Abstract
By 2050, electricity is expected to shift from 18 to 50% of the world’s energy resources, renewable energy sources will enlarge approximately four times the current deployed capacity, and meanwhile, the expectation is that the release of carbon dioxide will be reduced by 50% of the current value. In this panorama, it is relevant to propose a new set-up and systems for energy storage that are not yet available and that can handle the expected requests. The lithium-O2 and zinc-air batteries, based on their performances and availability of raw material, comprise an alternative and revolutionary technology for application in electric vehicles in an accessible way.
In this context, the development of high-technological materials such as electrocatalysts is a promising alternative to provide efficient charge transport during the process of reducing oxygen and housing of the discharge. To understand the technology of rechargeable systems, it is necessary to know what materials and chemical reactions in a battery occur. Specifically, the air electrode architecture composed of different materials, such as alloys, metal oxides, carbon nanotubes, and gas diffusion layers, has been widely used in both catalytic systems to allow the efficient transfer of charge and the synergistic effect in the triple electrical layer, speeding up the relevant reactions in the process. In this sense, the objective of the chapter is to report the current trends related to electrocatalysts that reduce the overpotential generated during charge and discharge in the lithium-O2 and zinc-air batteries.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Abraham KM, Jiang Z (1996) A polymer electrolyte-based rechargeable lithium/oxygen battery. J Electrochem Soc 143:1–5. https://doi.org/10.1149/1.1836378
Akhtar N, Akhtar W (2015) Prospects, challenges, and latest developments in lithium-air batteries. Int J Energy Res 39:303–316. https://doi.org/10.1002/er.3230
Bai P, Li J, Brushett FR, Bazant MZ (2016) Transition of lithium growth mechanisms in liquid electrolytes. Energ Environ Sci 9:3221–3229. https://doi.org/10.1039/C6EE01674J
Balaish M, Kraytsberg A, Ein-Eli Y (2014) A critical review on lithium-air battery electrolytes. Phys Chem Chem Phys 16:2801–2822. https://doi.org/10.1039/C3CP54165G
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2011) Li-O2 and Li-S batteries with high energy storage. Nat Mater 11:19–29. https://doi.org/10.1038/nmat3191
Cao Y et al (2019) Synthesis of Ag/Co@CoO NPs anchored within N-doped hierarchical porous hollow carbon nanofibers as a superior free-standing cathode for LiO2 batteries. Carbon 144:280–288. https://doi.org/10.1016/j.carbon.2018.12.048
Chen X, Zhou Z, Karahan HE, Shao Q, Wei L, Chen Y (2018) Recent advances in materials and design of electrochemically rechargeable zinc-air batteries. Small 14:1801929. https://doi.org/10.1002/smll.201801929
Chen J et al (2019) Chitin-derived porous carbon loaded with Co, N and S with enhanced performance towards electrocatalytic oxygen reduction, oxygen evolution, and hydrogen evolution reactions. Electrochim Acta 304:350–359. https://doi.org/10.1016/j.electacta.2019.03.028
Cho Y-B, Moon S, Lee C, Lee Y (2017) One-pot electrodeposition of cobalt flower-decorated silver nanotrees for oxygen reduction reaction. Appl Surf Sci 394:267–274. https://doi.org/10.1016/j.apsusc.2016.10.068
