Abstract
This research proposes a facile deposition technique for VO2 particles on a silica glass substrate with the aim of evaluating the thermochromic effect. An aqueous medium of 2-propanol was used as a dispersant, and the prepared suspension was sprayed onto a glass substrate. The VO2 thin film was characterized using various techniques including Zeta Potential Analysis, X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Fourier Transform Infrared Spectroscopy (FTIR), Energy Dispersive Spectroscopy by Scanning Electron Microscope (SEM–EDS), Atomic force microscopy (AFM), and UV–VIS-NIR Spectrophotometry. The results showed an average particle size of 100 nm with 2-propanol suspension. Regarding the VO2 thin film, a homogeneous and thin film with a particle size of 150 nm was obtained. The solar modulation of ΔTSol = 3.9% was achieved with 5 layers. This innovative approach is useful for designing and controlling the energy-efficient properties in smart windows, bringing them closer to practical application.
Graphical Abstract
Similar content being viewed by others
Data availability
Not applicable.
References
M. Kumar, J.P. Singh, K.H. Chae, J. Park, H.H. Lee, Superl. Microstruct (2020). https://doi.org/10.1016/j.spmi.2019.106335
Y. Long, Y. Cui, Y. Ke, C. Liu, Z. Chen, N. Wang, L. Zhang, Y. Zhou, S. Wang, Y. Gao, Joule. (2018). https://doi.org/10.1016/j.joule.2018.06.018
J.B. Kim, D. Lee, I.H. Yeo, H.Y. Woo, D.W. Kim, J.Y. Chae, D.W. Lee, S.H. Han, T. Paik, Sol. Energy Maters. Sol. C. (2021). https://doi.org/10.1016/j.solmat.2021.111055
N. Wang, S. Liu, X.T. Zeng, S. Magdassi, Y. Long, J. Mater. Chem. C. Mater. (2015). https://doi.org/10.1039/c5tc01062d
M.K. Dietrich, B.G. Kramm, M. Becker, B.K. Meyer, A. Polity, P.J. Klar, J. Appl. Phys. (2015). https://doi.org/10.1063/1.4919433
L. Hu, H. Tao, G. Chen, R. Pan, M. Wan, D. **ong, X. Zhao, J. Solgel. Sci. Technol. (2016). https://doi.org/10.1007/s10971-015-3832-z
N. Shen, S. Chen, Z. Chen, X. Liu, C. Cao, B. Dong, H. Luo, J. Liua, Y. Gao, J. Mater. Chem. A Mater. (2014). https://doi.org/10.1039/c4ta02880e
S. Chen, L. Dai, J. Liu, Y. Gao, X. Liu, Z. Chen, J. Zhou, C. Cao, P. Han, H. Luoab, M. Kanahira, Phys. Chem. Chem. Phys. (2013). https://doi.org/10.1039/c3cp52009a
H. Zhou, J. Li, S. Bao, J. Li, X. Liu, P. **, Appl. Surf. Sci. (2016). https://doi.org/10.1016/j.apsusc.2015.12.045
M.J. Powell, R. Quesada-Cabrera, A. Taylor, D. Teixeira, I. Papakonstantinou, R.G. Palgrave, G. Sankar, I.P. Parkin, Chem. Mater. (2016). https://doi.org/10.1021/acs.chemmater.5b04419
G. Xu, P. **, M. Tazawa, K. Yoshimura, Jpn. J. Appl. Phys. (2004). https://doi.org/10.1143/JJAP.43.186
X. Cao, N. Wang, J.Y. Law, S.C.J. Loo, S. Magdassi, Y. Long, Langmuir (2014). https://doi.org/10.1021/la404666n
J. Outón, E. Blanco, M. Domínguez, H. Bakkali, J.M. Gonzalez-Leal, J.J. Delgado, M. Ramírez-del-Solar, Appl. Surf. Sci. (2022). https://doi.org/10.1016/j.apsusc.2021.152228
Y.C. Lu, C.H. Hsueh, A.C.S. Appl, Nano. Mater. (2022). https://doi.org/10.1021/acsanm.2c00138
H. Ji, D. Liu, H. Cheng, C. Zhang, J. Mater. Chem. C. Mater. (2018). https://doi.org/10.1039/c8tc00286j
C.Y. Fragoso-Fernández, J.R. González-López, M.A. Guerra-Cossío, A. Toxqui-Terán, A.A. Zaldívar-Cadena, M.Z. Figueroa-Torres, J. Mater. Sci. Mater. Electron. (2022). https://doi.org/10.1007/s10854-022-09334-y
M. Zhu, H. Wang, H. Qi, D. Zhang, W. Lv, Opt. Mater. Express (2019). https://doi.org/10.1364/ome.9.001979
G. Bodurov, T. Ivanova, M. Abrashev, Z. Nenova, K. Gesheva, Phys. Proc. (2013). https://doi.org/10.1016/j.phpro.2013.07.054
S. Majid, S. Sahu, A. Ahad, K. Dey, K. Gautam, F. Rahman, P. Behera, U. Deshpande, V. Sathe, D. Shukla, Am. Phys. Soc. (2020). https://doi.org/10.1103/PhysRevB.101.014108
Acknowledgments
J.A. Mendoza-Jiménez thanks CONACYT for the scholarship provided with CVU 591308. The authors would like to thank the University Laboratory of Spectroscopic Characterization, LUCE_ICAT_UNAM and the researchers, Ph.D. Selene Islas, M.C. Viridiana Maturano, Ph.D. José Ocotlán and PhD. Rodolfo Zanella for the characterization of the samples through the techniques UV-VIS-NIR Spectrophotometry. The authors would like to thank to LANNBIO Cinvestav-Merida for XPS measurement.
Funding
Not applicable.
Author information
Authors and Affiliations
Contributions
MZF-T, MAR-G, JRG-L, AAZ-C, JAM-J: Conceptualization, Experimental Design; MZF-T, JAM-J: Introduction, Experimental Design, Results and Discussion; MZF-T, AC-L, JAM-J: Experimentation, Data Processing; MZF-T, JAM-J: Manuscript translate.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Figueroa-Torres, M.Z., Ruíz-Gómez, M.A., González-López, J.R. et al. Characterization of VO2 thin films deposited by simple and sustainable spray technique. MRS Advances 8, 1413–1418 (2023). https://doi.org/10.1557/s43580-023-00738-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/s43580-023-00738-4