Abstract
Electrochemical studies on the technetium as a radioactive waste component focus on several aspects related to the waste immobilization and recycling.
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References
Abdulaziz R, Brown LD, Inman D et al (2016) Predominance diagrams of spent nuclear fuel materials in LiClâKCl and NaClâKCl molten salt eutectics. Int J Electrochem Sci 11:10417â10435
Abdulaziz R (2016) Electrochemical reduction of metal oxides in molten salts for nuclear reprocessing. PhD thesis, University College London, p 143
Adachi T, Ohnuki M, Yoshida N et al (1990) Dissolution study of spent PWR fuel: Dissolution behavior and chemical properties of insoluble residues. J Nucl Mater 174:60â71
Aihara H, Arai Y, Shibata et al (2016) Characterisation og the insoluble sludge from the dissolution of irradiated fast breeder reactor fuel. Proc Chem 21:279â284
Asakura T, Kim S-Y, Morita Y et al (2005) Study on electrolytic reduction of pertechnetate in nitric acid solution for electrolytic extraction of rare metals for future reprocessing. J Nucl Radiochem Sci 6(3):267â269
Bebko J (2011) Spectroelectrochemical investigations of pertechnetates reduction in the environment of sulfuric and nitric acid. Master thesis, University of Warsaw (in polish)
Box W (1968) Electrolyte for the electrodeposition of technetium. US Patent 3Â 374Â 157
Boyd GE (1959) Technetium and promethium. J Chem Edu 36(1):3â14
Boyd GE, Larson QV, Motta EE (1960) J Am Chem Soc 82:809â815
Bramman JI, Sharpe RM, Thom D, Yates G (1968) Metallic fission-product inclusions in irradiated oxide fuels. J Nucl Mater 25:201â215
Brewer L, Lamoreaux RH (1980) Thermochemical properties, in molybdenum: physico-chemical properties of its compounds and alloys. At Energy Rev, Spec Issue 7:1â191
Burton-Pye BP, Radivojevic I, McGregor D, Francesconi LC et al (2011), photoreduction of 99Tc pertechnetate by nanometer-sized metal oxides: new strategies for formation and sequestration of low-valent technetium. J Am Chem Soc 133:18802
Cartledge GH (1955) The pertechnetate ion as an inhibitor of corrosion. J Am Chem Soc 77:2658â2659
Cartledge GH (1971) The electrochemical behavior of technetium and iron containing technetium. J Electrochem Soc 118(11):1752â1757
Cartledge GH, Sympson RF (1957) The existence of a flade potential on iron inhibited by ions of the XO4â type. J Phys Chem 61(7):973â980
Chatterjee S, Hall GB, Johnsonet I et al (2018) Surprising formation of quasi-stable Tc(VI) in high ionic strength alkaline media. Inorg Chem Front 5:2081â2091
Chotkowski M, CzerwiĆski A (2012) Electrochemical and spectroelectrochemical studies of pertechnetate electroreduction in acidic media. Electrochim Acta 76:165â173
Chotkowski M, CzerwiĆski A (2016) Stability of technetium in the moderate oxidation states in acidic media. Annales UMCS Sectio AA LXXI(1): 141â149
Chotkowski M (2018) Redox interactions of technetium with neptunium in acid solutions. J Radioanal Nucl Chem 317:527â533
Compton RG, Sanders GHW (1996) Electrode potentials. Oxford Scientific Publications
Darby JB Jr, Norton LJ, Downey JW (1963) A survey of the binary systems of technetium with group VIII transition elements. J Less-Common Met 5:397â402
Denden I, Essehli R, Fattahi M (2013) Spectrophotometric study of the behaviour of pertechnetate in trifluoromethanesulfonic acid: effect of alpha irradiation on the stability of Tc(VII). J Radioanal Nucl Chem 296:149â155
de Zoubov, N, Pourbaix M (1966) Technetium Chapter IV, Section 11.2. In: Pourbaix M Atlas of electrochemical equilibria in aqueous solutions, Pergamon Press, p 298
