applications of rapeseed oil byproducts have been presented.
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References
Carré P, Pouzet A (2014) Rapeseed market, worldwide and in Europe’. OCL- Oilseeds fats 21(1):1–12. https://doi.org/10.1051/ocl/2013054
Jafarian Asl P, Niazmand R, Yahyavi F (2020) Extraction of phytosterols and tocopherols from rapeseed oil waste by supercritical CO2 plus co-solvent: a comparison with conventional solvent extraction. J Hel 6(3). https://doi.org/10.1016/j.heliyon.2020.e03592
FAO (2020) FAOSTAT. Food and Agriculture Organization of the United Nations. FAO, Rome
USDA-ARS (Agricultural Research Service) (2011) USDA nutrient database for standard reference, Release 23, Nutrient Data Laboratory Homepage, USDA, Washington D.C., website http://www.ars.usda.gov/Services/docs.htm?docid=8964 (Accessed Oct 2011).
Krautgartner R, Lefebvre L, Rehder L E, Boshnakova M, Dobrescu M, Flach B (2017) ‘EU-28 oilseeds and products annual’, GAIN Report, p. 51. Available at: https://gain.fas.usda.gov/Recent GAIN Publications/Oilseeds and Products Annual_Vienna_EU-28_3-31-2017.pdf.
Jafarian Asl P, Niazmand R (2020) Modelling and simulation of supercritical CO2 extraction of bioactive compounds from vegetable oil waste. Food Bio Proc 122:311–321. https://doi.org/10.1016/j.fbp.2020.05.005
Rekas A, Siger A, Wroniak M, Scibisz I, Derewiaka D, Anders A (2017) Dehulling and microwave pretreatment effects on the physicochemical composition and antioxidant capacity of virgin rapeseed oil. J Food Sci Technol 54(3):627–638
Fazli Y, Tajdari M, Kermani P (2013) Soap stock separation process. As J Chem 25(4):2333–2334. https://doi.org/10.14233/ajchem.2013.13295
FAO and WHO (Food and Agriculture Organisation and World Health Organization of the United Nations) (2021) Human vitamin and mineral requirements-chapter 10 Vitamin K, Report of a Joint FAO/WHO Expert Consultation. FAO/WHO, Bangkok/Rome
Çulcuoǧlu E, Ünay E, Karaosmanoǧlu F (2002) Rapeseed cake as a biomass source. J Energy Sour 24(4):329–336. https://doi.org/10.1080/00908310252888709
Eriksson G (2009) Combustion characterization of rapeseed meal and possible combustion applications. Energy Fuels 23(8):3930–3939. https://doi.org/10.1021/ef900308r
Fridrihsone A, Romagnoli F, Cabulis U (2020) Environmental life cycle assessment of rapeseed and rapeseed oil produced in Northern Europe: a Latvian case study. Sustainability (Switzerland) 12(14). https://doi.org/10.3390/su12145699
Newkirk R (2009) Canola meal feed industry guide director of biofuels and feed canadian international grains institute’. Available at: https://cigi.ca/wp-content/uploads/2011/12/2009-Canola_Guide.pdf.
Johansson B (2015) Cold-pressed rapeseed cake or full fat rapeseed to organic dairy cows-milk production and profitability. J Org Agric 5(1):29–38. https://doi.org/10.1007/s13165-014-0094-y
Bach Knudsen K E (2018) Alternative feed ingredients and technologies for improved nutritive value of feed. EuroTier 2018, 13–16 November 2018, Hanover, Germany
Directorate E (2011) ‘Joint meeting of the chemicals committee and the working party on chemicals, pesticides and biotechnology revised consensus document on compositional considerations for new varieties of low erucic acid rapeseed (canola): key food and feed nutrients, anti-’, (24)
Leming R, Lember A (2005) Chemical composition of expeller-extracted and cold-pressed rapeseed cake. J Chem 16(5):103–109
Daun JK, Adolphe D (2010, July) A revision to the canola definition. Can Res Bulletin:134–141
CCC (2009) Canola meal: feed industry guide, 4th edition, available online at http://www.canolacouncil.org/uploads/feedguide/Canola_Guide_ENGLISH_2009_small.pdf (Accessed 16 Apr 2010).
