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Liquid-Liquid Extraction of Palladium(II) from Hydrobromic Acid Media by Hexadecylpyridinium Bromide

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Abstract

A simple and rapid liquid-liquid extraction of palladium has been studied involving ion-pairing of bromocomplexes of palladium(II) with hexadecylpyridinium bromide (HDPB) dissolved in chloroform. The stoichiometry and distribution of (HDP)2PdBr4 between the aqueous and organic phase was investigated by spectrophotometric mole ratio method. The extraction efficiency of palladium(II) by HDPB was studied as a function of several variables: acid, salt, surfactant concentration and equilibrium time. The results showed that PdBr42- extraction could be explained by assuming the formation of (HDP)2PdBr4 complexes in the aqueous solution and transfer to organic phase. The extraction was fast and the shaking time was only a few min. The average recovery of palladium(II) from an aqueous solution containing 10 µg/ml of analyte was 99% with an RSD% of 0.95. The percentage recovery of 0.2 µg/ml palladium(II) was 96%.

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References

  1. A. K. De, S. M. Khopkar, and R. A. Chalmers, “Solvent Extraction of Metals”, 1970, Van Norstand, NewYork.

    Google Scholar 

  2. H. Freiser, Crit. Rev. Anal. Chem., 1970, 1, 14.

    Article  Google Scholar 

  3. Y. Marcus and A. S Kertes, “Ion Exchange and Solvent Extraction of Metal Complexes”, 1996, Wiley, New York.

    Google Scholar 

  4. G. H. Morrison and H. Freiser, “Solvent Extraction in Analytical Chemistry”, 1957, Wiley, New York.

    Google Scholar 

  5. Methods for Chemical Analysis of Water and Waste, EPA-600/4-79-020, 1983, Environmental Protection Agency, Research Triangle Park.

    Google Scholar 

  6. M. Wisniewski and J. Szymanowski, Anal. Sci., 1998, 14, 241.

    Article  CAS  Google Scholar 

  7. P. Riyazuddin, Talanta, 1982, 29, 1122.

    Article  CAS  Google Scholar 

  8. Z. Markzenko, S. Kus, and M. Mojski, Talanta, 1984, 31, 959.

    Article  Google Scholar 

  9. Z. Markzenko and S. Kus, Analyst, 1977, 25, 163.

    Google Scholar 

  10. S. J. Al-Bazi and H. Freiser, Solvent Extr. Ion Exchange, 1986, 4, 1121.

    Article  CAS  Google Scholar 

  11. G. Cote, K. M. Gangly, and D. Bauer, Hydrometallorgy, 1989, 23, 37.

    Article  CAS  Google Scholar 

  12. G. Cote, K. M. Gangly, D. Bauer, and S. Daamach, J. Chem. Res. (S), 1989, 158, (M) 1989, 1232.

    Google Scholar 

  13. G. Cote, K. M. Gangly, D. Bauer, and S. Daamach, Proceedings of Intern. Solvent Ext. Conf., ISEC 88, 1988 USSR Academy of Sciences, Moscow, 83.