Choi R et al (2014) Ultra-low overpotential and high rate capability in Li-O2 batteries through surface atom arrangement of PdCu nanocatalysts. Energ Environ Sci 7:1362–1368. https://doi.org/10.1039/C3EE43437K
Christensen J et al (2011) A critical review of Li/air batteries. J Electrochem Soc 159:R1–R30. https://doi.org/10.1149/2.086202jes
Danner T, Eswara S, Schulz VP, Latz A (2016) Characterization of gas diffusion electrodes for metal-air batteries. J Power Sources 324:646–656. https://doi.org/10.1016/j.jpowsour.2016.05.108
Ding N, Chien SW, Hor TSA, Lum R, Zong Y, Liu Z (2014) Influence of carbon pore size on the discharge capacity of Li-O2 batteries. J Mater Chem A 2:12433–12441. https://doi.org/10.1039/C4TA01745E
Fu J, Cano ZP, Park MG, Yu A, Fowler M, Chen Z (2017) Electrically rechargeable zinc-air batteries: progress, challenges, and perspectives. Adv Mater 29:1604685. https://doi.org/10.1002/adma.201604685
Gao R, Zhou Y, Liu X, Wang J (2017) N-doped defective carbon layer encapsulated W2C as a multifunctional cathode catalyst for high performance Li-O2 battery. Electrochim Acta 245:430–437. https://doi.org/10.1016/j.electacta.2017.05.177
Girishkumar G, McCloskey B, Luntz AC, Swanson S, Wilcke W (2010) Lithium-air battery: promise and challenges. J Phys Chem Lett 1:2193–2203. https://doi.org/10.1021/jz1005384
Imanishi N, Yamamoto O (2014) Rechargeable lithium–air batteries: characteristics and prospects. Mater Today 17:24–30. https://doi.org/10.1016/j.mattod.2013.12.004
Jia G, Zhang W, Fan G, Li Z (2017) Three-dimensional hierarchical architectures derived from surface-mounted metal-organic framework membranes for enhanced electrocatalysis. Angew Chem Int Ed Engl 56:13781–13785. https://doi.org/10.1002/anie.201708385
Jiao Y, Zheng Y, Jaroniec M, Qiao SZ (2015) Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. Chem Soc Rev 44:2060–2086. https://doi.org/10.1039/C4CS00470A
Joo Y, Ahmed MS, Han HS, Jeon S (2017) Preparation of electrochemically reduced graphene oxide-based silver-cobalt alloy nanocatalysts for efficient oxygen reduction reaction. Int J Hydrogen Energ 42:21751–21761. https://doi.org/10.1016/j.ijhydene.2017.07.123
Kuang M, Zheng G (2016) Nanostructured bifunctional redox electrocatalysts. Small 12:5656–5675. https://doi.org/10.1002/smll.201600977
Lai Y, Chen W, Zhang Z, Qu Y, Gan Y, Li J (2016) Fe/Fe3C decorated 3-D porous nitrogen-doped graphene as a cathode material for rechargeable Li-O2 batteries. Electrochim Acta 191:733–742. https://doi.org/10.1016/j.electacta.2016.01.134
Lee J-S, Tai Kim S, Cao R, Choi N-S, Liu M, Lee KT, Cho J (2011) Metal-air batteries with high energy density: Li-air versus Zn-air. Adv Energy Mater 1:34–50. https://doi.org/10.1002/aenm.201000010
Lee J, Hwang B, Park M-S, Kim K (2016) Improved reversibility of Zn anodes for rechargeable Zn-air batteries by using alkoxide and acetate ions. Electrochim Acta 199:164–171. https://doi.org/10.1016/j.electacta.2016.03.148
Lee J-SM, Sarawutanukul S, Sawangphruk M, Horike S (2019) Porous Fe-N-C catalysts for rechargeable zinc-air batteries from an iron-imidazolate coordination polymer. ACS Sustain Chem Eng 7:4030–4036. https://doi.org/10.1021/acssuschemeng.8b05403
Li Y, Dai H (2014) Recent advances in zinc–air batteries. Chem Soc Rev 43:5257–5275. https://doi.org/10.1039/C4CS00015C