Maison T (2015) Evaluation of the nutritional value of canola meal, 00-rapeseed meal, and 00-rapeseed expellers fed to pigs. (Doctoral dissertation) Department of Animal Science, University of Illinois at Urbana-Champaign. 2013. https://www.ideals.illinois.edu/bitstream/handle/2142/46593/nawong_Maison.pdf?sequence=1. Accessed 10 July 2015
Wickramasuriya SS, Yi YJ, Yoo J, Kang NK, Heo JM (2015) A review of canola meal as an alternative feed ingredient for ducks. J Anim Sci Technol 57(7). https://doi.org/10.1186/s40781-015-0062-4
Ivanova P, Chalova V, Uzunova G, Koleva L, Manolov I (2016) Biochemical characterization of industrially produced rapeseed meal as a protein source in food industry. J Agric Sci Pro 10(6):55–62. https://doi.org/10.1016/j.aaspro.2016.09.009
Kalaydzhiev H, Vanova PS, Magdalena P, Atanas R, Turid S, Cristina LM, Chalova VI (2020) Valorization of rapeseed meal: influence of ethanol antinutrients removal on protein extractability, amino acid composition and fractional profile. J West Bio Val 11(6):2709–2719. https://doi.org/10.1007/s12649-018-00553-1
Bell JM, Keith MO (1991) A survey of variation in the chemical composition of commercial canola meal produced in Western Canadian crushing plants. Cana J Anim Sci 71(3):469–480
Bell JM (1999) Factors affecting the nutritional value of canola meal: a review. Can J Anim Sci 73(5):679–697
Pawar DM, Marathe AB (2015) Critical review on value added products from cracking of waste vegetable oil. J Sci Eng Res 6(1):1063–1068
Thiyam U, Kuhlmann A, Stöckmann H, Schwarz K (2004) Prospects of rapeseed oil by-products with respect to antioxidative potential. Com Ren Chim 7(6-7):611–616. https://doi.org/10.1016/j.crci.2004.02.011
Jafarian P, Asefi N, Teimori R (2014) Phenolic compounds content in leaf of different varieties of olive and its effect on stability of rapeseed oil. J Food Res 24(3):307–314
Young Moo P, Sang Ho C, He JE, ** Suk L, Kwan Young L (2010) Tungsten oxide zirconia as solid superacid catalyst for esterification of waste acid oil (dark oil). Bio Technol 101:6589–6593
Haslenda H, Jamaludin MZ (2011) Industry to industry by-products exchange network towards zero waste in palm oil refining processes. Res Cons Recy 55:713–718
Dumont MJ, Narine SS (2007) Characterization of flax and soybean soapstocks, and soybean deodorizer distillate by GC-FID. J Am Oil Chem Soc 84(12):1101–1105. https://doi.org/10.1007/s11746-007-1154-1
Heuzé V, Tran G, Sauvant D, Lessire M, Lebas F (2020) Rapeseed meal. Feedipedia, a programme by INRAE, CIRAD, AFZ and FAO. https://www.feedipedia.org/node/52 Last updated on July 23, 2020, 16:36
Durant AA, Dumont MJ, Narine SS (2007) In situ silylation for the multicomponent analysis of canola oil by-products by gas chromatography-mass spectrometry. Anal Chem 559(2):227–233. https://doi.org/10.1016/j.aca.2005.11.075
Ribeiro dos Santos R, Nolasco Macedo Muruci L, Oliveira Santos L, Antoniassi R, Passos Lima da Silva J, Mônica CTD (2014) Characterization of different oil soapstocks and their application in the lipase production by Aspergillus niger under solid state fermentation. J Food Nutr Res 2(9):561–566. https://doi.org/10.12691/jfnr-2-9-6
Cherng Yuan L, Yi Wei L (2012) Fuel characteristics of biodiesel produced from a high-acid oil from soybean soapstock by supercritical-methanol transesterification. J Energy 5(1):2370–2380
Kulkarni BM, Pujar BG, Shanmukhappa S (2008) Investigation of acid oil as a source of biodiesel. Int J Chem Tech 15:467–471
Watanabe Y, Pinsirodom P, Nagao T, Yamauchi A, Kobayashi T, Nishida Y, Takagi Y, Shimada Y (2007) Conversion of acid oil by-produced in vegetable oil refining to biodiesel fuel by im- mobilized Candida antarctica lipase. J Mol Catal B: Enzym 44:99–105
Haas MJ, Michalski PJ, Runyon S, Nunez A, Scott KM (2003) Production of FAME from acid oil, a by-product of vegetable oil refining. J Am Oil Chem Soc 80:97–102
Asl PJ, Niazmand R, Sherazi STH (2021) Rapid determination of bioactive lipid-type materials of rapeseed oil deodorizer distillate by GC-MS. J Res In Food Sci Technol 9(4):351–362. https://doi.org/10.22101/JRIFST.2020.212592.1136
Verleyen T, Verhe R, Garcia L, Dewettinck K, Huyghebaert A, De Greyt W (2001) Gas chromatographic characterization of vegetable oil deodorization distillate. J Chromatogr A 921:277–285
Naz S et al (2014) ‘Chemical characterization of canola and sunflower oil deodorizer distillates. Polish J Food Nutr Sci 64(2):115–120. https://doi.org/10.2478/pjfns-2013-0008
Sherazi STH, Mahesar SA, Sirajuddin (2016) Vegetable oil deodorizer distillate: a rich source of the natural bioactive components. J Oleo Sci 65(12):957–966. https://doi.org/10.5650/jos.ess16125
Shoaib H, Ahmed Mahesar S, Jafarian P, Niazmand R, Tufail HSS (2019) Quality evaluation of Canola oils and deodorizer distillate during industrial processing. J Chem Soc Pak 41(6):983–1001
Jafarian Asl P, Niazmand R, Jahani M (2020) Solid-phase extraction of phytosterols from rapeseed oil deodorizer distillates with magnetic graphene oxide nanocomposite. J Exp Nano 15(1):307–321. https://doi.org/10.1080/17458080.2020.1786064
Nergiz C, Çelikkale D (2011) The effect of consecutive steps of refining on squalene content of vegetable oils. J Food Sci Technol 48(3):382–385. https://doi.org/10.1007/s13197-010-0190-2
Jafarian Asl P, Niazmand R, Jahani M (2020) Theoretical and experimental assessment of supercritical CO2 in the extraction of phytosterols from rapeseed oil deodorizer distillates. J Food Eng 269. https://doi.org/10.1016/j.jfoodeng.2019.109748
Naz S (2012) Determination of unsaponifiable constituents of deodorizer distillates by GC-MS. J Am Oil Chem Soc 89(6):973–977. https://doi.org/10.1007/s11746-011-2000-z
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Jafarian Asl, P., Niazmand, R. (2022). Bioactive Phytochemicals from Rapeseed (Brassica napus) Oil Processing By-products. In: Ramadan Hassanien, M.F. (eds) Bioactive Phytochemicals from Vegetable Oil and Oilseed Processing By-products. Reference Series in Phytochemistry. Springer, Cham. https://doi.org/10.1007/978-3-030-63961-7_3-1
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