Engelmann MD, Metz LA, Delmore JE (2008) Electrodeposition of technetium on platinum for thermal ionization mass spectrometry (TIMS). J Radioanal Nucl Chem 276(2):493â498
Ferrier M, Poineau F, Jarvinen GD et al (2013) Chemical and electrochemical behavior of metallic technetium in acidic media. J Radioanal Nucl Chem 298:1809â1817
Garcia-Garcia R, Ortega-Zarzosa G, RincĂłn ME et al (2014) The hydrogen evolution reaction on rhenium metallic electrodes: a selected review and new experimental evidence. Electrocatal 6(3):263â273
Garcia-Garcia R, Rivera JG, Antaño-Lopez R (2016) Impedance spectra of the cathodic hydrogen evolution reaction on polycrystalline rhenium. Int J Hydrogen Energy 41:4660â4669
Garraway J, Wilson PD (1984) The technetium-catalysed oxidation of hydrazine by nitric acid. J Less-Common Met 97:191â203
German KE, Obruchnikova YA, Tumanova DN et al (2011) Technetium catalytic effect and speciation in nitric acid solutions in presence of Np(V), Th(IV), Zr(IV) and reducing nitrogen derivatives. In: German KE, Myasoedov BF, Kodina GE, Maruk AY, Troshkina ID (eds) Book of proceedings, 7th ISTR July 4-8, 2011. Russia, Moscow, pp 114â120
Ghalei M, Vandenborre J, Poineau F (2018) Speciation of technetium in carbonate media under helium ions and Îł radiation. Radiochim Acta 1â9. https://doi.org/10.1515/ract-2018-2939
Hoshi H, Wei Y-Z, Kumagai M (2007) Study on valence of Pu, Np and Tc in nitric acid after electrolytic reduction. J Alloys Compd 444â445:663â667
Inazawa S, Nitta K, Okada K et al (2016) molten salt bath, deposit, and method of producing metal deposit. US Patent 9Â 512Â 530 B2
Jaksic MM (2000) Volcano plots along the periodic table, their causes and consequences on electrocatalysis for hydrogen electrode reactions. J New Mat Electrochem Sys 3:167â182
Kemp TJ, Thyera SAM, Wilsonb PD (1993) The Role of Intermediate Oxidation States of Technetium in Catalysis of the Oxidation of Hydrazine by oxo-anions. Part I Nitrate ions. J Chem Soc Dalton Trans 2601â2605
Kleykamp H (1985a) The chemical state of the fission products in oxide fuels. J Nucl Mater 131:221â246
Kleykamp H (1985b) Composition and structure of fission products precipitates in irradiated oxide fuels: Correlaction with phase studies in the MoâRuâRhâPd and BaOâUO2âZrO2âMoO2 systems. J Nucl Mater 130:426â433
Kolman DG, Moore DP, Jarvinen GD et al (2012) the aqueous corrosion behavior of technetiumâiron alloy materials. LA-UR-12â25629. https://doi.org/10.2172/1053896
Koltunov VS, Marchenko VI, Nikiforov AS (1986) The role taken by technetium in the oxidation-reduction processes used in irradiated-fuel technology. At Energy 43â51
Koyama S, Suzuki T, Mimura H et al (2011) Current status and future plans of Advanced ORIENT Cycle strategy. Prog Nucl Energy 53:980â987
Kuznetsov VV, Volkova MA, German KE et al (2020) Electroreduction of pertechnetate ions in concentrated acetate solutions. J Electroanal Chem 869:114090. https://doi.org/10.1016/j.jelechem.2020.114090. Accessed 20 June 2020
LĂĄng GG, HorĂĄnyi G (2003) Some interesting aspects of the catalytic and electrocatalytic reduction of perchlorate ions. J Electroanal Chem 552:197â211
Lemire RJ, Fuger J, Nitsche H et al (2001) Chemical thermodynamics of neptunium and plutonium, vol 4. Elsevier, Amsterdam, pp 91â104
Lukens WW, Bucher JJ, Edelstein NM et al (2001) Radiolysis of TcO4â in alkaline, nitrate solutions: reduction by NO32â. J Phys Chem A 105:9611â9615
Lukens WW, Bucher JJ, Edelstein NM et al (2002) Products of pertechnetate radiolysis in highly alkaline solution: structure of TcO2·xH2O. Environ Sci Technol 36:1124â1129
