Electronic Structure and Optical Properties

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Intercalation in Layered Materials

Part of the book series: NATO ASI Series ((NSSB,volume 148))

Abstract

Graphite exhibits a lamellar structure (Fig.1). The lattice consists of oexagonal carbon monolayers separated by an interplanar spacing (d=3.35Å) much larger than the in-plane nearest neighbour distance (b=1.42Å). The weak interlayor interactions allow the intercalation of a wide diversity of atomic and molecular species between the carbon layers. Graphite Intercalation Compounds (GIC) are characterized by the existence of stage ordering: a periodic sequence of n graphite layers and an intercalated layer, with n defining the stage of the compound [1–11].

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References

  1. A. Herold: In Physics and Chemistry of Materials with Layered Structures, ed. by F.A. Levy, D. Reidel (Dordrecht 1979), Vol.6 (Intercalated Layered Materials), p.323

    Google Scholar 

  2. J.E. Fischer: In Physics and Chemistry of Materials with Layered Structures, ed. by F.A. Levy, D. Reidel (Dordrecht 1979, Vol.6 [Intercalated Layered Materials), p.383

    Google Scholar 

  3. S.A. Solin: In Advances in Chemical Physics

    Google Scholar 

  4. P. Pfluger and H.H. Gunterodt: In Advances in Solid State Physics Vol.21 (Vieweg, Braunsweig 1981)

    Google Scholar 

  5. M.S. Dresselhaus and G. Dresselhaus: In Adv. Phys. 30, 139 (1981).

    Article  Google Scholar 

  6. Proceedings Franco-American Conference on Intercalation Compounds of Graphite (La Napoule, France), Mat. Sci. Eng. 31 (1977)

    Google Scholar 

  7. Proceedings of the International Conference on layered Materials and Intercalated (Nijmegen, The Netherlands), Physica 99B (1980)

    Google Scholar 

  8. E. Proceedings of the Second International Conference on Intercalation Compounds of Graphite (Provincetown, Mass., USA), Synthetic Metals 2/3 (1980/1981)

    Google Scholar 

  9. Ptroceedings of the Third International Conference on Intercalation Compounds of Graphite (Pont-à-Mousson, France), Synthetic Metals 8 (1983)

    Google Scholar 

  10. Proceedings of the Fourth International Conference on Intercalation Compounds of Graphite (Tsukuba, Japan), Synthetic Metals 12 (1986)

    Google Scholar 

  11. Proceedings of the French-Japanese Symposium on Graphite Intercalation Compounds (Paris, France), Annales de Physique N°2 (Supp1.2) 11 (1986)

    Google Scholar 

  12. M. Zanini and J.E. Fischer: In Ref.[6], p.169

    Google Scholar 

  13. P.R. Wallace: In Phys. Rev. 71, 622 (1947)

    Article  CAS  Google Scholar 

  14. G.S. Painter and D.E. Ellis: In Phys. Rev. 81, 4747 (1970)

    Article  Google Scholar 

  15. M. Tsukada, K. Nakao, Y. Uemura and S. Nagai: in Journ. Phys. Soc. Jap. 32, 54 (1972)

    Article  CAS  Google Scholar 

  16. J. Blinowski, Nguyen Hy Hau, C. Rigaux, J.P. Vieren, R. Le Toullec, G. Furdin, A. Herold, J. Melin: In Journal Physique (Faris) 41, 47 (1981)

    Article  Google Scholar 

  17. J.C. Slonczewski and P.R. Weiss: In Phys. Rev. 109, 272 (1958)

    Article  CAS  Google Scholar 

  18. J.N. McClure: In Phys. Rev. 108, 612 (1957)

    Article  CAS  Google Scholar 

  19. A. Zunger: In Phys. Rev. 817, 626 (1978)

    Article  Google Scholar 

  20. R.C. Tatar and S. Rabii: In Phys. Rev. 825 4126 (1982)

    Google Scholar 

  21. I.L. Spain: In Proceedings of the International Conference on Semi-metals and Narrowgap Semiconductors (Pergamon Press, New York 1973), p.177, and in Chemistry and Physics of Carbon, ed. by P.L. Walker (New York:Marcel Dekker), Vol. 8, p. 105