    Google Scholar 

  14. J. Szymanowski, D. Bauer, G. Cote, and K. Prochaska, J. Chem. Tech. Biotechnol., 1990, 1, 144.

    Google Scholar 

  15. M. Wisniewski, J. Symanowski, G. Cote, and E. Meissner, J. Chem. Tech. Biotechnol., 1994, 60, 31.

    Article  CAS  Google Scholar 

  16. G. Cote, K. M. Gangly, D. Bauer, and S. Daamach, CR Acad Sci Paris, Serie II, 1988, 306, 571.

    CAS  Google Scholar 

  17. Q. Rong and H. Freiser, Solvent Extr. Ion Exchange, 1987, 5, 923.

    Article  CAS  Google Scholar 

  18. K. L. Mittal, “Solution Chemistry of Surfactants”, 1979, Plenum Press, New York.

    Book  Google Scholar 

  19. W. L. Hmze, H. N. Singh, Y. Baha, and N. G. Harrey, Tr. Anal. Chem., 1984, 3, 193.

    Article  Google Scholar 

  20. A. J. Tomg, Y. G. Wu, and L. D. Li, Anal. Chim. Acta, 1996, 322, 91.

    Article  Google Scholar 

  21. F. J. Detuccia, M. Arunyanart, and L. J. Cline Love, Anal. Chem., 1985, 57, 1564.

    Article  Google Scholar 

  22. S. Terabe, K. Qtsuka, K. Ichikawa, A. Tsuchiya, and T. Ando, Anal. Chem., 1984, 56, 111.

    Article  CAS  Google Scholar 

  23. H. Watanabe and H. Tanaka, Talanta, 1973, 25, 585.

    Article  Google Scholar 

  24. W. L. Hinze and E. Pramauro. Crit. Rev. Anal. Chem., 1993, 24, 133.

    Article  CAS  Google Scholar 

  25. N. N. Li, US Patent, 1968, 3, 410, 794.

    Google Scholar 

  26. W. Furst, J. Draxler, and R. Marr, Proc. 3rd World Congr. Chem. Eng., Tokyo, Japan, 1986, 3, 331.

    Google Scholar 

  27. R. M. Izatt, G. A. Clark, and J. J. Christensen, Sep. Sci. Technol., 1987, 22, 691.

    Article  CAS  Google Scholar 

  28. T. Kakoi, M. Goto, and F. Nakashio, Solvent. Extr. Res. Dev., Jpn., 1995, 2, 149.

    CAS  Google Scholar 

  29. N. Alizadeh, H. Gharibi, and M. Shamsipur, Bull. Chem. Soc. Jpn., 1995, 68, 730.

    Article  CAS  Google Scholar 

  30. M. Shamsipur, N. Alizadeh, and H. Gharibi, Bull. Chem. Soc. Jpn., 1996, 69, 311.

    Article  CAS  Google Scholar 

  31. M. Shamsipur, N. Alizadeh, and H. Gharibi, Indian J. Chem., 1997, 36A, 1031.

    CAS  Google Scholar 

  32. M. Shamsipur, N. Alizadeh, H. Gharibi, and M. F. Mousavi, J. Chin. Chem. Soc., 1997, 44, 9.

    Article  CAS  Google Scholar 

  33. F. Jalali, M. Shamsipur, and N. Alizadeh, J. Chem. Thermody., 2000, 32, 755.

    Article  CAS  Google Scholar 

  34. A. I. Vogel, “A Textbook of Quantitative Inorganic Analysis”, 4th ed., 1978, Longmans, London.

    Google Scholar 

  35. K. Vytras, J. Kalous, B. Simickova, J. Cerna, and I. Silena, Anal. Chim. Acta, 1988, 209, 357.

    Article  CAS  Google Scholar 

  36. G. D. Christian and J. E. Oreilly, “Instrumental Analysis”, 2nd ed., 1986, Allyn and Bacon, Boston.

    Google Scholar 

  37. V. J. Mathew and S. M. Khopkar, Talanta, 1977, 44, 1703.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Tarbiat Modarres University, P. O. Box, 14115-111, Tehran, Iran

    Naader Alizadeh & Shabnam Salimi

  2. Department of Chemistry, Khajeh Nasir Toosi University, Tehran, Iran

    Ali Jabbari

Authors
  1. Naader Alizadeh
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  2. Shabnam Salimi
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  3. Ali Jabbari
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Correspondence to Naader Alizadeh.

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Alizadeh, N., Salimi, S. & Jabbari, A. Liquid-Liquid Extraction of Palladium(II) from Hydrobromic Acid Media by Hexadecylpyridinium Bromide. ANAL. SCI. 18, 307–311 (2002). https://doi.org/10.2116/analsci.18.307

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  • DOI: https://doi.org/10.2116/analsci.18.307

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