Li C, Yu Z, Liu H, Chen K (2018) High surface area LaMnO3 nanoparticles enhancing electrochemical catalytic activity for rechargeable lithium-air batteries. J Phys Chem Solids 113:151–156. https://doi.org/10.1016/j.jpcs.2017.10.039
Li C, Wu M, Liu R (2019a) High-performance bifunctional oxygen electrocatalysts for zinc-air batteries over mesoporous Fe/Co-N-C nanofibers with embedding FeCo alloy nanoparticles. Appl Catal B Environ 244:150–158. https://doi.org/10.1016/j.apcatb.2018.11.039
Li C, Zhang Z, Wu M, Liu R (2019b) FeCoNi ternary alloy embedded mesoporous carbon nanofiber: an efficient oxygen evolution catalyst for rechargeable zinc-air battery. Mater Lett 238:138–142. https://doi.org/10.1016/j.matlet.2018.11.160
Li Z et al (2019c) Structural modulation of Co catalyzed carbon nanotubes with Cu-Co bimetal active center to inspire oxygen reduction reaction. ACS Appl Mater Interfaces 11:3937–3945. https://doi.org/10.1021/acsami.8b18496
Lim SH, Kim DH, Byun JY, Kim BK, Yoon WY (2013) Electrochemical and catalytic properties of V2O5/Al2O3 in rechargeable Li-O2 batteries. Electrochim Acta 107:681–685. https://doi.org/10.1016/j.electacta.2013.06.045
Lu Y-C, Gasteiger HA, Crumlin E, McGuire R, Shao-Horn Y (2010) Electrocatalytic activity studies of select metal surfaces and implications in Li-Air batteries. J Electrochem Soc 157:A1016–A1025. https://doi.org/10.1149/1.3462981
Lu X et al (2019a) 3D Ag/NiO-Fe2O3/Ag nanomembranes as carbon-free cathode materials for Li-O2 batteries. Energy Storage Mater 16:155–162. https://doi.org/10.1016/j.ensm.2018.05.002
Lu Z et al (2019b) An isolated zinc-cobalt atomic pair for highly active and durable oxygen reduction. Angew Chem Int Ed 58:2622–2626. https://doi.org/10.1002/anie.201810175
Ma L, Meng N, Zhang Y, Lian F (2019) Improved electrocatalytic activity of δ-MnO2@MWCNTs by inducing the oriented growth of oxygen reduction products in Li-O2 batteries. Nano Energy 58:508–516. https://doi.org/10.1016/j.nanoen.2019.01.089
McCloskey BD, Scheffler R, Speidel A, Bethune DS, Shelby RM, Luntz AC (2011) On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries. J Am Chem Soc 133:18038–18041. https://doi.org/10.1021/ja207229n
Meng F-L, Liu K-H, Zhang Y, Shi M-M, Zhang X-B, Yan J-M, Jiang Q (2018) Recent advances toward the rational design of efficient bifunctional air electrodes for rechargeable Zn–air batteries. Small 14:1703843. https://doi.org/10.1002/smll.201703843
Mohamad AA (2006) Zn/gelled 6M KOH/O2 zinc–air battery. J Power Sources 159:752–757. https://doi.org/10.1016/j.jpowsour.2005.10.110
Monaco S, Soavi F, Mastragostino M (2013) Role of oxygen mass transport in rechargeable Li/O2 batteries operating with ionic liquids. J Phys Chem Lett 4:1379–1382. https://doi.org/10.1021/jz4006256
Naik KM, Sampath S (2018) Two-step oxygen reduction on spinel NiFe2O4 catalyst: rechargeable, aqueous solution- and gel-based, Zn-air batteries. Electrochim Acta 292:268–275. https://doi.org/10.1016/j.electacta.2018.08.138
Neburchilov V, Wang H, Martin JJ, Qu W (2010) A review on air cathodes for zinc–air fuel cells. J Power Sources 195:1271–1291. https://doi.org/10.1016/j.jpowsour.2009.08.100
Othman R, Basirun WJ, Yahaya AH, Arof AK (2001) Hydroponics gel as a new electrolyte gelling agent for alkaline zinc–air cells. J Power Sources 103:34–41. https://doi.org/10.1016/S0378-7753(01)00823-0
