Abstract—
The structure and dielectric properties of new hybrid polymer nanocomposites based on polyvinylidene fluoride (PVDF) and CdS and ZnS nanoparticles (NPs) have been studied. It was established that ZnS and CdS NPs, when added at low concentrations, define the structure of the host polymer matrix, and new polar groups and stable charge traps arise, which, in turn, leads to an increase in the dielectric permittivity and polarizing ability of the nanocomposites based on PVDF + CdS/ZnS NPs. As the NP concentration is increased, the NPs start to behave like a separate dispersion phase, and the conductivity of nanocomposites grows as the content of this phase increases, which results in the nanocomposite’s polarizing ability gradually diminishing.
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REFERENCES
Pomogailo, A.D., Rozenberg, A.S., and Uflyand, I.E., Nanochastitsy metallov v polimerakh (Metal Nanoparticles in Polymers), Moscow: Khimiya, 2000.
Lai, L.-H., Protesescu, L., Kovalenko, M., and Loi, M., Phys. Chem. Chem. Phys., 2014, vol. 16, pp. 736–742.
Yitan, L., Lin, W., **ya, C., Ruizi, Z., et al., Nanoscale Res. Lett., 2013, vol. 8, no. 1, pp. 1–7.
Chunchun, H., Feng, W., Chong, G., Peng, L., et al., J. Mater. Chem. C, 2015, vol., pp. 5065–5072.
Lidong, S., Sci. China Mater., 2016, vol. 59, no. 10, pp. 817–824.
Novruzova, A.A., Ramazanov, M.A., Chianese, A., Hajiyeva, F.V., et al., Chem. Eng. Trans., 2017, vol. 60, pp. 61–66.
Wang, L., Wei, H., Fan, Y., Liu, X., and Zhan, J., Nanoscale Res. Lett., 2009, vol. 4, no. 6, pp. 558–564.
Khan, S., Jiang, Z., Premathilka, S.M., Antu, A., Hu, J., et al., J. Nanomater., 2017, vol. 2, no. 60, pp. 3685–3690.
Durmusoglu, E.G., Yildizhan, M.M., Gulgun, M.A., et al., J. Phys. Chem. C, 2017, vol. 121, no. 45, pp. 25520–25530.
Magerramov, A.M., Ramazanov, M.A., and Hajiyeva, F.V., Optoelectron. Adv. Mater., 2008, vol. 2, no. 11, pp. 743–746.
Magerramov, A.M., Ramazanov, M.A., and Gadjiyeva, F.V., Optoelectron. Adv. Mater., Rapid Commun., 2009, vol. 3, no. 12, pp. 1348–1353.
Magerramov, A.M., Ramazanov, M.A., Hajiyeva, F.V., and Alieva, S.G., J. Appl. Electrochem., 2011, vol. 47, no. 5, pp. 428–432.
Ramazanov, M.A., Hajiyeva, F.V., Maharramov, A.M., Shirinova, H.A., et al., Proc. Int. Conf. of Young Scientists “Problems of Physics and Astronomy,” May 25, 2018, Baku: Baku State Univ., 2018, pp. 30–36.
Ramazanov, M.A., Hajiyeva, F.V., Shirinova, H.A., and Mamedov, H.M., Int. J. Mod. Phys. B, 2019, vol. 33, no. 10, 1950083.
Ramazanov, M.A., Hajiyeva, F.V., and Maharramov, A.M., Integr. Ferroelectr., 2019, vol. 192, no. 1, pp. 103–112.
Magerramov, A.M., Ramazanov, M.A., Hajiyeva, F.V., and Nuriyeva, S.G., Proc. Int. Conf. “Modern Trends in Physics,” April 20–22, 2017, Baku: Baku State Univ., 2017, pp. 7–11.
Maharramov, A.M., Ramazanov, M.A., Ahmadova, A.B., Hajiyeva, F.V., et al., Digital J. Nanomater. Biosci., 2016, vol. 11, no. 3, pp. 781–786.
Maharramov, A.M., Ramazanov, M.A., and Hajiyeva, F.V., Chalcogenide Lett., 2016, vol. 13, no. 1, pp. 35–40.
Maharramov, A.M., Ramazanov, M.A., Sultanova, J.R., Hajiyeva, F.V., et al., J. Optoelectron. Biomed. Mater., 2016, vol. 8, no. 3, pp. 113–118.
Maharramov, A.M., Ramazanov, M.A., Hajiyeva, F.V., and Amirov, S.S., J. Optoelectron. Biomed. Mater., 2016, vol. 8, no. 1, pp. 15–20.
Magerramov, A.M., Ramazanov, M.A., Hajiyeva, F.V., and Guliyeva, V.M., J. Appl. Electrochem., 2011, vol. 9, no. 5, pp. 133–141.
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Hajiyeva, F.V. New Hybrid Polymer Nanocomposites Based on Polyvinylidene Fluoride and CdS/ZnS Nanoparticles: Structure and Dielecric Properties. Surf. Engin. Appl.Electrochem. 56, 649–655 (2020). https://doi.org/10.3103/S1068375520060058
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DOI: https://doi.org/10.3103/S1068375520060058