Abstract
Chromium is one of the earth-abundant transition metals. The use of chromium as low-cost alternative to precious metals for catalysis is of great synthetic and mechanistic interest. Progress in the development of cross-coupling reactions by chromium catalysis has been recently made, offering valuable strategies to forge C–C bonds under mild conditions. This chapter aims to highlight recent achievements in the development of strategies for constructing ubiquitous C–C bonds through chromium catalysis in recent years. It is organized by cross couplings with chemically inert C–heteroatom and C–H bonds in forming C–C bonds, mainly focusing on the discussion of plausible mechanisms for insight into design of robust catalysts, as well as the development of new coupling models and catalytic strategies.
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We thank the National Natural Science Foundation of China (Nos. 22125107, 21971168 and 21572175) for financial support. We also thank the authors whose names are listed in the references for their contributions in the field.
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Hou, Y., Xu, W., Zeng, X. (2023). C–C Cross Couplings with Chromium Catalysis. In: Wu, XF. (eds) C-C Cross Couplings with 3d Base Metal Catalysts. Topics in Organometallic Chemistry, vol 71. Springer, Cham. https://doi.org/10.1007/3418_2023_91
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DOI: https://doi.org/10.1007/3418_2023_91
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