Ottakam Thotiyl MM, Freunberger SA, Peng Z, Bruce PG (2013) The carbon electrode in nonaqueous Li-O2 cells. J Am Chem Soc 135:494–500. https://doi.org/10.1021/ja310258x
Park J, Park M, Nam G, Kim MG, Cho J (2017) Unveiling the catalytic origin of nanocrystalline yttrium ruthenate pyrochlore as a bifunctional electrocatalyst for Zn-air batteries. Nano Lett 17:3974–3981. https://doi.org/10.1021/acs.nanolett.7b01812
Pelegov VD, Pontes J (2018) Main drivers of battery industry changes: electric vehicles—a market overview batteries. Batteries 4(4):65. https://doi.org/10.3390/batteries4040065
Qian Y et al (2017) A metal-free ORR/OER bifunctional electrocatalyst derived from metal-organic frameworks for rechargeable Zn-air batteries. Carbon 111:641–650. https://doi.org/10.1016/j.carbon.2016.10.046
Read J (2006) Ether-based electrolytes for the lithium/oxygen organic electrolyte battery. J Electrochem Soc 153:A96–A100. https://doi.org/10.1149/1.2131827
Ren J-T, Yuan G-G, Chen L, Weng C-C, Yuan Z-Y (2018) Rational dispersion of Co2P2O7 fine particles on N,P-codoped reduced graphene oxide aerogels leading to enhanced reversible oxygen reduction ability for Zn-air batteries. ACS Sustain Chem Eng 6:9793–9803. https://doi.org/10.1021/acssuschemeng.8b00873
Shang C et al (2018) Fe3O4@CoO mesospheres with core-shell nanostructure as catalyst for Li-O2 batteries. Appl Surf Sci 457:804–808. https://doi.org/10.1016/j.apsusc.2018.07.026
Shao Q, Liu J, Wu Q, Li Q, Wang H-G, Li Y, Duan Q (2019) In situ coupling strategy for anchoring monodisperse Co9S8 nanoparticles on S and N dual-doped graphene as a bifunctional electrocatalyst for rechargeable Zn-air battery. Nano-Micro Lett 11:4. https://doi.org/10.1007/s40820-018-0231-3
Song L et al (2017) Functional species encapsulated in nitrogen-doped porous carbon as a highly efficient catalyst for the oxygen reduction reaction chemistry. Eur J 23:3398–3405. https://doi.org/10.1002/chem.201605026
Su H, Xu Q, Chong J, Li H, Sita C, Pasupathi S (2017) Eliminating micro-porous layer from gas diffusion electrode for use in high temperature polymer electrolyte membrane fuel cell. J Power Sources 341:302–308. https://doi.org/10.1016/j.jpowsour.2016.12.029
Sun C, Guo X, Zhang J, Han G, Gao D, Gao X (2019) Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide. J Energy Chem 38:34–40. https://doi.org/10.1016/j.jechem.2019.01.001
Tan P et al (2017) Advances and challenges in lithium-air batteries. Appl Energy 204:780–806. https://doi.org/10.1016/j.apenergy.2017.07.054
Tang C, Wang H-F, Zhang Q (2018) Multiscale principles to boost reactivity in gas-involving energy electrocatalysis accounts of chemical research. Acc Chem Res 51:881–889. https://doi.org/10.1021/acs.accounts.7b00616
Veith GM, Dudney NJ (2011) Current collectors for rechargeable Li-air batteries. J Electrochem Soc 158:A658–A663. https://doi.org/10.1149/1.3569750
Vij V et al (2017) Nickel-based Electrocatalysts for energy-related applications: oxygen reduction, oxygen evolution, and hydrogen evolution reactions. ACS Catal 7:7196–7225. https://doi.org/10.1021/acscatal.7b01800
Wilcke WW, Kim H (2016) The 800-km battery lithium-ion batteries are played out. Next up: lithium-air. IEEE Spectrum 53:42–62. https://doi.org/10.1109/MSPEC.2016.7420398
