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Chiral Alkaline Earth Metal Complexes in Asymmetric Catalysis

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Chiral Lewis Acids

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 62))

Abstract

Alkaline earth metal catalysis for asymmetric reactions is a hot topic from the viewpoint of green sustainable chemistry. The stable alkaline earth metals, calcium (Ca), strontium (Sr), and barium (Ba) are abundant in the Earth’s crust, and their strong Brønsted basicity and mild Lewis acidity are useful for construction of alkaline earth metal complexes as chiral catalysts. In this chapter, the development of chiral alkaline earth metal catalysts for catalytic asymmetric reactions is described. The chiral alkaline earth metal complexes are categorized into three types of complexes, types I–III, by coordination modes, and those complexes successfully promoted many types of reactions in acid–base catalysis with high enantioselectivities.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

    Yasuhiro Yamashita, Tetsu Tsubogo & Shū Kobayashi

Authors
  1. Yasuhiro Yamashita
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  2. Tetsu Tsubogo
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  3. Shū Kobayashi
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Corresponding author

Correspondence to Shū Kobayashi .

Editor information

Editors and Affiliations

  1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, Tokyo, Japan

    Koichi Mikami

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Yamashita, Y., Tsubogo, T., Kobayashi, S. (2015). Chiral Alkaline Earth Metal Complexes in Asymmetric Catalysis. In: Mikami, K. (eds) Chiral Lewis Acids. Topics in Organometallic Chemistry, vol 62. Springer, Cham. https://doi.org/10.1007/3418_2015_144

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