Lukens W, Shuh D, Schroeder N et al (2004) Identification of the non-pertechnetate species in hanford waste tanks, Tc(I)-carbonyl complexes. Los Alamos Technical Report 38:229â233
Magee RJ, Cardwell TJ (1974) Rhenium and Technetium in: Bard AJ (ed) Encyclopedia of electrochemistry of the elements. vol II, Marcel Dekker, pp 126â189
Marchenko VI, Zhuravleva GI, Dvoeglazov KN et al (2008) Behaviors of plutonium and neptunium in nitric acid solutions containing hydrazine and technetium ions. Theor Fund Chem Eng 42(5):733â739
Masahira Y, Ohishi Y, Kurosaki K et al (2015) Effect of Mo content on thermal and mechanical properties of MoâRuâRhâPd alloys. J Nucl Mater 456:369â372
Maslennikov A, Masson M, Peretroukhine V et al (1998) Technetium electrodeposition from aqueous formate solutions: electrolysis kinetics and material balance study. Radiochim Acta 83:31â37
Maslennikov A (2012) Electrochemistry of actinides and selected fission products in the head end of spent nuclear fuel reprocessing. Procedia Chem 7:39â44
Mausolf E, Poineau F, Hartmann T et al (2011) Characterization of electrodeposited technetium on gold foil. J Electrochem Soc 158(3):E32âE35
McGregor D, Burton-Pye BP, Howell RC et al (2011) Synthesis, structure elucidation, and redox properties of 99Tc complexes of lacunary wells-dawson polyoxometalates: insights into molecular 99Tc-metal oxide interactions. Inorg Chem 50:1670â1681
McGregor D, Burton-Pye BP, Mbomekalle IM et al (2012) 99Tc and Re incorporated into metal oxide polyoxometalates: oxidation state stability elucidated by electrochemistry and theory. Inorg Chem 51:9017â9028
OECD (2012) NEA/NSC/WPFC/DOC(2012)15 Spent nuclear fuel reprocessing flowsheet. Nuclear Energy Agency. p 10
Okada I (2002) Transport properties of molten salts. In: Bockris JOâM, Conway BE, White RE (eds) Modern aspects of electrochemistry, vol 34, Kluwer, pp 119â204
Ozawa M, Shinoda Y, Sano Y (2002) The separationof fission products rare elements toward bridging the nuclear and soft energy systems. Prog Nucl Energy 40(3â4):527â538
Ozawa M, Ishida M, Sano Y (2003) Strategic separation of technetium and rare metal fission-products in spent nuclear fuel e solvent extraction behavior and partitioning by catalytic electrolytic extraction. Radiochem (Radiokhim) 45(3):225â232
Ozawa M, Suzuki T, Koyama S et al (2005) Separation of rare metal fission products in radiactive wastes in new direction of their utilization. Prog Nucl Energy 47(1â4):462â471
Ozawa M, Suzuki T, Koyama S (2008) new back-end cycle strategy for enhancing separation, transmutation and utilization of materials (Adv.-ORIENT cycle). Prog Nucl Energy 50:476â482
Peretrukhin VF, Silin VI, Kareta AV et al (1998) Purification of alkaline solutions and wastes from actinides and technetium by coprecipitation with some carriers using the method of appearing reagents: Final Report Final report of Institute of Physical Chemistry of Russian Academy of Sciences Contract with DOE, PNNL 1998
Perterukhin VF, Moisy F, Maslennikov AG (2008) Physicochemical behavior of uranium and technetium in some new stages of the nuclear fuel cycle. Russ J Gen Chem 78(5):1031â1046
Pikaev AK, Gogolev AV, Kryutchkov SV et al (1996) Radiolysis of Actinides and Technetium in Alkaline Media. WHC-EP-0901, Westinghouse Hanford Corporation
Poineau F, Weck PF, Burton-Pye BP et al (2013) Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations. Dalton Trans 42:4348â4352
Poineau F, Gray K, Ebert W (2014) Electrochemical corrosion studies for modeling metallic waste form release rates. Project No. 12â4026. Final report. Nuclear Energy University Program USA
