Abstract
Microporous, transition metal ion-substituted aluminophosphate molecular sieves have attracted considerable attention over the last decade owing to their shape-selective catalytic properties for both acid-catalyzed conversion of methanol to lower olefins and aerobic oxyfunctionalization of saturated hydrocarbons. By controlling the types of transition metal ions that are substituted in place of Al(III) ions in the framework of the aluminophosphate structure and the pore structure of the microporous materials, it is now possible to perform both reactant- and product-selective catalytic reactions. Detailed structures of the molecular sieves, local structures of the active (transition metal ion) sites and their relationship to catalytic properties are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Wilson, S. T.; Lok, B. M.; Messina, C. A.; Cannan, T. R.; Flanigen, E. M. J. Am. Chem. Soc. 1982, 104, 1146,.
Wilson, S. T.; Flanigen, E. M. in ACS Symp. Ser. Zeolite Synthesis, Occelli, M. L. Robson, H. E., Eds. ACS: Washington D.C. 1989, 398, 329.
Thomas, J. M. Phil. Trans. Royal Soc. Lond. Ser. A 1990,333, 173.
Thomas, J. M. Angew. Chem., Int. Ed. Engl. 1994,33, 913.
Thomas, J. M.; Raja, R.; Sankar, G.; Bell, R. G. Acc. Chem. Res. 2001, 34, 191.
Chen, J. S.; Thomas, J. M. J. Chem. Soc., Chem. Comm. 1994, 603.
Marchese, L.; Chen, J. S.; Thomas, J. M.; Coluccia, S.; Zecchina, A. J. Phys. Chem. 1994, 98, 13350.
Thomas, J. M.; Greaves, G. N.; Sankar, G.; Wright, P. A.; Chen, J. S.; Dent, A. J. Marchese, L. Angew. Chem., Int. Ed. Engl. 1994, 33, 1871.
Sheldon, R. A.; Dakka, J. Catal. Today 1994, 19, 215.
Sheldon, R. A. Proc. 3rd World Congress on Oxidation Catalysis 1997, 770, 151.
Vanoppen, D. L., Devos, D. E.; Genet, M. J.; Rouxhet, P. G.; Jacobs, P. A Angew. Chem., Int. Ed. Engl. 1995, 34, 560.
Weckhuysen, B. M., Rao, R. R.; Martens, J. A.; Schoonheydt, R. A.; Eur. J. Inorg. Chem. 1999, 565.
Hartmann, M.; Kevan, L. Chem. Rev. 1999, 99, 635.
Weckhuysen, B. M.; Verberckmoes, A. A.; Uytterhoeven, M. G.; Mabbs, F. E.; Collison, D.; de Boer, E.; Schoonheydt, R. A. J. Phys. Chem. B 2000, 704, 37.
Canesson, L.; Boudeville, Y.; Tuel, A. J. Am. Chem. Soc. 1997, 119, 10754.
Sankar, G.; Thomas, J. M. Top. Catal. 1999, 8, 1.
Sankar, G., Thomas, J. M.; Catlow, C. R. A. Top. Catal 2000, 10, 255.
Chen, J. S.; Sankar, G., Thomas, J. M.; Xu, R. R.; Greaves, G. N.; Waller, D. Chem. Mater. 1992, 4, 1373.
Sankar, G; Thomas, J. M.; Chen, J.; Wright, P. A.; Barrett, P. A.; Greaves, G. N.; Catlow, C. R. A. Nucl. Instrum. Meth. B 1995, 97, 37.
Barrett, P. A., Sankar, G.; Catlow, C. R. A.; Thomas, J. M. J. Phys. Chem. 1996, 100, 8977.
Barrett, P. A., Sankar, G.; Catlow, C. R. A.; Thomas, J. M. J. Phys. Chem. Solids 1995, 56, 1395.
Iton, L. E.; Choi, I.; Desjardins, J. A.; Maroni, V. A. Zeolites 1989, 9, 535.
Kurshev, V.; Kevan, L.; Parillo, D. J.; Pereira, C.; Kokotailo, G. T.; Gorte, R. J. J. Phys. Chem. 1994, 98, 10160.
Prakash, A. M.; Hartmann, M.; Kevan, L. J. Phys. Chem. B 1997, 101, 6819.
Moen, A.; Nicholson, D. G.; Ronning, M.; Lamble, G. M.; Lee, J. F.; Emerich, H. J. Chem. Soc., Farad. Trans. 1997, 93, 4071.
Thomson, S.; Luca, V.; Howe, R. Phys. Chem. Chem. Phys. 1999, 1, 615.
Montes, C.; Davis, M. E.; Murray, B.; Narayana, M. J. Phys. Chem. 1990, 94, 6425.
Muncaster, G.; Sankar, G.; Catlow, C. R. A.; Thomas, J. M.; Coles, S. J.; Hursthouse, M. Chem. Mater. 2000, 12, 16.
Yannoni, N. F. PhD thesis, Univ. Boston, 1961; also see ICSD data base reference number 17580.
Toriumi, K.; Ozima, M.; Akaogi, M; Saito, Y. Acta Crystal. B 1978, 34, 1093.
Sankar, G.; Raja, R.; Thomas, J. M. Catal. Lett. 1998, 55, 15.
Thomas, J. M.; Raja, R.; Sankar, G.; Bell, R. G. Nature 1999, 398, 227.
Chen, J. S.; Wright, P. A.; Thomas, J. M.; Natarajan, L.; Marchese, L.; Bradley, S. M.; Sankar, G.; Catlow, C. R. A.; Gaiboyes, P. L.; Townsend, R. P.; Lok, C. M. J. Phys. Chem. 1994, 98, 10216.
Muncaster, G.; Davies, A. T; Sankar, G.; Catlow, C. R. A.; Thomas, J. M.; Colston, S. L.; Barnes, P. I.; Walton, R. I.; O’Hare, D. Phys. Chem. Chem. Phys. 2000, 2, 3523.
Walton, R. L; O’Hare, D. J. Chem. Soc., Chem. Comm. 2000, 2283.
Francis, R. J.; O’Hare, D. J. Chem. Soc., Dalton Trans. 1998, 3133.
Raja, R.; Sankar, G.; Thomas, J. M. Angew. Chem. Int. Ed. 2000, 39, 2313.
Sankar, G.; Wyles, J. K.; Jones, R. H.; Thomas, J. M.; Catlow, C. R. A.; Lewis, D. W.; Clegg, W.; Coles, S. J.; Teat, S. J. J. Chem. Soc., Chem. Comm. 1998, 117.
Lewis, D.W.; Sankar, G.; Wyles, J. K.; Thomas, J. M.; Catlow, C. R. A.; Willock, D. J. Angew. Chem. Int. Ed. 1997, 36, 2675.
Raja, R.; Sankar, G.; Thomas, J. M. J. Am. Chem. Soc 1999, 121, 11926.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2005 Springer Science + Business Media, Inc.
About this chapter
Cite this chapter
Sankar, G., Raja, R. (2005). On the Structure of Cobalt-Substituted Aluminophosphate Catalysts and Their Catalytic Performance. In: Scott, S.L., Crudden, C.M., Jones, C.W. (eds) Nanostructured Catalysts. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-30641-4_8
Download citation
DOI: https://doi.org/10.1007/978-0-387-30641-4_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-0-306-47484-2
Online ISBN: 978-0-387-30641-4
eBook Packages: Springer Book Archive