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Electrogenerated Chemiluminescence of Tris(dibenzoylmethane)phenanthroline Europium(III) as a Light Source: An Application for the Detection of PO43-Based on the Ion Associate Formation of Phosphomolybdic Acid and Malachite Green

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Abstract

We demonstrate that electorogenerated chemiluminescence (ECL) of an organometallic Eu(III) complex, tris(dibenzoylmethane)phenanthroline europium(III), whose emission spectra is very sharp with the maximum wavelength of 612 nm, can be used as a light source for the detection of PO43– based on changing the absorbance of the ion associate of malachite green (MG+) and phosphomolybdic acid. The ECL was also applied to measure the absorbance of MG+. With the detection system we established, absorbance up to ~1.6 with a change of ~0.1 could be detected.

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Acknowledgments

This research was supported by the Japan Society for the Promotion of Science (JSPS) through its KAKENHI Grant Number JP 18K05176.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi, Fukuoka, 819-0395, Japan

    Eri Kunisawa, Ryoichi Ishimatsu, Koji Nakano & Toshihiko Imato

Authors
  1. Eri Kunisawa
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  2. Ryoichi Ishimatsu
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  3. Koji Nakano
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  4. Toshihiko Imato
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Corresponding authors

Correspondence to Ryoichi Ishimatsu or Toshihiko Imato.

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Kunisawa, E., Ishimatsu, R., Nakano, K. et al. Electrogenerated Chemiluminescence of Tris(dibenzoylmethane)phenanthroline Europium(III) as a Light Source: An Application for the Detection of PO43-Based on the Ion Associate Formation of Phosphomolybdic Acid and Malachite Green. ANAL. SCI. 35, 799–802 (2019). https://doi.org/10.2116/analsci.19N003

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  • DOI: https://doi.org/10.2116/analsci.19N003

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