Poineau F, Koury DJ, Bertoia J et al (2016) Electrochemical studies of technetium-ruthenium alloys in HNO3: implications for the behavior of technetium waste forms1. Radiochemistry 59(1):41â47
Rard JA, Rand MH, Anderegg G et al (1999) Chemical thermodynamics of technetium, vol 3. Elsevier
Rotmanov KV, Maslennikov AG, Zakharova LV, Goncharenko YuD, Pertetrukhin VF (2015) Anodic dissolution oof Tc metal in HNO3 solutions. Radiochemistry 57(1):26â30
Rudenko A, Isakov A, Apisarov A et al (2019) Liquidus temperature and electrical conductivity of molten eutectic CsClâNaClâKCl containing ReCl4. J Chem Eng Data 64:567â573
Salakhova E (2014) The electrochemical deposition of rhenium chalcogenides from different electrolytes. J Chem Eng Chem Res 1(3):185â198
Sekine T, Narushima H, Suzuki et al (2004) Technetium(IV) oxide colloids produced by radiolytic reactions in aqueous pertechnetate solution. Colloids Surf. A Physicochem Eng Asp 249:105â109
Skriver HL, Rosengaard NM (1992) Surface energy and work function of elemental metals. Phys Rev 46(11):7157â7168
Sympson RF, Cartledge GH (1956) The mechanism of the inhibition of corrosion by the pertechnetate ion. IV. Comparison with other \( {\text{XO}}_{4}^{{{\text{n}} - }} \) inhibitors. J Phys Chem 60(8):1037â1043
SzabĂł S, Bakos I (2000) Electroreduction of rhenium from sulfuric acid solutions of perrhenic acid. J Electroanal Chem 492(2):103â111
Taylor CD (2011) Surface segregation and adsorption effects of ironâtechnetium alloys from first-principles. J Nucl Mater 408:183â187
Trasatti S (1972a) Discussion of the electrochemical behavior of technetium and iron containing technetium. Cartledge GH (pp 1752â1758, vol 118, no 11)] Discussion Section. J Electrochem Soc 119(12):1696â1697
Trasatti S (1972b) Work function, electronegativity, and electrochemical behavior of metals. III Electrolytic hydrogen evolution in acid soultions. J Electroanal Chem Interfacial Electrochem 39:163â184
Trasatti S, Petri OA (1991) Real surface area measurements in electrochemistry. Pure Appl Chem 63(5):711â734
Volkovich VA, Vasin BD, Griffiths TR (2010) Electrochemical and spectroscopic properties of technetium in fused alkali metal chlorides. ECS Trans 33(7):381â390
Voltz RE, Holt ML (1967) Electrodeposition of Tc99 from aqueous solution. J Electrochem Soc 114(2):128â131
Westphal BR, Frank BR, McCartin WM et al (2015) Characterization of irradiated metal waste from the pyrometallurgical treatment of used EBR-II fuel. Metall Mater Trans A 46A:83â92
Wotteen CB (1977) Method for prevention of fouling by marine growth and corrosion utilizing technetium-99. US Patent 4Â 017Â 370
Yamanaka S, Kurosaki K (2003) Thermophysical properties of MoâRuâRhâPd alloys. J Alloys Compd 353:269273
Zakharov EN, Bagaev SP, Kudryavtsev VN et al (1991) On the possibility of a hydride phase formation under Tc-99 electrodeposition. Zashch Met 27(6):1024â1026
Zhou X, Ye G, Zhang H et al (2014) Chemical behavior of neptunium in the presence of technetium in nitric acid media. Radiochim Acta 102(1â2):111â116
Zhuz Q, Wang S-Q (2016) Trends and regularities for halogen adsorption on various metal surfaces. J Electrochem Soc 163(9):H796âH808
Zilberman BY, Pokhitonova YA, Kirshin MY et al (2007) Prospects for development of a process for recovering technetium from spent fuel of nuclear power plants. Radiochem 49(2):156â161
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Chotkowski, M., CzerwiĆski, A. (2021). Metallic Technetium, Corrosion, Technetium Alloys and Its Behavior in Spent Nuclear Fuel. In: Electrochemistry of Technetium. Monographs in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-030-62863-5_5
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