Yang Z, Zhang J, Kintner-Meyer MC, Lu X, Choi D, Lemmon JP, Liu J (2011) Electrochemical energy storage for green grid. Chem Rev 111:3577–3613. https://doi.org/10.1021/cr100290v
Yang L, Wang D, Lv Y, Cao D (2019) Nitrogen-doped graphitic carbons with encapsulated CoNi bimetallic nanoparticles as bifunctional electrocatalysts for rechargeable Zn-Air batteries. Carbon 144:8–14. https://doi.org/10.1016/j.carbon.2018.12.008
Yu A, Lee C, Lee N-S, Kim MH, Lee Y (2016) Highly efficient silver-cobalt composite nanotube electrocatalysts for favorable oxygen reduction reaction. ACS Appl Mater Interfaces 8:32833–32841. https://doi.org/10.1021/acsami.6b11073
Zhang T, Imanishi N, Takeda Y, Yamamoto O (2011) Aqueous lithium/air rechargeable batteries. Chem Lett 40:668–673. https://doi.org/10.1246/cl.2011.668
Zhang RH, Zhao TS, Wu MC, Jiang HR, Zeng L (2018) Mesoporous ultrafine Ta2O5 nanoparticle with abundant oxygen vacancies as a novel and efficient catalyst for non-aqueous Li-O2 batteries. Electrochim Acta 271:232–241. https://doi.org/10.1016/j.electacta.2018.03.164
Zhang J et al (2019a) Bimetallic nickel cobalt sulfide as efficient electrocatalyst for Zn-air battery and water splitting. Nano-Micro Lett 11:2. https://doi.org/10.1007/s40820-018-0232-2
Zhang P-F et al (2019b) High-performance rechargeable Li-CO2/O2 battery with Ru/N-doped CNT catalyst. Chem Eng J 363:224–233. https://doi.org/10.1016/j.cej.2019.01.048
Zheng Q, **ng F, Li X, Ning G, Zhang H (2016) Flow field design and optimization based on the mass transport polarization regulation in a flow-through type vanadium flow battery. J Power Sources 324:402–411. https://doi.org/10.1016/j.jpowsour.2016.05.110
Zhong B, Zhang L, Yu J, Fan K (2019) Ultrafine iron-cobalt nanoparticles embedded in nitrogen-doped porous carbon matrix for oxygen reduction reaction and zinc-air batteries. J Colloid Interface Sci 546:113–121. https://doi.org/10.1016/j.jcis.2019.03.038
Zou L, Jiang Y, Cheng J, Gong Y, Chi B, Pu J, Jian L (2016) Dandelion-like NiCo2O4 hollow microspheres as enhanced cathode catalyst for Li-oxygen batteries in ambient air. Electrochim Acta 216:120–129. https://doi.org/10.1016/j.electacta.2016.08.151
Zou L, Jiang Y, Cheng J, Chen Y, Chi B, Pu J, Jian L (2018) Bifunctional catalyst of well-dispersed RuO2 on NiCo2O4 nanosheets as enhanced cathode for lithium-oxygen batteries. Electrochim Acta 262:97–106. https://doi.org/10.1016/j.electacta.2018.01.005
Zouhri K, Lee S-Y (2016) Evaluation and optimization of the alkaline water electrolysis ohmic polarization: exergy study. Int J Hydrogen Energ 41:7253–7263. https://doi.org/10.1016/j.ijhydene.2016.03.119
Acknowledgment
This work was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES) (Finance Code 001).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Costa, J.M., de Almeida Neto, A.F. (2020). New Approaches for Renewable Energy Using Metal Electrocatalysts for Lithium-O2 and Zinc-Air Batteries. In: Inamuddin, Asiri, A. (eds) Sustainable Green Chemical Processes and their Allied Applications. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-42284-4_3
Download citation
DOI: https://doi.org/10.1007/978-3-030-42284-4_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-42283-7
Online ISBN: 978-3-030-42284-4
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)