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A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS

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Abstract

The separation properties of arsenic species was investigated using HPLC-ICP-MS with several commercially available fluorocarbon stationary phases and no ion-pair reagents in HPLC. One pentafluorophenyl column showed the highest potential for the separation of a larger number of arsenic species when using simple acid-based mobile phases. After modification of the operational parameters in HPLC, the speciation analysis of 13 representative arsenic species: arsenite, arsenate, methylarsonic acid, dimethylarsinic acid, trimethylarsine oxide, tetramethylarsonium, arsenobetaine, arsenocholine, thio-dimethylarsinic acid, oxo-arsenosugar-glycerol, oxo-arsenosugar-phosphate, oxo-arsenosugarsulfonate, and oxo-arsenosugar-sulfate, was achieved by HPLC-ICP-MS with the column along with a mobile phase of 0.05% heptafluorobutyric acid-methanol (99:1, volume per volume).

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Authors and Affiliations

  1. Environmental Standards Group, Research Institute for Material and Chemical Measurement, National Metrology Institute of Japan, National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 3, 1-1-1 Umezono Tsukuba, Ibaraki, 305-8563, Japan

    Shin-ichi Miyashita

  2. Biotechnology Group, Research and Development Department, Tokyo Metropolitan Industrial Technology Research Institute, 2-4-10 Aomi Koto, Tokyo, 135-0064, Japan

    Kenji Kinoshita

  3. Laboratory of Environmental Chemodynamics, School of Life Sciences, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi Hachioji, Tokyo, 192-0392, Japan

    Toshikazu Kaise

Authors
  1. Shin-ichi Miyashita
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  2. Kenji Kinoshita
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  3. Toshikazu Kaise
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Correspondence to Shin-ichi Miyashita.

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Miyashita, Si., Kinoshita, K. & Kaise, T. A Simple and Effective Method for Speciation Analysis of 13 Arsenic Species Using HPLC on a Fluorocarbon Stationary Phase Coupled to ICP-MS. ANAL. SCI. 37, 381–386 (2021). https://doi.org/10.2116/analsci.20N019

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  • DOI: https://doi.org/10.2116/analsci.20N019

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