    Google Scholar 

  22. N.A.W. Holtzwarth, L.A. Girifalco and S. Rabii: In Phys. Rev. 818, 5190 (1978) and in Phys. Rev. 818, 5206 (1978)

    Google Scholar 

  23. T. Ohno, K. Nakao, H. Kamimura: In J. Phys. Soc. Jap. 47, 1125 (1979), and H. Kamimura: In Ref.[11], p.39

    Google Scholar 

  24. T. Inoshita, K. Nakao and H. Kamimura: In J. Phys. Soc. Jap. 43, 2137 (1977)

    Google Scholar 

  25. D.P.DiVicenzo and S. Rabii: In Ref.[7], p.406, and in Phys. Rev. 825, 4110 (1982)

    Google Scholar 

  26. T.C. Tatar: In Ph. D. Thesis (University of Pennsylvania, USA,1985)

    Google Scholar 

  27. G. Dresselhauss and S.Y. Leung: In Phys. Rev. 824, 3490 (1981)

    Google Scholar 

  28. W.D. Ellenson, D. Semmingson and J.E. Fischer: In Mat. Sci. Eng. 31 (1977)

    Google Scholar 

  29. G.S. Parry and D.E. Nixon: In J. Phys. C 2, 2156 (1969)

    CAS  Google Scholar 

  30. N.A.W. Holtzwarth: In Phys. Rev. B21, 3665 (1980)

    Article  Google Scholar 

  31. L. Pietronero, S. Strassier, H.K. Zeller and M.J. Rice: In Phys. Rev. Lett. 41, 763 (1978), and in Sol. St. Comm. 10, 399 (1979)

    Article  Google Scholar 

  32. J. Blinowski and C. Rigaux: In Journ. Physique (Faris) 41, 667 (1980), and in Ref.[8], p.297

    Google Scholar 

  33. S.A. Safran and D.R. Hamann: In Phys. Rev. B22, 3490 (1981), and in Phys. Rev. B23, 565 (1981), and in Ref.[p.1

    Google Scholar 

  34. S. Shimamura and A. Morita: Ln J. Phys. Soc. Jap. 51, 502 (1982)

    Article  CAS  Google Scholar 

  35. T. Ohno and H. Kamimura: In J. Phys. Soc. Jap. 52, 223 (1983), and in Ref.[11], p.179

    Google Scholar 

  36. D.L. Greenaway, G. Harbeke, F. Bassani and E. Tosatti: In Phys. Rev. 178, 1340 (1969)

    Article  CAS  Google Scholar 

  37. M.S. Dresselhaus, G. Dresselhaus and S.E. Fischer: In Phys. Rev. B15, 3180 (1977)

    Article  CAS  Google Scholar 

  38. P.R. Hanlon, E.R. Falardeau, D. Guerard, J.E. Fischer: Ir Mat. Sci. Eng. 31, 161 (1 977), and in Sol. St. Comm. 377 (1 977)

    Google Scholar 

  39. M. Saint Jean, Nguyen Hy Hau, C. Rigaux, G. Furdin: In Sol. St. Comm. 46, 55 (1983)

    Article  Google Scholar 

  40. T.E. Thompson, E.R. Falardeau and L.R. Hannon: In Carbon 15, 39 (1977)

    Article  CAS  Google Scholar 

  41. Nguyen Hy Hau, J. Blinowski, C. Rigaux, R. Le Toullec, G. Furdin, A. Herold, R. Vangelisti: In Synth. Metals 3, 99 (1981)

    Article  Google Scholar 

  42. J. Blinowski, Nguyen Hy Hau, C. Rigaux, J.P. Vieren: In J. Phys. Soc. Jap. 49, Suppla, 915 (1980)(15th Intern. Conf. Phys. Semicond.)

    Google Scholar 

  43. C. Rigaux and J. Blinowski: In Physics of Narrow Gap Semiconductors (4 Intern. Conf.), p.352, Lecture Notes in Physics N°152 (Springer, Beriin 1982)

    Google Scholar 

  44. P.C. Eklund, D.S. Smith and V.R.K. Murthy: In Synth. Metals 3, 111 (1981)

    Google Scholar 

  45. D,M.Hoffman, R.E. Heinz, G.L. Doll and P.C. Eklund: In Fhys. Rev. 332, 1278 (1985)

    Google Scholar 

  46. D.M. Hoffman, P.C. Eklund, R.E. Heins, P. Hawrylak and K.o. Subbaswamy! In Phys. Rev. 831, 3973 (1985)

    Google Scholar 

  47. J.E. Fischer, T.E. Thompson, G.M.T. Foley, D. Guerard, M. Hoke and F.L. Lederman: In P:tys. Rev. Lett. 37, 769 (1976)

    Article  CAS  Google Scholar 

  48. C.C. Shieh, R.L. Schmidt and J.E. Fischer: In Phys, Rev. B20, 3351 (1979)

    Article  CAS  Google Scholar 

  49. M. Saint Jean, M. Menant, Nguyen Hy Hau, C. Rigaux, A. Metrot: In Synth. Metals 8, 189 (1985)

    Article  Google Scholar 

  50. M. Saint Jean: in Thesis (Paris 1983)

    Google Scholar 

  51. J.M. Mang, D.U. Hoffman and P.C. Eklund: In Plays. Rev. B (in press)

    Google Scholar 

  52. E.A. Taft and H.R. Philipp: In Phys, Rev. 138, A197 (1965)

    Google Scholar 

  53. F. Bassani, G. Fastori-Parravicini: In Nuovo Cimento 50E, 95 (1967)

    Article  CAS  Google Scholar 

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Rigaux, C. (1986). Electronic Structure and Optical Properties. In: Dresselhaus, M.S. (eds) Intercalation in Layered Materials. NATO ASI Series, vol 148. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5556-5_19

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  • DOI: https://doi.org/10.1007/978-1-4757-5556-5_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-5558-9

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